AZ91D镁合金在氯化胆碱-尿素离子液体中电镀Zn的研究

中国腐蚀与防护学报

2010, Vol. 30

Issue (2): 155-160

会议论文

本期目录 | 过刊浏览

AZ91D镁合金在氯化胆碱-尿素离子液体中电镀Zn的研究

杨海燕^1;2;郭兴伍^1;2;吴国华^1;2;丁文江^1;2

1. 上海交通大学轻合金精密成型国家工程研究中心上海 200240
2. 上海交通大学金属基复合材料国家重点实验室上海 200240

ELECTRODEPOSITION OF Zn ON AZ91D IN CHOLINE CHLORIDE-2UREA IONIC LIQUID

YANG Haiyan^1;2; GUO Xingwu^1;2; WU Guohua^1;2; DING Wenjiang^1;2

1. National Engineering Research Center of Light Alloy Net Forming; Shanghai Jiaotong University; Shanghai 200240
2. State Key Laboratory of Metal Matrix Composites; Shanghai Jiaotong University; Shanghai 200240

全文: PDF(1911 KB)

摘要:

采用价廉、环保和稳定性好的氯化胆碱-尿素离子液体作为溶剂，在AZ91D镁合金上进行电镀Zn 研究，包括AZ91D基体的前处理机制及电流方式对镀层形貌及耐腐蚀性能的影响。结果表明，经前处理的AZ91D镁合金在氯化胆碱-尿素离子液体中电镀可获得Zn镀层，脉冲电镀比恒流电镀更利于获得致密均匀、与基体结合良好的Zn层；脉冲电镀Zn层后，基体AZ91D镁合金的开路电位OCP从-1610 mV正移至-1072 mV，腐蚀电流I_corr从14.9 μA/cm²降为6.9 μA/cm²，与纯Zn(OCP=-1078 mV， I _corr=6.6 μA/cm²)相当。

关键词 ： AZ91D镁合金, 离子液体, 电镀, 腐蚀

Abstract：

In aqueous electrolytes, electrodeposition on Mg alloys is still a challenge because Mg has high chemical reactivity. The process becomes more complicated in aqueous electrolytes owing to the hydrogen evolution. Ionic liquids as non-aqueous electrolytes in electrodeposition have received much attention from researchers. In present study, choline chloride-urea ionic liquid, which is sustainable, biodegradable and stable in air and water, was used as the solvent and the electrodeposition of Zn on AZ91D magnesium alloy was investigated. The pretreatment mechanism of the AZ91D substrate and the effect of current mode on the Zn coatings were studied by scanning electron microscope (SEM/EDX). The corrosion resistance of the deposited Zn coatings were studied by electrochemical testing. The results show, Zn coatings could be electrodeposited on pretreated AZ91D substrate from choline chloride-urea ionic liquid. Application of pulse deposition was superior to galvanostatic deposition in producing dense, uniform and cohesive Zn coating. By pulse deposition Zn coatings, the OCP of AZ91D substrate moves in positive direction from -1610 mV to -1072 mV and the corrosion current density I_corr decreases from 14.9 μA/cm² to 6.9 μA/cm²，comparable to those of pure Zn (OCP=-1078 mV， I_corr=6.6 μA/cm²).

Key words： AZ91D magnesium alloy ionic liquid electrodeposition corrosion

收稿日期: 2009-10-27

ZTFLH:

TG174.441

基金资助:

上海市优秀学科带头人计划项目(08XD14020), 国家重点基础研究发展规划项目(2007CB613701)和中国航天科技集团公司航天科技创新基金项目(0502)资助

通讯作者: 郭兴伍 E-mail: xingwuguo@sjtu.edu.cn

Corresponding author: GUO Xingwu E-mail: xingwuguo@sjtu.edu.cn

作者简介: 杨海燕，女，1981年生，博士生，研究方向为离子液体中电沉积

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	杨海燕
	郭兴伍
	吴国华
	丁文江
44.8K

引用本文:

杨海燕;郭兴伍;吴国华;丁文江. AZ91D镁合金在氯化胆碱-尿素离子液体中电镀Zn的研究[J]. 中国腐蚀与防护学报, 2010, 30(2): 155-160.
YANG Hai-Yan, GUO Xin-Wu, WU Guo-Hua, DING Wen-Jiang. ELECTRODEPOSITION OF Zn ON AZ91D IN CHOLINE CHLORIDE-2UREA IONIC LIQUID. J Chin Soc Corr Pro, 2010, 30(2): 155-160.

