Stress Corrosion Cracking Behavior of 2205 Duplex Stainless Steel in 3.5%NaCl Solution with Sulfate Reducing Bacteria

doi:10.11902/1005.4537.2019.268

Journal of Chinese Society for Corrosion and protection

2021, Vol. 41

Issue (1): 43-50 DOI: 10.11902/1005.4537.2019.268

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Stress Corrosion Cracking Behavior of 2205 Duplex Stainless Steel in 3.5%NaCl Solution with Sulfate Reducing Bacteria

WANG Xintong, CHEN Xu(

), HAN Zhenze, LI Chengyuan, WANG Qishan

College of Petroleum Engineering, Liaoning Shihua University, Fushun 113001, China

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Abstract

Materials served in marine environments are not only subjected to the Cl^- and ocean currents, but also suffered from biological fouling. The effect of sulfate reduction bacteria (SRB) metabolism on the stress corrosion cracking (SCC) behavior of 2205 duplex stainless steel (DSS) in 3.5% (mass fraction) NaCl solution were investigated by means of potentiondynamic polarization technology, slow strain rate test (SSRT) and scanning electron microscopy (SEM). The results showed that compared with the sterile solution, the presence of SRB promoted the anodic dissolution process of 2205 DSS in the bacterial solution and induced pitting, which facilitated cracks initiation. The SCC sensitivity of 2205 DSS was positively correlated with the concentration of SRB activity. The SRB activity concentration was the highest during their stable growth period, and the resulted metabolite H₂S could induce the increase of brittleness of the steel. In this case, SCC sensitivity of 2205DSS was the highest. The SCC mechanism of 2205DSS in 3.5%NaCl solution containing SRB was the mutual control of anodic dissolution and hydrogen damage. In the presence of SRB, the ferritic phase in 2205DSS exhibited transgranular cleavage, while the austenitic phase exhibited ductile tearing, and the ferritic phase had higher SCC sensitivity.

Key words: 2205 duplex stainless steel sulfate-reducing bacteria microbiological corrosion stress corrosion cracking

Received: 19 December 2019

ZTFLH:

TG172.5

Fund: Key Project of Education Department of Liaoning Province of China(L2017LZD004);Chunhui;Program of the Ministry of Education of China

Corresponding Authors: CHEN Xu E-mail: cx0402@sina.com

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Cite this article:

WANG Xintong, CHEN Xu, HAN Zhenze, LI Chengyuan, WANG Qishan. Stress Corrosion Cracking Behavior of 2205 Duplex Stainless Steel in 3.5%NaCl Solution with Sulfate Reducing Bacteria. Journal of Chinese Society for Corrosion and protection, 2021, 41(1): 43-50.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2019.268 OR https://www.jcscp.org/EN/Y2021/V41/I1/43

Fig.1 Metallographic microstructure of 2205DSS

Fig.2 Schematic diagram of SSRT sample

Fig.3 Growth curve of SRB in 3.5%NaCl solution

Fig.4 Polarization curves of 2205DSS in 3.5%NaCl solution

Table 1 Fitting parameters of polarization curves of 2205 stainless steel in 3.5%NaCl solution

Fig.5 Stress-strain curves of 2205DSS after immersion in 3.5%NaCl solutions for different time

Fig.6 Elongation (a) and reduction of area (b) curves of 2205DSS after SSRT

Fig.7 Main fracture (a1~e1) and side fracture (a2~e2) morphologies of 2205DSS immersed in sterile solution (a1, a2) and bacteria containing solution for 3 d (b1, b2), 8 d (c1, c2), 10 d (d1, d2) and 14 d (e1, e2)

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