空间分辨技术在金属腐蚀原位监测中的应用

doi:10.11902/1005.4537.2019.120

中国腐蚀与防护学报

2020, Vol. 40

Issue (6): 495-507 DOI: 10.11902/1005.4537.2019.120

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空间分辨技术在金属腐蚀原位监测中的应用

赵鹏雄, 武玮, 淡勇(

)

西北大学化工学院西安 710069

Application of Spatial-resolution Technology for In-situ Monitoring of Metal Corrosion

ZHAO Pengxiong, WU Wei, DAN Yong(

)

School of Chemical Engineering, Northwest University, Xi'an 710069, China

全文: PDF(30317 KB) HTML

摘要:

综述了腐蚀领域几种经典的空间分辨技术，并详细探讨了每一种技术的工作原理、优缺点及其在金属腐蚀原位监测领域的应用现状和发展前景。

关键词 ：金属腐蚀, 空间分辨技术, 原位

Abstract：

Corrosion is one of the main causes of metal material failure. In corrosion research, it is difficult to obtain accurate information on the corrosion evolution. The development of spatial-resolution technology enables the in-situ observation of metal corrosion processes to be realized. By combining the spatial-resolution technology and electrochemical techniques, more microscopic metal corrosion information can be obtained, which facilitates more accurate acquisition of corrosion information and provides reliable support for the illustration of corrosion mechanism. This paper reviews several classical spatial-resolution techniques in the field of corrosion in terms their working principle, advantages and disadvantages etc. The industrial CCD camera, digital holographic surface imaging technology, X-ray computed tomography, optical microscope, scanning electron microscope, atomic force microscope and transmission electron microscope are introduced. The application status and development prospects of each technology in the field of in-situ monitoring of metal corrosion are discussed. Finally, these spatial-resolution techniques are compared and corresponding recommendations for use are proposed in the review.

Key words： metal corrosion spatial-resolved technology in-situ

收稿日期: 2019-08-11

ZTFLH:

TG172

基金资助:国家自然科学基金(21576224);国家自然科学基金(51605368);陕西省自然科学基础研究计划(2020JM-436)

通讯作者: 淡勇 E-mail: danyong@nwu.edu.cn

Corresponding author: DAN Yong E-mail: danyong@nwu.edu.cn

作者简介: 赵鹏雄，男，1995年生，硕士生

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赵鹏雄, 武玮, 淡勇. 空间分辨技术在金属腐蚀原位监测中的应用[J]. 中国腐蚀与防护学报, 2020, 40(6): 495-507.
Pengxiong ZHAO, Wei WU, Yong DAN. Application of Spatial-resolution Technology for In-situ Monitoring of Metal Corrosion. Journal of Chinese Society for Corrosion and protection, 2020, 40(6): 495-507.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2019.120 或 https://www.jcscp.org/CN/Y2020/V40/I6/495

图1 数字图像相关与电化学技术原位监测装置示意图[19]

图2 合金600在连四硫酸盐溶液中SCC原位实验CCD图像和DIC分析[19]

图3 数字全息表面成像系统的实验装置[23]

图4 304不锈钢在0.30 V下0.1 mol·L-1 FeCl3溶液中恒电位测量期间不同时间的全息图和相应的相图[23]

图5 用于304L不锈钢试样原位X射线断层扫描实验的可施加应变的微型电化学系统和X射线CT原位装置[31]

图6 第一次电化学极化扫描后试样的X射线CT图像，第二次电位-动态极化扫描后的X射线CT图像和试样的SEM像[31]

图7 用于应力腐蚀实验的光学显微镜原位测试装置[40]

图8 7075铝合金在光学显微镜下的SCC过程及相应的应力-应变曲线[40]

图9 X80管线钢在不同溶液中浸泡1 h后腐蚀表面蚀坑的SEM像[45]

图10 HS-AFM原位实验平台三电极装置的局部放大图[58]

图11 敏化AISI 304不锈钢在1%NaCl水溶液中晶界腐蚀的AFM像[58]

图12 极化测量后试样的动电位极化曲线和腐蚀过程STEM图像[66]

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