Inhibition Effect of Soybean Meal Extract on Corrosion of Q235 Steel in Hydrochloric Acid Medium

doi:10.11902/1005.4537.2018.118

Journal of Chinese Society for Corrosion and protection

2019, Vol. 39

Issue (3): 267-273 DOI: 10.11902/1005.4537.2018.118

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Inhibition Effect of Soybean Meal Extract on Corrosion of Q235 Steel in Hydrochloric Acid Medium

Xia WANG(

),Shuaifei REN,Daixiong ZHANG,Huan JIANG,Yue GU

School of Material Science and Engineering, Southwest Petroleum University, Chengdu 610500, China

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Abstract

The inhibition effect of soybean meal extract (SME) on the corrosion of Q235 carbon steel in 1 mol/L HCl solution was investigated by weight loss method, potentiodynamic polarization curve measurement, electrochemical impedance spectroscopy and scanning electron microscope. The inhibition efficiency increased and then decreased with the increasing temperature in the range of 25~90 ℃. With a dose of 0.8 g/L SME, the inhibition efficiency was 92% at 40 ℃, and the SME acted as a mixed-type inhibitor. The adsorption of SME on Q235 steel accorded with Langmuir isothermal equation, and including chemical and physical adsorption.

Key words: soybean meal plant corrosion inhibitor Q235 steel polarization curve electrochemical impedance spectroscopy

Received: 25 August 2018

ZTFLH:

TG174.42

Fund: National Natural Science Foundation of China(51774242)

Corresponding Authors: Xia WANG E-mail: swpi_wx@126.com

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Cite this article:

Xia WANG,Shuaifei REN,Daixiong ZHANG,Huan JIANG,Yue GU. Inhibition Effect of Soybean Meal Extract on Corrosion of Q235 Steel in Hydrochloric Acid Medium. Journal of Chinese Society for Corrosion and protection, 2019, 39(3): 267-273.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2018.118 OR https://www.jcscp.org/EN/Y2019/V39/I3/267

