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中国腐蚀与防护学报  2017, Vol. 37 Issue (4): 347-353    DOI: 10.11902/1005.4537.2016.046
  研究报告 本期目录 | 过刊浏览 |
Zn-7Mg合金热处理显微组织演变及耐蚀性能研究
牛振国1,2, 郭浦山1, 叶宏2, 杨丽景1(), 许赪1, 宋振纶1
1 中国科学院宁波工业技术研究院慈溪生物医学工程研究所 宁波 315201
2 重庆理工大学 材料科学与工程学院 重庆 400054
Microstructure Evolution and Corrosion Behavior of Degradable Zn-7Mg Alloy After Heat Treatment
Zhenguo NIU1,2, Pushan GUO1, Hong YE2, Lijing YANG1(), Cheng XU1, Zhenlun SONG1
1 Cixi Institute of Biomedical Engineering, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
2 College of Materials Science and Engineering, Chongqing University of Technology, Chongqing 400054, China
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摘要: 

研究了可降解Zn-7Mg合金经不同时间热处理后的显微组织演变及耐蚀性能。设计了锌镁合金Zn-7Mg材料,通过改变热处理时间获得Mg2Zn11相。通过EDS和ICP确定了锌镁合金的成分,运用OM和SEM分析合金的微观组织,利用XRD谱表征合金的物相组成,采用电化学方法测试合金的耐蚀性能。结果表明,Zn-7Mg合金在铸态时主要由α-Zn和MgZn2两相组成,热处理时包晶反应迅速发生。Zn-7Mg合金热处理后的平衡组织为Mg2Zn11相和少量残余的MgZn2相;电化学开路电位和电化学阻抗谱分析表明,Mg2Zn11在PBS溶液中的耐腐蚀性能较纯Zn差,在实际生产中应避免Mg2Zn11的产生。

关键词 : 锌合金,  热处理,  显微组织,  腐蚀    
Abstract:

Microstructure evolution and corrosion behavior of a degradable Zn-7Mg alloy after heat treatment was investigated by means of inductively coupled plasma emission spectrometer (ICP) and energy dispersive spectrometer (EDS), optical microscope (OM), scanning electron microscope (SEM) and X-ray diffraction (XRD) as well as electrochemical test in phosphate buffered saline (PBS). Results indicated that, the microstructure of the as-cast Zn-7Mg alloy was mainly composed of α-Zn and MgZn2, while the peritectic reaction occurred rapidly during heat treatment. After heat treatment the Zn-7Mg alloy was composed of stable phase Mg2Zn11 and a little of residual MgZn2. The phase Mg2Zn11 showed lower corrosion resistance in PBS solution than the pure zinc, therefore, the phase Mg2Zn11 should be avoided in actual production.

Key words: Zn alloy    heat treatment    microstructure    corrosion
收稿日期: 2016-04-06     
ZTFLH:  TG146.1+3  
基金资助:国家自然科学基金 (51301193),浙江省公益项目 (2015C31031) 和宁波市自然科学基金 (2015A610070)
作者简介:

作者简介 牛振国,男,1987年生,硕士生

引用本文:

牛振国, 郭浦山, 叶宏, 杨丽景, 许赪, 宋振纶. Zn-7Mg合金热处理显微组织演变及耐蚀性能研究[J]. 中国腐蚀与防护学报, 2017, 37(4): 347-353.
Zhenguo NIU, Pushan GUO, Hong YE, Lijing YANG, Cheng XU, Zhenlun SONG. Microstructure Evolution and Corrosion Behavior of Degradable Zn-7Mg Alloy After Heat Treatment. Journal of Chinese Society for Corrosion and protection, 2017, 37(4): 347-353.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2016.046      或      https://www.jcscp.org/CN/Y2017/V37/I4/347

图1  Zn-7Mg合金铸态金相显微组织
图2  Mg-Zn二元合金相图[25]
图3  铸态锌镁合金的SEM像
Point C O Mg Zn Total
1 7.29 3.04 12.54 77.13 100
2 7.69 3.23 0.34 88.74 100
表1  图3中不同位置的EDS结果
图4  不同热处理时间后Zn-7Mg合金的XRD谱
图5  Zn-7Mg合金经不同时间热处理后的金相组织
图6  Zn-7Mg合金经不同时间热处理后的SEM像
Point Mg Zn Total
1 0.12 99.88 100
2 7.24 92.76 100
3 15.44 84.56 100
表2  图6a中不同位置的EDS分析结果
图7  纯Zn和Mg2Zn11在PBS溶液中的开路电位曲线
图8  纯Zn和Mg2Zn11的电化学阻抗谱及等效电路
Material R1 / Ωcm2 Q R2 / Ωcm2 W / μFcm-2
P / μFcm-2 n
Pure Zn 4.49 150.6 0.80 3303 801
Mg2Zn11 12.48 241.2 0.59 1161 1960
表3  等效电路元件拟合值
图9  纯Zn和Mg2Zn11的电化学极化曲线
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