Food Spices 2,5-Dihydroxy-1,4-dithiane as an Eco-friendly Corrosion Inhibitor for X70 Steel in 0.5 mol/L H2SO4 Solution

doi:10.11902/1005.4537.2020.100

Journal of Chinese Society for Corrosion and protection

2021, Vol. 41

Issue (4): 469-476 DOI: 10.11902/1005.4537.2020.100

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Food Spices 2,5-Dihydroxy-1,4-dithiane as an Eco-friendly Corrosion Inhibitor for X70 Steel in 0.5 mol/L H₂SO₄ Solution

TAN Bochuan¹, ZHANG Shengtao¹(

), LI Wenpo¹, XIANG Bin¹, QIANG Yujie²

^1.School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China
^2.Key Laboratory of Marine Materials and Related Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

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Abstract

The corrosion inhibition performance of 2,5-Dihydroxy-1,4-dithiane (DDD) for X70 pipeline steel in 0.5 mol/L sulfuric acid solution was studied via experimental and theoretical means. Electrochemical experimental data show that DDD can effectively inhibit the corrosion of X70 steel in sulfuric acid solution. The corrosion inhibition efficiency of DDD can reach 93.6% at 298 K. In addition, DDD can still exhibit good corrosion inhibition performance at higher temperatures. The adsorption of DDD on the surface of X70 steel is consistent with Langmuir single layer adsorption. Results of quantum chemical calculation and molecular dynamics simulation also proved the above adsorption and inhibition mechanism of DDD on steel deduced from experimental results.

Key words: corrosion inhibitor food spice sulfuric acid Langmuir adsorption quantum chemistry calculation

Received: 11 June 2020

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(21878029);Chongqing Graduate Student Research Innovation Project(CYB19032);Sail Plan of Guangdong, China(2015YT02D025)

Corresponding Authors: ZHANG Shengtao E-mail: stzhangcqu@163.com

About author: ZHANG Shengtao, E-mail: stzhangcqu@163.com

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	Bochuan TAN
	Shengtao ZHANG
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	Yujie QIANG

Cite this article:

TAN Bochuan, ZHANG Shengtao, LI Wenpo, XIANG Bin, QIANG Yujie. Food Spices 2,5-Dihydroxy-1,4-dithiane as an Eco-friendly Corrosion Inhibitor for X70 Steel in 0.5 mol/L H₂SO₄ Solution. Journal of Chinese Society for Corrosion and protection, 2021, 41(4): 469-476.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2020.100 OR https://www.jcscp.org/EN/Y2021/V41/I4/469

Fig.1 Molecular structure of DDD

Fig.2 Nyquist (a) and Bode (b) plots of X70 steel immersed at 298 K in 0.5 mol/L H₂SO₄ solutions with different concentrations of DDD

Fig.3 Nyquist (a, c) and Bode (b, d) plots of X70 steel immersed at 298~313 K in 0.5 mol/L H₂SO₄ solutions with (a, b) and without (c, d) 5 mmol/L DDD

Table 1 Fitting parameters of EIS of X70 steel immersed at 298 K in 0.5 mol/L H₂SO₄ solutions without and with different concentrations of DDD

Table 2 Fitting parameters of EIS of X70 steel immersed at different temperatures in 0.5 mol/L H₂SO₄ solutions without and with different concentrations of DDD

Fig.4 Equivalent circuit diagrams for fitting EIS of X70 steel in 0.5 mol/L H₂SO₄ solutions with (a) and without (b) inductance

Fig.5 Polarization curves of X70 steel in 0.5 mol/L H₂SO₄ solutions with different concentrations of DDD at 298 K (a), with (b) and without (c) 5 mmol/L DDD at different temperatures

Table 3 Fitting parameters of polarization curves of X70 steel immersed in 0.5 mol/L H₂SO₄ solutions with different concentrations of DDD

Table 4 Fitting parameters of polarization curves of X70 steel immersed in 0.5 mol/L H₂SO₄ solution without DDD at different temperatures

Fig.6 Fitting curves of Langmuir (a), El-Awady (b), Flory-Huggins (c), Freundlich (d), Frunkin (e) and Temkin (f) isothermal adsorption models

Fig.7 SEM images of X70 steel before (a) and after immersion at 298 K for 4 h in 0.5 mol/L H₂SO₄ solution with (b) and without (c) 5 mmol/L DDD

Fig.8 Optimized configuration (a), electrostatic potential map (b), and distributions of electron clouds of HOMO (c) and LUMO (d) orbitals of DDD molecular

Fig.9 Stable adsorption configuration of DDD molecule on Fe (110) surface: (a) side view, (b) top view

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