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Journal of Chinese Society for Corrosion and protection  2014, Vol. 34 Issue (6): 502-506    DOI: 10.11902/1005.4537.2013.232
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Hot Corrosion Behavior of Four Modified Aluminide Coatings on DZ38G Alloy
WU Duoli, ZHANG Hongyu, WEI Hua(), ZHENG Qi, JIN Tao, SUN Xiaofeng
Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
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Abstract  

Four modified aluminide coatings were prepared on superalloy DZ38G, which include a two step co-cementation coating NiCr-CrAl and three one step co-cementation coatings Co-Al, Al-Si and Al-Ti. Then their microstructure and hot corrosion behavior in a salt melt of 25%NaCl (mass fraction)+75%Na2SO4 (mass fraction) at 900 ℃ were investigated. The results show that a continuously compact scale of corrosion products with good adhesion to the matrix could form on Ti-Al coating during corrosion, therefore, the Al-Ti coating may provide much better protectiveness to the alloy rather than the other three coatings in this kind of salt mixture.

Key words:  superalloy      coating      hot corrosion     
ZTFLH:  TG174.3  

Cite this article: 

WU Duoli, ZHANG Hongyu, WEI Hua, ZHENG Qi, JIN Tao, SUN Xiaofeng. Hot Corrosion Behavior of Four Modified Aluminide Coatings on DZ38G Alloy. Journal of Chinese Society for Corrosion and protection, 2014, 34(6): 502-506.

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https://www.jcscp.org/EN/10.11902/1005.4537.2013.232     OR     https://www.jcscp.org/EN/Y2014/V34/I6/502

Coating Cr Co Ti Al Si Ni
NiCr-CrAl 7 9 1 23 --- Bal.
Co-Al --- 14 --- 33 --- Bal.
Al-Si 5 9 1 22 3.5 Bal.
Al-Ti --- --- 5 30 --- Bal.
Table 1  Chemical compositions of the out layer of four aluminide coatings
Fig.1  Hot corrosion kinetic curves of the four coatings on DZ38G alloy at 900 ℃
Fig.2  Surface XRD spectra of the four coatings on DZ38G alloy after hot corrosion for 100 h at 900 ℃
Fig.3  Surface morphologies of NiCr-CrAl coating on DZ38G alloy after hot corrosion for 100 h: (a) overall morphology, (b) local morphology
Fig.4  Surface morphologies of Co-Al coating on DZ38G alloy after corrosion for 100 h:

(a) overall morphology, (b) local morphology

Fig.5  Surface morphologies of Al-Si coating on DZ38G alloy after hot corrosion for 100 h:

(a) overall morphology, (b) local morphology

Fig.6  Surface morphologies of Al-Ti coating on DZ38G alloy after hot corrosion for 100 h:

(a) overall morphology, (b) local morphology

Fig.7  Cross sectional morphologies of NiCr-CrAl coating (a), Co-Al coating (b), Al-Si coating (c) and Al-Ti coating (d) on DZ38G alloy after hot corrosion for 100 h
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