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[1]	Raja P B, Sethuraman M G. Natural products as corrosion inhibitor for metals in corrosive media—a review [J]. Mater. Lett., 2008, 62: 113
[2]	Wang X, Ren S F, Jiang H, et al. Preparation method and research direction of plant corrosion inhibitors [J]. Surf. Technol., 2018, 47(3): 196
[2]	(王霞, 任帅飞, 蒋欢等. 植物缓蚀剂的制备方法与研究方向 [J]. 表面技术, 2018, 47(3): 196)
[3]	Deng Q, Shi H W, Ding N N, et al. Novel triazolyl bis-amino acid derivatives readily synthesized via click chemistry as potential corrosion inhibitors for mild steel in HCl [J]. Corros. Sci., 2012, 57: 220
[4]	Barouni K, Kassale A, Albourine A, et al. Amino acids as corrosion inhibitors for copper in nitric acid medium: Experimental and theoretical study [J]. J. Mater. Environ. Sci., 2014, 5: 456
[5]	Wu W M, Yang P, Du H Y, et al. Application of amino acid in metal corrosion suppression [J]. Surf. Technol., 2006, 35(6): 51
[5]	(吴伟明, 杨萍, 杜海燕等. 绿色缓蚀剂氨基酸在抑制金属腐蚀方面的应用 [J]. 表面技术, 2006, 35(6): 51)
[6]	Li X H, Deng S D, Xie X G, et al. Inhibition effect of bamboo leaf extract on the corrosion of aluminum in HCl solution [J]. Acta Phys. Chim. Sin., 2014, 30: 1883
[7]	Nasser R M. Novel green soybean oil derivatives as corrosion inhibitors for mild steel at 0.5N HCl [J]. Pet. Coal, 2017, 59: 357
[8]	Xiao Z J, Liu P H, Qin J Y, et al. Statistical optimization of medium components for enhanced acetoin production from molasses and soybean meal hydrolysate [J]. Appl. Microbiol. Biotechnol., 2007, 74: 61
[9]	Lagos L V, Stein H H. Chemical composition and amino acid digestibility of soybean meal produced in the United States, China, Argentina, Brazil, or India [J]. J. Anim. Sci., 2017, 95: 1626
[10]	Zhu Z Y, Yuan J, Ju X R, et al. Detection of soybean protein and crude fat by Fourier transform-near infrared spectroscopy [J]. J. Food Saf. Qual., 2015, 6: 4924
[10]	(朱贞映, 袁建, 鞠兴荣等. 傅立叶变换近红外光谱在大豆蛋白质和粗脂肪检测中的研究 [J]. 食品安全质量检测学报, 2015, 6: 4924)
[11]	Baianu I C, You T F, Guo J, Nelson R L, et al. Determination of isoflavone contents for selected soybean lines by Fourier transform near infrared reflectance spectroscopy [J]. Nat. Preced., 2011, doi: 10.1038/npre.2011.6194.1
[12]	Ahn M S, Jie E Y, Song S Y, et al. Simultaneous estimation of saponin contents from soybean seed using Fourier transform infrared spectroscopy and high-performance liquid chromatography analysis [J]. Plant Biotechnol. Rep., 2016, 10: 403
[13]	Wolfenden R, Lewis Jr C A, Yuan Y, et al. Temperature dependence of amino acid hydrophobicities [J]. Proc. Natl. Acad. Sci. U. S. A.,2015, 112: 7484
[14]	Ahamad I, Quraishi M A. Mebendazole: New and efficient corrosion inhibitor for mild steel in acid medium [J]. Corros. Sci., 2010, 52: 651
[15]	Jokar M, Farahani T S, Ramezanzadeh B. Electrochemical and surface characterizations of morus alba pendula leaves extract (maple) as a green corrosion inhibitor for steel in 1 M HCl [J]. J. Taiwan Inst. Chem. Eng., 2016, 63: 436
[16]	Hu Q, Qiu Y B, Zhang G A, et al. Capsella bursa-pastoris extract as an eco-friendly inhibitor on the corrosion of Q235 carbon steels in 1 mol·L-1 hydrochloric acid [J]. Chin. J. Chem. Eng., 2015, 23: 1408
[17]	Fouda A S, El-Awady G Y, El Behairy W T. Prosopis juliflora plant extract as potential corrosion inhibitor for low-carbon steel in 1 M HCl solution [J]. J. Bio. Tribo. Corros., 2018, 4: 8
[18]	Verma C, Quraishi M A, Singh A. A thermodynamical, electrochemical, theoretical and surface investigation of diheteroaryl thioethers as effective corrosion inhibitors for mild steel in 1 M HCl [J]. J. Taiwan Inst. Chem. Eng., 2016, 58: 127
[19]	Li X X, Yang W Z. Inhibition of 1-propyl-2-methyl-3-alkyl benzimidazole on Q235 steel in HCl solution [J]. J. Chin. Soc. Corros. Prot., 2012, 32: 168
[19]	(李相旭, 杨文忠. 盐酸介质中1-丙基-2-甲基-3-烷基苯并咪唑盐对Q235钢的缓蚀作用 [J]. 中国腐蚀与防护学报, 2012, 32: 168)
[20]	Hu Q. Study on natural plants’ extracts as eco-friendly corrosion inhibitors [D]. Wuhan: Huazhong University of Science and Technology, 2014
[20]	(胡琴. 天然植物型缓蚀剂的研究 [D]. 武汉: 华中科技大学, 2014)
[21]	Li X H, Deng S D, Fu H, et al. Synergistic inhibition effects of bamboo leaf extract/major components and iodide ion on the corrosion of steel in H3PO4 solution [J]. Corros. Sci., 2014, 78: 29
[22]	Cao C N. Principles of Electrochemistry of Corrosion [M]. 3rd Ed. Beijing: Chemical Industry Press, 2008
[22]	(曹楚南. 腐蚀电化学原理 [M]. 第3版. 北京: 化学工业出版社, 2008)
[23]	Da Rocha J C, Da Cunha Ponciano Gomes J A, D'Elia E. Corrosion inhibition of carbon steel in hydrochloric acid solution by fruit peel aqueous extracts [J]. Corros. Sci., 2010, 52: 2341
[24]	Chen W, Guan C P, Yang S M, et al. Corrosion inhibition of equisetum ramosissimum extractive for carbon steel in hydrochloric acid solution [J]. J. Chin. Soc. Corros. Prot., 2016, 36: 177
[24]	(陈文, 管春平, 杨申明等. 节节草提取物在盐酸介质中对碳钢的缓蚀行为研究 [J]. 中国腐蚀与防护学报, 2016, 36: 177)

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