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y2010/V30/I2/155

[1] Peng T, Wang Q D, Lin J B. Microstructure and mechanical properties of Mg-10Gd-2Y-0.5Zr alloy recycled by cyclic extrusion compression [J]. Mater. Sci. Eng., 2009, A516(1-2): 23-30
[2] Wang Q D, Ding W J. Trends and development of magnesium alloys and their forming technology [J]. World Sci-Technol. R&D, 2004,26(3)：39-46
    (王渠东，丁文江. 镁合金及其成形技术的国内外动态与发展[J]. 世界科技研究与发展，2004, 26(3)：39-46)
[3] Ambat R, Zhou W. Electroless nickel-plating on AZ91D magnesium alloy: Effect of substrate microstructure and plating parameters [J].Surf. Coat. Technol., 2004, 179(2-3): 124-134
[4] Jiang Y F, Guo X W, Wei Y H,et al. Corrosion protection of polypyrrole electrodeposited on AZ91 magnesium alloys in alkaline solutions [J]. Synth. Met., 2003, 139(2): 335-339
[5] Song G L, Atrens A. Corrosion mechanisms of magnesium alloys [J]. Adv. Eng. Mater. 1999, 1(1): 11-33
[6] Song G. Recent progress in corrosion and protection of magnesium alloys [J]. Adv. Eng. Mater., 2005, 7(7) 563-586
[7] Liu Q X, El Abedin S Z, Endres F. Electroplating of mild steel by aluminium in a first generation ionic liquid: a green alternative to commercial Al plating in organic solvents [J]. Surf. Coat.Technol., 2006, 201(3-4): 1352-1356
[8] Tai C C, Su F Y, Sun I W. Electrodeposition of palladium-silver in a Lewis basic 1-ethyl-3-methylimidazolium chloride-tetrafluoroborate ionic liquid [J]. Electrochim. Acta, 2005, 50(28): 5504-5509
[9] Hsiu S I, Tai C C, Sun I W. Electrodeposition of palladium-indium from 1-ethyl-3-methylimidazolium chloride tetrafluoroborate ionic liquid [J]. Electrochim. Acta., 2006, 51(13): 2607-2613
[10] Yang H Y, Guo X Y, Wu G H, et al. Research progress of electrodeposition in ionic liquids [J]. Mater. Rev., 2009, 23(3): 17-21
     (杨海燕，郭兴伍，吴国华等. 离子液体中电沉积的研究进展 [J]. 材料导报,2009, 23(3)：17-21)
[11] Chang J K, Chen S Y, Tsai W T, et al. Electrodeposition of aluminum on magnesium alloy in aluminum chloride (AlCl₃)-1-ethyl-3-methylimidazolium chloride (EMIC) ionic liquid and its corrosion behavior [J]. Electrochem.Comm., 2007, 9: 1602-1606
[12] Chang J K, Chen S Y, Tsai W T. et al. Improved corrosion resistance of magnesium alloy with a surface aluminum coating electrodeposited in ionic liquid [J]. J.Electrochem. Soc., 2008, 155(3): C112-C116
[13] Bakkar A, Neubert V. Electrodeposition onto magnesium in air and water stable ionic liquids: From corrosion to successful plating [J].Electrochem. Comm., 2007, (9): 2428-2435
[14] Abbott A P, Davies D L, Capper G, et al. Ionic liquids and their use as solvents [P]. World Intellectual Property Organization (WIPO) WO0226701, 2002
[15] Liu Y F, Qian J G, Huang W. Effect of pretreatment process on electroless nickel plating of AZ91D magnesium alloy [J]. Mater.Prot., 2008, 41(6): 33-36
     (刘玉芬, 钱建刚, 黄巍. AZ91D镁合金前处理工艺对化学镀镍的影响 [J]. 材料保护, 2008, 41(6): 33-36)
[16] Yang H Y, Wei Y H, Bi H C, et al. Electroless plating of Ni-P on mobile telephone's inner component made of die-cast AZ91D [J]. Rare Met. Mater. Eng., 2005, 34(12): 1978-1981
     (杨海燕, 卫英慧, 毕虎才等. 压铸镁合金AZ91D手机内构件的Ni-P化学镀.稀有金属材料与工程. 2005, 34(12): 1978-1981)
[17] Yang H Y, Wu G H, Ding W J. Present research status of process of electroless Ni-P alloy plating on magnesium alloys [J]. Plat.Finish., 2008, 30(3): 16-20
     (杨海燕, 吴国华，丁文江. 镁合金化学镀Ni-P合金工艺研究现状 [J]. 电镀与精饰, 2008, 30(3): 16-20)
[18] Jiang Y F, Liu L F, Zhai C Q, et al. Corrosion behavior of pulse-plated Zn-Ni alloy coating on AZ91 magnesium in alkaline solutions [J]. Thin Solid Films, 2005, 484(1-2): 232-237

