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中国腐蚀与防护学报  2021, Vol. 41 Issue (6): 877-882    DOI: 10.11902/1005.4537.2020.201
  研究报告 本期目录 | 过刊浏览 |
激光重熔对高锰铝青铜在3.5%NaCl溶液中空蚀行为的影响研究
宋亓宁1,2(), 武竹雨2, 李慧琳2, 佟瑶2, 许楠2, 包晔峰2
1.河海大学 疏浚技术教育部工程研究中心 常州 213022
2.河海大学 机电工程学院 常州 213022
Effect of Laser Surface Melting on Cavitation Erosion of Manganese-nickel-aluminum Bronze in 3.5%NaCl Solution
SONG Qining1,2(), WU Zhuyu2, LI Huilin2, TONG Yao2, XU Nan2, BAO Yefeng2
1.Engineering Research Center of Dredging Technology of Education, Hohai University, Changzhou 213022, China
2.College of Mechanical and Electrical Engineering, Hohai University, Changzhou 213022, China
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摘要: 

采用激光重熔对高锰铝青铜进行表面处理,并通过显微组织观察、电化学测试和超声振动空蚀等实验,研究激光重熔对铸态高锰铝青铜微观组织、腐蚀和空蚀行为的影响。结果表明,重熔后合金组织明显细化,且晶粒分布均匀,硬度相对于铸态合金提高了约45%。电化学实验结果表明,重熔处理合金与铸态合金的电极反应过程相似,但铸态合金的腐蚀电位较低,腐蚀倾向较大。空蚀实验结果表明,在3.5%NaCl溶液中空蚀5 h后,重熔处理合金的失重率仅为铸态合金的3/5。空蚀形貌观察结果表明,重熔处理合金表面损伤较轻且分布较均匀,表面粗糙度明显小于铸态合金。铸态和激光重熔合金的纯空蚀作用引起的失重占空蚀总失重比例分别为71.1%和50.8%,即力学冲击是造成空蚀损伤的主导因素。

关键词 高锰铝青铜激光重熔腐蚀空蚀交互作用    
Abstract

Laser remelting (LSM) was applied on cast high-Mn aluminum bronze (MAB). Then the effect of LSM on the microstructure, corrosion and cavitation erosion behavior in 3.5%NaCl solution for the cast MAB was studied via microstructure observation, electrochemical test and ultrasonic vibration cavitation test. The results showed that in comparison with the as cast bronze, the LSM bronze presents a microstructure of much finer and much homogeneously distributed crystallites, as well as a hardness of 45% higher. During electrochemical test, the LSM bronze shows more or less the same anodic and cathodic processes as that of the as cast one, however the cast bronze had a lower corrosion potential, indicating higher corrosion tendency. After cavitation erosion test in 3.5%NaCl solution for 5 h the weight loss rate of the LSM bronze was only 3/5 of that of the as cast one. Accordingly, the surface damage of the LSM bronze was much lighter with a similar damage degree everywhere, whilst the surface roughness of the LSM bronze was obviously smaller than that of the as cast one. In 3.5%NaCl solution, the synergy between corrosion and cavitation erosion deteriorated the surface damage. For both the as cast and the LSM bronze, the mechanical impact was the dominated factor for the cavitation erosion damage. For the cast bronze, the mass loss caused by the pure cavitation erosion accounted for 71.1% of the total mass loss and 50.8% for the LSM bronze.

Key wordsManganese-nickel-aluminum bronze    laser surface melting    corrosion    cavitation erosion    synergy
收稿日期: 2020-10-23     
ZTFLH:  TG172  
基金资助:国家自然科学基金(51601058);中央高校基本科研业务费专项(B210202129);江苏省自然科学基金(BK20191161)
通讯作者: 宋亓宁     E-mail: qnsong@hhu.edu.cn
Corresponding author: SONG Qining     E-mail: qnsong@hhu.edu.cn
作者简介: 宋亓宁,女,1990年生,博士,副教授

引用本文:

宋亓宁, 武竹雨, 李慧琳, 佟瑶, 许楠, 包晔峰. 激光重熔对高锰铝青铜在3.5%NaCl溶液中空蚀行为的影响研究[J]. 中国腐蚀与防护学报, 2021, 41(6): 877-882.
Qining SONG, Zhuyu WU, Huilin LI, Yao TONG, Nan XU, Yefeng BAO. Effect of Laser Surface Melting on Cavitation Erosion of Manganese-nickel-aluminum Bronze in 3.5%NaCl Solution. Journal of Chinese Society for Corrosion and protection, 2021, 41(6): 877-882.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2020.201      或      https://www.jcscp.org/CN/Y2021/V41/I6/877

图1  铸态及LSM MAB的显微组织
图2  铸态和LSM MAB在蒸馏水和3.5%NaCl溶液中的空蚀失重量-时间曲线及空蚀失重率-时间曲线
图3  静态和空蚀条件下铸态及LSM MAB在3.5%NaCl溶液中的极化曲线
SampleStaticCavitation
Icorr / A·cm-2Ecorr / mVv / mg·cm-2·h-1I'corr / A·cm-2E'corr / mVv / mg·cm-2·h-1
Cast MAB2.9472×10-6-4460.00703.5123×10-5-3480.0838
LSM MAB3.2265×10-6-3180.00775.9900×10-5-2930.1430
表1  铸态和LSM MAB在3.5%NaCl溶液中静态和空蚀条件下的电化学参数
Mass loss rate / mg·cm-2·h-1TECSCE
Cast MAB2.03901.45000.00700.58200.07680.5062
LSM MAB1.24000.63000.00770.60230.13530.4670
表2  铸态及LSM MAB的空蚀-腐蚀交互作用分析
图4  铸态及LSM MAB的腐蚀-空蚀交互作用各分量占空蚀总失重的比例
图5  铸态及LSM MAB在3.5%NaCl溶液中空蚀不同时间后的表面形貌图
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