壳聚糖及其衍生物的制备与缓蚀性能的研究进展

doi:10.11902/1005.4537.2017.142

中国腐蚀与防护学报

2018, Vol. 38

Issue (5): 409-414 DOI: 10.11902/1005.4537.2017.142

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壳聚糖及其衍生物的制备与缓蚀性能的研究进展

孔佩佩, 陈娜丽(

), 白德忠, 王跃毅, 卢勇, 冯辉霞(

)

兰州理工大学石油化工学院兰州 730050

Research Progress on Preparation and Corrosion Inhibition Performance of Chitosan Derivatives

Peipei KONG, Nali CHEN(

), Dezhong BAI, Yueyi WANG, Yong LU, Huixia FENG(

)

College of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China

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摘要:

壳聚糖作为一种天然高分子产物,其分子中的大量游离氨基和羟基,使得壳聚糖在防腐蚀领域引起了人们诸多关注。本文综述了壳聚糖改性以及壳聚糖及其衍生物的缓蚀行为研究进展,展望了壳聚糖及其衍生物在缓蚀剂领域的发展趋势。

关键词 ：壳聚糖, 腐蚀, 绿色, 应用, 缓蚀剂

Abstract：

Chitosan as a natural green polymer, which bears rich hydroxyl and free amino groups, so has attracted more and more attention in the field of anti-corrosion. In this paper, the research progress of chitosan modification, chitosan and its derivatives, as well as their application as a green corrosion inhibitor are reviewed. The developing tendencies of chitosan derivatives inhibitors are prospected.

Key words： chitosan corrosion green application inhibition

收稿日期: 2017-08-27

ZTFLH:

TG174.42

基金资助:国家自然科学基金 (51063003和201664009),甘肃省自然科学基金 (1208RJZA173) 及国家级大学生创新创业训练计划 (201410731009)

作者简介:

作者简介孔佩佩,男,1992年生,硕士生

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引用本文:

孔佩佩, 陈娜丽, 白德忠, 王跃毅, 卢勇, 冯辉霞. 壳聚糖及其衍生物的制备与缓蚀性能的研究进展[J]. 中国腐蚀与防护学报, 2018, 38(5): 409-414.
Peipei KONG, Nali CHEN, Dezhong BAI, Yueyi WANG, Yong LU, Huixia FENG. Research Progress on Preparation and Corrosion Inhibition Performance of Chitosan Derivatives. Journal of Chinese Society for Corrosion and protection, 2018, 38(5): 409-414.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2017.142 或 https://www.jcscp.org/CN/Y2018/V38/I5/409

图1 壳聚糖在Cu表面的吸附模型[19]

图2 壳聚糖磷酸酯分子式[26,27]

图3 HTACC的合成示意图[29]

图4 TSFCS和TCFCS的合成路线图[31]

图5 CTS-PANI,HPCS-PANI和CMC-PANI的分子结构式[34]

图6 TEPA-Ch的合成示意图[36]

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