冷喷涂<strong>B<sub>4</sub>C/Al</strong>复合涂层在硼酸溶液中的腐蚀行为

doi:10.11902/1005.4537.2024.244

中国腐蚀与防护学报

2025, Vol. 45

Issue (1): 164-172 CSTR: 32134.14.1005.4537.2024.244 DOI: 10.11902/1005.4537.2024.244

研究报告

本期目录 | 过刊浏览

冷喷涂B₄C/Al复合涂层在硼酸溶液中的腐蚀行为

赵立佳¹^,², 崔新宇¹, 王吉强¹(

), 熊天英¹

1 中国科学院金属研究所师昌绪先进材料创新中心沈阳 110016
2 中国科学技术大学材料科学与工程学院沈阳 110016

Corrosion Behavior of Cold-sprayed B₄C/Al Composite Coating in Boric Acid Solution

ZHAO Lijia¹^,², CUI Xinyu¹, WANG Jiqiang¹(

), XIONG Tianying¹

1 Shi -changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
2 School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China

引用本文:

赵立佳, 崔新宇, 王吉强, 熊天英. 冷喷涂B₄C/Al复合涂层在硼酸溶液中的腐蚀行为[J]. 中国腐蚀与防护学报, 2025, 45(1): 164-172.
Lijia ZHAO, Xinyu CUI, Jiqiang WANG, Tianying XIONG. Corrosion Behavior of Cold-sprayed B₄C/Al Composite Coating in Boric Acid Solution[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(1): 164-172.

全文: PDF(15456 KB) HTML

摘要:

采用浸泡和电化学实验，研究了冷喷涂B₄C/Al复合涂层在硼酸溶液中的腐蚀行为。结果表明，冷喷涂涂层内颗粒间界面的结合弱，硼酸溶液倾向于沿着颗粒间的界面优先发生腐蚀，进而腐蚀涂层内部。后热处理可以有效改善冷喷涂B₄C/Al涂层的组织，增强颗粒间的界面结合，进而提升其在硼酸溶液中的耐腐蚀性能。

关键词 ：冷喷涂, B₄C/Al, 耐腐蚀性能, 热处理

Abstract：

Due to the excellent neutron absorption properties, cold-sprayed B₄C/Al composite coating shows a good application prospect in the field of spent fuel storage. However, there are few studies on the corrosion behavior of cold-sprayed B₄C/Al coating in boric acid solution. In this paper, the corrosion behavior of cold-sprayed B₄C/Al coating coated 316L stainless steel in boric acid solution was studied by immersion test, electrochemical workstation, and EIS as well as SEM + EDS and XRD. Results show that the interface between B₄C particles in the cold-sprayed coating is weak, and the boric acid solution tend to preferentially corrode along the interparticle interface, thus results in the corrosion of the coating matrix. Post heat treatment can effectively improve the structure of cold sprayed B₄C/Al coating and enhanced interfacial bonding between particles. As a result, the corrosion resistance of B₄C/Al coating in boric acid solution was improved.

Key words： cold spray B₄C/Al corrosion resistance heat treatment

收稿日期: 2024-08-07 32134.14.1005.4537.2024.244

ZTFLH:

TG174

基金资助:中国科学院青年创新促进会项目(2023199)

通讯作者: 王吉强，E-mail：jqwang11s@imr.ac.cn，研究方向为冷喷涂技术

Corresponding author: WANG Jiqiang, E-mail: jqwang11s@imr.ac.cn

作者简介: 赵立佳，男，1997年生，博士生

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	赵立佳
	崔新宇
	王吉强
	熊天英
44.8K

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2024.244 或 https://www.jcscp.org/CN/Y2025/V45/I1/164

