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Surface Modification of TA1 Bipolar Plate for Proton Exchange Membrane Fuel Cell |
HAN Yuetong, ZHANG Pengchao, SHI Jiefu, LI Ting, SUN Juncai( ) |
Institute of Materials Technology, Dalian Maritime University, Dalian 116026, China |
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Abstract The operation efficiency of proton exchange membrane fuel cell (PEMFC) is primarily affected by the electrical conductivity, corrosion resistance and hydrophobicity of the bipolar plate. Zr coating (Zr-TA1) is prepared by double glow plasma method on TA1 commercial pure Ti-bipolar plate. Then the microstructure and properties of the Zr coated TA1 Ti-plate are studied. It follows that, the thickness of Zr coating is about 3 μm and the coating surface is smooth and compact. Its potentiodynamic/potentiostatic polarization curves are measured in the cathodic and anodic environments of PEMFC, which shows that the corrosion potential of Zr-TA1 is increased significantly and the corrosion current density is decreased by 1~2 orders of magnitude in comparison with the bare TA1 Ti-plate. Furthermore, the hydrophobicity of TA1 is improved by Zr coating and the water contact angle is increased from 71o (TA1) to 94o (Zr-TA1). In addition, the contact resistance of Zr-TA1 (under the compaction pressure of 140 N·cm-2) is decreased from 117.3 mΩ·cm2 to 15.5 mΩ·cm2, namely, the surface conductivity of the Ti-plate was significantly improved.
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Received: 14 January 2020
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Fund: National Key R&D Program of China(2016YFB0101206) |
Corresponding Authors:
SUN Juncai
E-mail: sunjc@dlmu.edu.cn
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