CORROSION BEHAVIOR OF Q235 CARBON STEEL IN SEAWATER REVERSE OSMOSIS PERMEATE

Journal of Chinese Society for Corrosion and protection

2012, Vol. 32

Issue (5): 412-416 DOI:

Current Issue | Archive | Adv Search

CORROSION BEHAVIOR OF Q235 CARBON STEEL IN SEAWATER REVERSE OSMOSIS PERMEATE

LIANG Qinqin¹, CAO Shun’an¹, YIN Li¹, XIAO Li²

1. College of Power and Mechanical Engineering, Wuhan University, Wuhan 430072
2. Zhejiang Zheneng Yueqing Power Generation Co. Ltd, Wenzhou 325609

Download:

PDF(970KB)
Export: BibTeX | EndNote (RIS)

Abstract

The corrosion behavior of Q235 steel in seawater reverse osmosis permeate(RO) was investigated by rotation coupon method, SEM, IR and XRD, and electrochemical tests were used for studying the control step and electrode process of corrosion reaction. Experimental results showed that the corrosion rate was speeded up in first 48 h and maintained at 1.4 mm/a afterwards. Initial rust layer was formed by a thin layer of\linebreak γ-FeOOH, and with time passing by, it transformed to a double-layer structure with inner thick Fe₃O₄ layer and outer α-FeOOH/γ-FeOOH layer. Corrosion process was controlled by cathodic reaction, resistance of which reached peak in initial stage, then reduced rapidly because of conversion of γ-FeOOH to Fe₃O₄, which provided no inhibition of corrosion and caused high corrosion rate of Q235 steel. As the generation and conversion of γ-FeOOH reached equilibrium on the surface of Q235 steel, corrosion resistance and corrosion rate kept steady.

Key words: seawater desalination reverse osmosis permeate Q235 steel corrosion

Received: 12 October 2011

ZTFLH:

TG172

Corresponding Authors: LIANG Qinqin E-mail: liangqinqin716@gmail.com

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	LIANG Qinqin
	CAO Shun’an
	YIN Li
	XIAO Li

Cite this article:

LIANG Qinqin, CAO Shun’an, YIN Li, XIAO Li. CORROSION BEHAVIOR OF Q235 CARBON STEEL IN SEAWATER REVERSE OSMOSIS PERMEATE. Journal of Chinese Society for Corrosion and protection, 2012, 32(5): 412-416.

URL:

https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y2012/V32/I5/412

[1] Marangou V S, Savvides K. First desalination plant in cyprus product water aggressivity and corrosion control[J]. Desalination, 2001, 138: 251-258

[2] Wei C Z, Shen S R. Application of membrane method seawater desalination technology in Yuhuan power plant[J]. Electric Power Technol. Environ. Prot., 2010, 26(5): 48-49

    (韦存忠, 沈隼睿. 膜法海水淡化技术在玉环电厂的应用[J]. 电力科技与环保, 2010, 26(5): 48-49)

[3] Li J, Liu G C, Wang W, et al. Research of corrosion resistance of carbon steel in RO desalinated water[J]. Guangzhou Chem. Ind., 2009, 37(4): 95-97

    (李敬, 刘贵昌, 王玮等. 碳钢在反渗透水中耐蚀性研究[J]. 广州化工, 2009, 37(4): 95-97)

[4] Liu G Z, Zhang X, Hao S L, et al. Corrosion inhibition of seawater reverse osmosis permeate[P]. China: CN101381169

    (刘光洲, 张茜, 郝少丽等. 一种海水淡化一级反渗透水的缓蚀方法[P]. 中国: CN101381169)

[5] GB/T 18175-2000. Determination of corrosion inhibition performance of water treatment agents-rotation specimen method[S]. Beijing: Standards Press of China, 2001(GB/T 18175-2000. 水处理剂缓蚀性能的测定旋转挂片法[S]. 北京: 中国标准出版社, 2001)

[6] Zou Y, Zheng Y Y, Wang Y H, et al. Cathodic electrochemical behaviors of mild steel in seawater[J]. Acta Metall. Sin., 2010, 46(1): 123-128

    (邹妍, 郑莹莹, 王燕华等. 低碳钢在海水中的阴极电化学行为[J]. 金属学报, 2010, 46(1): 123-128)

[7] Cao C N, Zhang J Q. An Introduction to Electrochemical Impedance Spectroscopy[M]. Beijing: Science Press, 2002

    (曹楚南, 张鉴清. 电化学阻抗谱导论[M]. 北京: 科学出版社, 2002)

[8] Misawa T, Kyuno T, Suetaka W, et al. The mechanism of atmospheric rusting and the effect of Cu and P on the rust formation of low alloy steels[J]. Corros. Sci., 1971, 11: 35-48