图1 B4C/Al涂层在硼酸溶液中浸泡不同时间后的宏观形貌

图2 涂层浸泡前以及经768 h浸泡后的XRD谱图

图3 B4C/Al涂层在硼酸溶液中浸泡不同时间后的微观形貌

图4 经768 h浸泡的涂层表面腐蚀坑的截面背反射电子像及其局部放大图，腐蚀坑的截面二次电子图像，图4中区域1和区域2处的元素百分比

图5 冷喷涂B4C/Al涂层在硼酸溶液中浸泡不同时间后的失重曲线

图6 B4C/Al涂层在硼酸溶液中的腐蚀过程示意图

图7 喷涂态及热处理后B4C/Al涂层的晶粒尺寸以及位错密度分布图

图8 喷涂态及热处理态试样的极化曲线和阻抗谱

表1 冷喷涂态和热处理试样的腐蚀电位和腐蚀电流密度

图9 拟合Nyquist曲线的等效电路图

表2 冷喷涂和热处理试样的等效电路图中各元件拟合数据

1	Wang D B, Wu J, Cui J P, et al. Long-term corrosion evolution associated with the structural heterogeneities of an Fe-based amorphous coating in H₃BO₃ solution at various temperatures [J]. J. Mater. Sci. Technol., 2023, 140: 233
2	Fu X L, Ji Z B, Lin W, et al. The advancement of neutron shielding materials for the storage of spent nuclear fuel [J]. Sci. Technol. Nucl. Install., 2021, 2021: 5541047
3	Chen Y S. Thermal analysis for the integrated spent fuel pool of the Chinshan plant in the decommissioning process [J]. Ann. Nucl. Energy, 2018, 119: 163
4	Ghayebloo M, Mostaedi M T, Rad H F. A review of recent studies of fabrication of Al-B₄C composite sheets used in nuclear metal casks [J]. Trans. Indian Inst. Met., 2022, 75: 2477
5	Chen H S, Wang W X, Nie H H, et al. Research progress and development of neutron-absorbing materials for nuclear shielding [J]. Rare Met. Mater. Eng., 2020, 49: 4358
5	陈洪胜, 王文先, 聂慧慧等. 核屏蔽用中子吸收材料研究现状与展望 [J]. 稀有金属材料与工程, 2020, 49: 4358
6	Tariq N H, Gyansah L, Wang J Q, et al. Cold spray additive manufacturing: a viable strategy to fabricate thick B₄C/Al composite coatings for neutron shielding applications [J]. Surf. Coat. Technol., 2018, 339: 224
7	He L W, Hassani M. A review of the mechanical and tribological behavior of cold spray metal matrix composites [J]. J. Therm. Spray Technol., 2020, 29: 1565
8	Wang J Q, Cui X Y, Xiong T Y. Research progress of cold sprayed metal matrix composite coatings and materials [J]. China Surf. Eng., 2020, 33(4): 51
8	王吉强, 崔新宇, 熊天英. 冷喷涂金属基复合涂层及材料研究进展 [J]. 中国表面工程, 2020, 33(4): 51
9	Zhao L J, Peng Y H, Li Z, et al. A novel B₄C/Al-316 L neutron absorbing clad plate prepared by cold spraying: microstructure and mechanical properties [J]. Mater. Today Commun., 2024, 38: 108098
10	Li B, Shao L L. Appraisal of alumina and aluminium hydroxide by XRD [J]. Inorg. Chem. Ind., 2008, 40(2): 54
10	李波, 邵玲玲. 氧化铝、氢氧化铝的XRD鉴定 [J]. 无机盐工业, 2008, 40(2): 54
11	Wang X, Jiang X S, Sun H L, et al. Corrosion behaviour of bioinspired laminated Al matrix composite hybrid reinforced with B₄C and graphene nanoplatelets [J]. Corros. Eng. Sci. Technol., 2023, 58: 270
12	Ren Y P, Tariq N U H, Liu H H, et al. Unraveling the effects of hot rolling on microstructure and mechanical properties of cold sprayed Mg/Al clad plates [J]. Mater. Today Commun., 2022, 33: 104553
13	Li Y L, Wang W X, Chen H S, et al. Corrosion behavior of B₄C/6061Al neutron absorber composite in different H₃BO₃ concentration solutions [J]. Acta Metall. Sin. (Engl. Lett.), 2016, 29: 1037
14	Lin J X, Ran G, Lei P H, et al. Microstructure analysis of neutron absorber Al/B₄C metal matrix composites [J]. Metals, 2017, 7: 567
15	Wang Y Y, Normand B, Mary N, et al. Microstructure and corrosion behavior of cold sprayed SiC_p/Al 5056 composite coatings [J]. Surf. Coat. Technol., 2014, 251: 264
16	Zhou Y T, Zan Y N, Wei X X, et al. Corrosion onset associated with the reinforcement and secondary phases in B₄C-6061Al neutron absorber material in H₃BO₃ solution [J]. Corros. Sci., 2019, 153: 74 doi: 10.1016/j.corsci.2019.03.042
17	Zhou Y T, Zan Y N, Wang Q Z, et al. Grain boundary segregation of alloying Cu induced intergranular corrosion of B₄C-6061Al composite [J]. Mater. Charact., 2021, 173: 110930
18	Wang Y Y, Normand B, Mary N, et al. Effects of ceramic particle size on microstructure and the corrosion behavior of cold sprayed SiC_p/Al 5056 composite coatings [J]. Surf. Coat. Technol., 2017, 315: 314
19	Bai X M, Tang J Q, Gong J M, et al. Corrosion performance of Al-Al₂O₃ cold sprayed coatings on mild carbon steel pipe under thermal insulation [J]. Chin. J. Chem. Eng., 2017, 25: 533
20	Zhao L J, Zhou D, Xie G W, et al. Unraveling the influence of Al particle size on microstructure and tribological properties of cold sprayed Al/B₄C composite coatings [J]. Mater. Today Commun., 2023, 34: 105257
21	Bai Q, Zhang L L, Ke L, et al. The effects of surface chemical treatment on the corrosion behavior of an Al-B₄C metal matrix composite in boric acid solutions at different temperatures [J]. Corros. Sci., 2020, 164: 108356
22	Qin J, Li Z, Ma M Y, et al. Diversity of intergranular corrosion and stress corrosion cracking for 5083 Al alloy with different grain sizes [J]. Trans. Nonferrous Met. Soc. China, 2022, 32: 765

[1]	梁玉伟, 王婕, 宋鹏, 黄太红, 包宇旭. FeCrMoSiB非晶涂层的耐磨耐蚀性能研究[J]. 中国腐蚀与防护学报, 2025, 45(1): 191-200.
[2]	林一, 刘涛, 郭彦兵, 阮晴, 郭章伟, 董丽华. 船用低温钢焊接材料的研发与腐蚀方法评价[J]. 中国腐蚀与防护学报, 2024, 44(4): 957-964.
[3]	耿真真, 张钰柱, 杜小将, 吴汉辉. S^2- 和Cl^- 对316L奥氏体不锈钢的腐蚀钝化行为的协同作用[J]. 中国腐蚀与防护学报, 2024, 44(3): 797-806.
[4]	谢云, 刘婷, 王雯, 周佳琳, 唐颂. 微观组织对一种超轻高强镁锂合金耐蚀性的影响[J]. 中国腐蚀与防护学报, 2024, 44(1): 255-260.
[5]	蒋光锐, 刘广会, 商婷. 热处理对ZnAlMg镀层组织与耐腐蚀性能的影响[J]. 中国腐蚀与防护学报, 2024, 44(1): 246-254.
[6]	商婷, 蒋光锐, 刘广会, 秦汉成. 热处理对Zn-6%Al-3%Mg镀层微观组织与耐蚀性的影响[J]. 中国腐蚀与防护学报, 2023, 43(6): 1413-1418.
[7]	商强, 满成, 逄昆, 崔中雨, 董超芳, 崔洪芝. 后热处理对不同含碳量SLM-316L不锈钢晶间腐蚀行为的作用机制研究[J]. 中国腐蚀与防护学报, 2023, 43(6): 1273-1283.
[8]	丁立, 邹文杰, 张雪姣, 陈均. ADC12铝合金表面硅锆复合转化膜的研究[J]. 中国腐蚀与防护学报, 2023, 43(4): 903-910.
[9]	夏晓健, 万芯媛, 陈云翔, 韩纪层, 陈奕扬, 严康骅, 林德源, 陈天鹏, 左晓梅, 孙宝壮, 程学群. 两种热处理工艺对3Cr钢腐蚀行为影响及机理研究[J]. 中国腐蚀与防护学报, 2023, 43(3): 656-662.
[10]	梁超雄, 梁小红, 韩培德. 新热处理工艺调控B元素分布对S31254超级奥氏体不锈钢第二相析出和耐蚀性能的影响[J]. 中国腐蚀与防护学报, 2023, 43(3): 639-646.
[11]	胡雄鑫, 张弦, 刘静, 吴开明, 林安. 无取向电工钢用磷酸盐系绝缘环保涂层的研制及性能研究[J]. 中国腐蚀与防护学报, 2022, 42(5): 805-812.
[12]	潘鑫, 任泽, 连景宝, 何川, 郑平, 陈旭. 热处理工艺对超级13Cr不锈钢在饱和CO₂油田地层水中腐蚀行为影响[J]. 中国腐蚀与防护学报, 2022, 42(5): 752-758.
[13]	李玲, 杜汐然, 曲品权, 李建呈, 王金龙, 古岩, 张甲, 陈明辉, 王福会. 真空热处理对多弧离子镀NiCoCrAlY涂层高温氧化行为的影响[J]. 中国腐蚀与防护学报, 2022, 42(2): 243-248.
[14]	张赪栋, 刘斌, 石泽耀, 刘岩, 曹青敏, 蹇冬辉. 镍铝青铜合金海水腐蚀行为研究进展[J]. 中国腐蚀与防护学报, 2022, 42(1): 25-33.
[15]	孙宝壮, 周霄骋, 李晓荣, 孙玮潞, 刘子瑞, 王玉花, 胡洋, 刘智勇. 不同组织的316L不锈钢在NH₄Cl环境下应力腐蚀行为与机理[J]. 中国腐蚀与防护学报, 2021, 41(6): 811-818.

Viewed

Full text

Abstract

Cited

Shared

Discussed