耐腐蚀<strong>Mg-Li</strong>合金的腐蚀与防护及其性能研究进展

doi:10.11902/1005.4537.2022.300

中国腐蚀与防护学报

2023, Vol. 43

Issue (6): 1255-1263 CSTR: 32134.14.1005.4537.2022.300 DOI: 10.11902/1005.4537.2022.300

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耐腐蚀Mg-Li合金的腐蚀与防护及其性能研究进展

田光元¹, 严程铭¹, 杨智皓¹, 王俊升¹^,²(

)

^1.北京理工大学材料学院北京 100081
^2.北京理工大学前沿交叉学院北京 100081

Research Progress on Corrosion and Protection of Corrosion-resistant Mg-Li Alloys

TIAN Guangyuan¹, YAN Chengming¹, YANG Zhihao¹, WANG Junsheng¹^,²(

)

^1.School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China
^2.Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China

引用本文:

田光元, 严程铭, 杨智皓, 王俊升. 耐腐蚀Mg-Li合金的腐蚀与防护及其性能研究进展[J]. 中国腐蚀与防护学报, 2023, 43(6): 1255-1263.
Guangyuan TIAN, Chengming YAN, Zhihao YANG, Junsheng WANG. Research Progress on Corrosion and Protection of Corrosion-resistant Mg-Li Alloys[J]. Journal of Chinese Society for Corrosion and protection, 2023, 43(6): 1255-1263.

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摘要:

高比强度和高比刚度Mg-Li合金，由于其出色的减重效果，是理想的航空航天金属结构工程材料。然而，由于其耐腐蚀性能较差，严重制约了其在一些服役环境中的广泛应用。因此，耐腐蚀Mg-Li合金的成分、工艺研制是未来发展的重要方向。本文综述了其腐蚀机理及不同类型表面防护方法 (金属涂层、阳极氧化、导电性-屏蔽性聚合物涂层和智能涂层)、研究现状与未来应用。同时，分析了不同类型腐蚀防护方法的优势与局限性问题，讨论了耐腐蚀Mg-Li合金腐蚀与防护的未来研究趋势，以期为耐腐蚀Mg-Li合金开发提供新思路。

关键词 ： Mg-Li合金, 腐蚀, 防护, 智能涂层, 超疏水

Abstract：

Mg-Li alloys with high specific strength and stiffness are ideal metal structural engineering materials for aerospace due to their excellent weight reduction effect. However, their poor corrosion resistance severely limits the wide application in some service environments. Therefore, in order to meet the demand of application, it is still necessary to adjust and optimize the composition of corrosion resistant Mg-Li alloys and improve its preparation process in the future. The research status on corrosion mechanism and different types of surface protection methods (metallic coating, anodic oxidation, conductive-shielded polymer coating, and smart coating), as well as future applications of corrosion-resistant Mg-Li alloys were summarized in this paper. Meanwhile, the advantages and limitation of different types of corrosion protection methods were analyzed, and the future research directions of corrosion and protection for corrosion resistant Mg-Li alloys are discussed so that to provide new ideas for future development of higher corrosion-resistant Mg-Li alloys.

Key words： Mg-Li alloy corrosion protection smart coating superhydrophobic

收稿日期: 2022-09-28 32134.14.1005.4537.2022.300

ZTFLH:

TG146.22

基金资助:国家自然科学基金(52073030);国家自然科学基金广西区域创新联合基金(U20A20276)

通讯作者: 王俊升，E-mail: junsheng.wang@bit.edu.cn，研究方向为航空航天轻质铝合金、镁合金的设计与开发，铝合金、镁合金表面腐蚀与防护

Corresponding author: WANG Junsheng, E-mail: junsheng.wang@bit.edu.cn

作者简介: 田光元，男，1993年生，博士生

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表1 LC41合金在SBF中电化学极化实验的结果总结

图1 Mg-8Li合金在NaCl溶液中的腐蚀机理[11]

图2 HCP、HCP+BCC和BCC Mg-Li合金表面腐蚀层的形成示意图[13]

图3 含Ce-MCM-22的划痕环氧涂层在0.35%NaCl溶液中浸泡不同时间的SEM和Ce映射分析图像。(注：扫描前浸入120 h后，划痕样品的涂层从Mg-Li合金剥离)[42]

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