[9] Xie Y, Li Y, Sun T, et al. Research on protection performance of γ-FeOOH and α-FeOOH rust layer in-situ growing on Q235 steel[J]. Chin. Sci. Bull., 2008, 53(23): 2848-2855

    (谢颖, 李瑛, 孙挺等. 原位生长的纯γ-FeOOH 和α-FeOOH 锈膜对Q235钢保护性能的研究[J]. 科学通报, 2008, 53(23):2848-2855)

[10] Hack H P. Galvanic Corrosion[M]. Philadelphia: ASTM, 1988

[1]	HUANG Peng, GAO Rongjie, LIU Wenbin, YIN Xubao. Fabrication of Superamphiphobic Surface for Nickel-plate on Pipeline Steel by Salt Solution Etching and Its Anti-corrosion Properties[J]. 中国腐蚀与防护学报, 2021, 41(1): 96-100.
[2]	DONG Xucheng, GUAN Fang, XU Liting, DUAN Jizhou, HOU Baorong. Progress on the Corrosion Mechanism of Sulfate-reducing Bacteria in Marine Environment on Metal Materials[J]. 中国腐蚀与防护学报, 2021, 41(1): 1-12.
[3]	TANG Rongmao, ZHU Yichen, LIU Guangming, LIU Yongqiang, LIU Xin, PEI Feng. Gray Correlative Degree Analysis of Q235 Steel/conductive Concrete Corrosion in Three Typical Soil Environments[J]. 中国腐蚀与防护学报, 2021, 41(1): 110-116.
[4]	HAN Yuetong, ZHANG Pengchao, SHI Jiefu, LI Ting, SUN Juncai. Surface Modification of TA1 Bipolar Plate for Proton Exchange Membrane Fuel Cell[J]. 中国腐蚀与防护学报, 2021, 41(1): 125-130.
[5]	ZHANG Yuxuan, CHEN Cuiying, LIU Hongwei, LI Weihua. Research Progress on Mildew Induced Corrosion of Al-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 13-21.
[6]	RAN Dou, MENG Huimin, LIU Xing, LI Quande, GONG Xiufang, NI Rong, JIANG Ying, GONG Xianlong, DAI Jun, LONG Bin. Effect of pH on Corrosion Behavior of 14Cr12Ni3WMoV Stainless Steel in Chlorine-containing Solutions[J]. 中国腐蚀与防护学报, 2021, 41(1): 51-59.
[7]	BAI Yunlong, SHEN Guoliang, QIN Qingyu, WEI Boxin, YU Changkun, XU Jin, SUN Cheng. Effect of Thiourea Imidazoline Quaternary Ammonium Salt Corrosion Inhibitor on Corrosion of X80 Pipeline Steel[J]. 中国腐蚀与防护学报, 2021, 41(1): 60-70.
[8]	ZUO Yong, CAO Mingpeng, SHEN Miao, YANG Xinmei. Effect of Mg on Corrosion of 316H Stainless Steel in Molten Salts MgCl₂-NaCl-KCl[J]. 中国腐蚀与防护学报, 2021, 41(1): 80-86.
[9]	WANG Yating, WANG Kexu, GAO Pengxiang, LIU Ran, ZHAO Dishun, ZHAI Jianhua, QU Guanwei. Inhibition for Zn Corrosion by Starch Grafted Copolymer[J]. 中国腐蚀与防护学报, 2021, 41(1): 131-138.
[10]	WANG Xintong, CHEN Xu, HAN Zhenze, LI Chengyuan, WANG Qishan. Stress Corrosion Cracking Behavior of 2205 Duplex Stainless Steel in 3.5%NaCl Solution with Sulfate Reducing Bacteria[J]. 中国腐蚀与防护学报, 2021, 41(1): 43-50.
[11]	SHI Kunyu, WU Weijin, ZHANG Yi, WAN Yi, YU Chuanhao. Electrochemical Properties of Nb Coating on TC4 Substrate in Simulated Body Solution[J]. 中国腐蚀与防护学报, 2021, 41(1): 71-79.
[12]	ZHENG Li, WANG Meiting, YU Baoyi. Research Progress of Cold Spraying Coating Technology for Mg-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 22-28.
[13]	WEI Zheng, MA Baoji, LI Long, LIU Xiaofeng, LI Hui. Effect of Ultrasonic Rolling Pretreatment on Corrosion Resistance of Micro-arc Oxidation Coating of Mg-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 117-124.
[14]	YU Hongfei, SHAO Bo, ZHANG Yue, YANG Yange. Preparation and Properties of Zr-based Conversion Coating on 2A12 Al-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 101-109.
[15]	ZHANG Hao, DU Nan, ZHOU Wenjie, WANG Shuaixing, ZHAO Qing. Effect of Fe³⁺ on Pitting Corrosion of Stainless Steel in Simulated Seawater[J]. 中国腐蚀与防护学报, 2020, 40(6): 517-522.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed