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Journal of Chinese Society for Corrosion and protection  2021, Vol. 41 Issue (2): 209-218    DOI: 10.11902/1005.4537.2021.008
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Failure Behavior of Fresh Water Tank Coating in Different Water
CAO Jingyi1, YANG Yange2(), FANG Zhigang1, SHOU Haiming3, LI Liang1, FENG Yafei1, WANG Xingqi2, CHU Guangzhe1, ZHAO Yi1
1.Unit 92228, People's Liberation Army, Beijing 100072, China
2.Shi -changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3.Unit 92942, People's Liberation Army, Beijing 100161, China
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Abstract  

Failure behavior of epoxy coating used for fresh water tank, namely epoxy coating/Q235 carbon steel, in different media including three different fresh water and one kind of salt water was investigated by means of adhesion test, water absorption test and electrochemical impedance spectroscopy. Failure of the epoxy coating in fresh water was earlier than that in salt water owing to the faster penetration rate. The failure process of the epoxy coating in fresh waters, including reverse osmosis water, conditioning water and drinking water was similar, and can be differentiated as the following three stages: the quick penetration of water, corrosion of the substrate at the interface of coating/steel and the corrosion inhibition of pigments in the coating.

Key words:  coating      fresh water      corrosion      electrochemical impedance spectroscopy     
Received:  13 January 2021     
ZTFLH:  TG174  
Corresponding Authors:  YANG Yange     E-mail:  ygyang@imr.ac.cn
About author:  YANG Yange, E-mail: ygyang@imr.ac.cn

Cite this article: 

CAO Jingyi, YANG Yange, FANG Zhigang, SHOU Haiming, LI Liang, FENG Yafei, WANG Xingqi, CHU Guangzhe, ZHAO Yi. Failure Behavior of Fresh Water Tank Coating in Different Water. Journal of Chinese Society for Corrosion and protection, 2021, 41(2): 209-218.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2021.008     OR     https://www.jcscp.org/EN/Y2021/V41/I2/209

SamplepHTDS / mg·L-1Turbidity NTUBicarbonate / mg·L-1Hardness (CaCO3) / mg·L-1Ca2+ / mg·L-1Mg2+ / mg·L-1
ROW7.725.650.15------------
CW6.62103.20.2587.8485.7021.807.49
Table 1  Properties of ROW and CW
Fig.1  Adhesion vs time of the fresh water tank coating in different water
Fig.2  Macr-morphologies of the coating after adhesion test with immersion in salt water (a) and drinking water (b) at 0 h (a1, b1), 240 h (a2, b2), 480 h (a3, b3), 720 h (a4, b4) and 1200 h (a5, b5)
Fig.3  Water adsorption curve of the coating in salt water and drinking water
Fig.4  OCP vs time of the coating in salt water (a) and drinking water (b)
Fig.5  Nyquist (a, d, g), modules (b, e, h) and phase angle (c, f, i) plots of the fresh tank coating in salt water during immersion for 0~96 h (a~c), 96~600 h (d~f) and 600~1200 h (g~i)
Fig.6  Nyquist (a, d, g), modules (b, e, h) and phase angle (c, f, i) plots of the fresh tank coating in drinking water during immersion for 0~96 h (a~c), 96~600 h (d~f) and 600~1200 h (g~i)
Fig.7  Low-frequency modules vs time of the fresh tank coating in different water
Fig.8  Adhesion vs time of the fresh water tank coating in different water
Fig.9  Macr-morphologies of the coating after adhesion test with immersion in reverse osmosis water (a) and conditioned water (b) for 0 h (a1, b1), 240 h (a2, b2), 480 h (a3, b3), 720 h (a4, b4) and 1200 h (a5, b5)
Fig.10  Water adsorption curves of the coating in different fresh water
Fig.11  OCP vs time of the coating in three different fresh water
Fig.12  Nyquist (a, d, g), modules (b, e, h) and phase angle (c, f, i) plots of the fresh tank coating in reverse osmosis water during immersion for 0~96 h (a~c), 96~600 h (d~f) and 600~1200 h (g~i)
Fig.13  Nyquist (a, d, g), modules (b, e, h) and phase angle (c, f, i) plots of the fresh tank coating in conditioned water during immersion for 0~96 h (a~c), 96~600 h (d~f) and 600~1200 h (g~i)
Fig.14  Low-frequency modules vs time of the fresh tank coating in different water for 0~96 h (a), 96~600 h (b) and 600~1200 h (c)
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