<strong>FeCrMoSiB</strong>非晶涂层的耐磨耐蚀性能研究

doi:10.11902/1005.4537.2024.265

中国腐蚀与防护学报

2025, Vol. 45

Issue (1): 191-200 CSTR: 32134.14.1005.4537.2024.265 DOI: 10.11902/1005.4537.2024.265

研究报告

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FeCrMoSiB非晶涂层的耐磨耐蚀性能研究

梁玉伟¹^,²^,³, 王婕¹^,²^,³, 宋鹏¹^,²^,³^,⁴(

), 黄太红¹, 包宇旭⁵

1 昆明理工大学材料科学与工程学院昆明 650093
2 昆明理工大学先进金属凝固成形技术与装备国家地方联合工程研究中心昆明 650093
3 云南省内燃机清洁排放技术国际联合研究开发中心昆明 650093
4 昆明理工大学民航与航空学院昆明 650500
5 云南锡业新材料有限公司昆明 650500

Wear and Corrosion Resistance of FeCrMoSiB Amorphous Coating

LIANG Yuwei¹^,²^,³, WANG Jie¹^,²^,³, SONG Peng¹^,²^,³^,⁴(

), HUANG Taihong¹, BAO Yuxu⁵

1 Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China
2 National-Local Joint Engineering Research Center for Technology of Advanced Metallic Solidification Forming and Equiment, Kunming University of Science and Technology, Kunming 650093, China
3 Yunnan Provincial International Joint Research and Development Center for Clean Emission Technology of Internal Combustion Engine, Kunming 650093, China
4 Faculty of Civil Aviation and Aeronautics, Kunming University of Science and Technology, Kunming 650500, China
5 Yunnan Tin New Materials Co., Ltd., Kunming 650500, China

引用本文:

梁玉伟, 王婕, 宋鹏, 黄太红, 包宇旭. FeCrMoSiB非晶涂层的耐磨耐蚀性能研究[J]. 中国腐蚀与防护学报, 2025, 45(1): 191-200.
Yuwei LIANG, Jie WANG, Peng SONG, Taihong HUANG, Yuxu BAO. Wear and Corrosion Resistance of FeCrMoSiB Amorphous Coating[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(1): 191-200.

全文: PDF(15051 KB) HTML

摘要:

利用超音速火焰喷涂制备FeCrMoBSi非晶涂层，探究了不同热处理温度对涂层微观结构及腐蚀磨损性能的影响，研究结果显示，未经热处理的非晶涂层展现出了优异的抗腐蚀性能，其孔隙率最低(2.45%)并且涂层中Cr₂O₃含量最高(76.51%)，能够有效地保护基体。热处理后的涂层孔隙增大，裂纹拓展，为腐蚀溶液提供了扩散通道，降低了涂层的抗腐蚀能力。涂层摩擦磨损测试结果表明未经热处理的非晶涂层具有最小的磨损体积和最低的磨损率(1.784 × 10^-5 mm³/(N·m))，但随热处理温度的升高，磨损体积和磨损率均增加。

关键词 ：非晶涂层, 热处理, 腐蚀性能, 磨损性能

Abstract：

Herein, An amorphous coating of FeCrMoBSi (namely Fe-18%-20%Cr, 7%-8%Mo, 5%-6%Si and 4%-5%B, in mass fraction) on 310S stainless steel was prepared by high velocity oxy-fuel (HVOF) spraying technique. The corrosion resistance in 3.5%NaCl solution and friction-wear performance before and after heat treatment, as well as the effect of heat treatment on the crystallization behavior for the as prepared amorphous coating were studied. The results indicated that the amorphous coating exhibited excellent corrosion resistance in 3.5%NaCl solution, characterized by the low porosity (2.45%) and the high Cr₂O₃ content (76.51%) in the as prepared coating, which can effectively protect the substrate. However, after being post heat-treated, numerous pores and cracks emerged in the coating, which can act as short-circuit diffusion channel for the corrosive media, leading to poor corrosion resistance. Results of friction- and wear-testing indicated that the as prepared amorphous coating exhibited the lowest wear volume and wear rate (1.784 × 10^-5 mm³/(N·m)). Although, for the post heat-treated coatings, the wear volume and wear rate increase slightly with the increasing heat treatment temperature.

Key words： amorphous coating heat treatment corrosion performance wear performance

收稿日期: 2024-08-21 32134.14.1005.4537.2024.265

ZTFLH:

TG174

基金资助:云南省重点研发计划(202303AP140016);重大科技专项(202302AG050006)

通讯作者: 宋鹏，E-mail：songpeng@kust.edu.cn，研究方向为金属材料加工

Corresponding author: SONG Peng, E-mail: songpeng@kust.edu.cn

作者简介: 梁玉伟，女，1996年生，博士生

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图1 涂层制备及性能表征

图2 Fe-Cr-Mo-Si-B非晶粉末形貌及在310S不锈钢上所制备涂层的截面形貌

图3 Fe-Cr-Mo-Si-B非晶粉末以及喷涂态和热处理态涂层的XRD谱图

图4 摩擦系数、截面磨痕深度和磨损率曲线

图5 室温下涂层样品磨损轨迹的三维白光干涉图

图6 涂层表面磨损轨迹的SEM图

表1 图6中标记点处EDS成分分析结果

图7 原始与热处理涂层在3.5%NaCl溶液中的Tafel极化曲线

图8 原始与热处理涂层的EIS及其对应的等效电路图

表2 等效电路中各参数的拟合值

图9 4种涂层样品腐蚀后表面的SEM形貌

图10 4种涂层样品的XPS图及钝化膜的化学元素的比较

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