[1]	董续成, 管方, 徐利婷, 段继周, 侯保荣. 海洋环境硫酸盐还原菌对金属材料腐蚀机理的研究进展[J]. 中国腐蚀与防护学报, 2021, 41(1): 1-12.
[2]	唐荣茂, 朱亦晨, 刘光明, 刘永强, 刘欣, 裴锋. Q235钢/导电混凝土在3种典型土壤环境中腐蚀的灰色关联度分析[J]. 中国腐蚀与防护学报, 2021, 41(1): 110-116.
[3]	韩月桐, 张鹏超, 史杰夫, 李婷, 孙俊才. 质子交换膜燃料电池中TA1双极板的表面改性研究[J]. 中国腐蚀与防护学报, 2021, 41(1): 125-130.
[4]	张雨轩, 陈翠颖, 刘宏伟, 李伟华. 铝合金霉菌腐蚀研究进展[J]. 中国腐蚀与防护学报, 2021, 41(1): 13-21.
[5]	冉斗, 孟惠民, 刘星, 李全德, 巩秀芳, 倪荣, 姜英, 龚显龙, 戴君, 隆彬. pH对14Cr12Ni3WMoV不锈钢在含氯溶液中腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2021, 41(1): 51-59.
[6]	左勇, 曹明鹏, 申淼, 杨新梅. MgCl₂-NaCl-KCl熔盐体系中金属Mg对316H不锈钢的缓蚀性能研究[J]. 中国腐蚀与防护学报, 2021, 41(1): 80-86.
[7]	王欣彤, 陈旭, 韩镇泽, 李承媛, 王岐山. 硫酸盐还原菌作用下2205双相不锈钢在3.5%NaCl溶液中应力腐蚀开裂行为研究[J]. 中国腐蚀与防护学报, 2021, 41(1): 43-50.
[8]	史昆玉, 吴伟进, 张毅, 万毅, 于传浩. TC4表面沉积Nb涂层在模拟体液环境下的电化学性能研究[J]. 中国腐蚀与防护学报, 2021, 41(1): 71-79.
[9]	郑黎, 王美婷, 于宝义. 镁合金表面冷喷涂技术研究进展[J]. 中国腐蚀与防护学报, 2021, 41(1): 22-28.
[10]	于宏飞, 邵博, 张悦, 杨延格. 2A12铝合金锆基转化膜的制备及性能研究[J]. 中国腐蚀与防护学报, 2021, 41(1): 101-109.
[11]	贾世超, 高佳祺, 郭浩, 王超, 陈杨杨, 李旗, 田一梅. 再生水水质因素对铸铁管道的腐蚀研究[J]. 中国腐蚀与防护学报, 2020, 40(6): 569-576.
[12]	赵鹏雄, 武玮, 淡勇. 空间分辨技术在金属腐蚀原位监测中的应用[J]. 中国腐蚀与防护学报, 2020, 40(6): 495-507.
[13]	马鸣蔚, 赵志浩, 荆思文, 于文峰, 谷义恩, 王旭, 吴明. 17-4 PH不锈钢在含SRB的模拟海水中的应力腐蚀开裂行为研究[J]. 中国腐蚀与防护学报, 2020, 40(6): 523-528.
[14]	岳亮亮, 马保吉. 超声表面滚压对AZ31B镁合金腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2020, 40(6): 560-568.
[15]	艾芳芳, 陈义庆, 钟彬, 李琳, 高鹏, 伞宏宇, 苏显栋. T95油井管在酸性油气田环境中的应力腐蚀开裂行为及机制[J]. 中国腐蚀与防护学报, 2020, 40(5): 469-473.

Viewed

Full text

Abstract

Cited

Shared

Discussed