交变电场对不锈钢钝性和钝化膜性质的影响

中国腐蚀与防护学报

2002, Vol. 22

Issue (6): 375-379

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交变电场对不锈钢钝性和钝化膜性质的影响

李运超;严川伟;段红平

中科院金属所金属腐蚀与防护国家重点实验室

EFFECT OF ALTERNATING VOLTAGE MODULATIONON THE PASSIVITY AND THE FEATURE OFPASSIVE FILM OF STAINLESS STEELS

Yunchao Li;Chuanwei Yan;Hongping Duan

中科院金属所金属腐蚀与防护国家重点实验室

全文: PDF(196 KB)

摘要: 总结了交变电场对不锈钢自腐蚀电位、钝性和钝化膜性质的影响，概述了交变电场下钝化膜的生长机制。不锈钢载波钝化与彩色钝化的结果表明，控制在适当的参数条件下的交变电场对不锈钢钝化膜的综合性能有较大幅度的提高，显示了该领域的研究价值。

关键词 ：不锈钢, 钝化膜, 交变电场

Abstract：The effect of alternating voltage electric fiel d on the corrosion potential,the passivity and the features of passive film of s tainless steels is reviewed,and the results show that AV usually destroys passiv e film,decreases the passive potential region and causes a shift in the corrosio n poten tial.However,some experimental results have evidenced that the overall propertie s of the passive film of stainless steels formation under alternating voltage elec tric field controlled by adequate parameters(i.e.,alternating voltage modulation ) are enhanced by a large scale,such as increasing the stability,the breakdown p otential(Eb) and the resistance against cathodic reductive dissolution of the passive film.The mechanism of passive film formation under alternating v oltage (AV) modulation condition is also summarized in this paper.These indicate there is particular research value in this field.

Key words： stainless steel passive film alternating volta ge (AV) modulation

收稿日期: 2001-07-02

ZTFLH:

TG174

通讯作者: 李运超

Corresponding author: Yunchao Li

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引用本文:

李运超; 严川伟; 段红平 . 交变电场对不锈钢钝性和钝化膜性质的影响[J]. 中国腐蚀与防护学报, 2002, 22(6): 375-379 .
Yunchao Li, Chuanwei Yan, Hongping Duan. EFFECT OF ALTERNATING VOLTAGE MODULATIONON THE PASSIVITY AND THE FEATURE OFPASSIVE FILM OF STAINLESS STEELS. J Chin Soc Corr Pro, 2002, 22(6): 375-379 .

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y2002/V22/I6/375

[1]JWendtJL ,ChinDT .TheA .C .corrosionofstainlesssteel—I .ThebreakdownofpassivityofSS304inneutralaqueoussolutions[J].Corros.Sci.,1985,25(10):889-900
[2]WendtJL ,ChinDT .TheA .C .corrosionofstainlesssteel—II .Thepolarizati膜组成及稳定性的影响[J].中国腐蚀与防护学报,1992,12(1):CorrosionSci.,1985,25(10):901-915
[3]ChinDT ,VenkateshS .Astudyofalternatingvoltagemodulationonthepolarizationofmildsteel[J].J.Electrochem.Soc.,1979,126(11):1908-1913
[4]CaoCN ,ChangXY .ImprovingthestabilityofpassivefilmsonstainlesssteelsbyAVpassivation[J].CorrosionScience&Protec tionTechnology,1990,2(2):20-21
[5]SongGL ,CaoCN .EffectofalternatingvoltagemodulationonthefeaturesofthepassivefilmonSS321[J].J.ChineseSocietyforCorrosionandProtection,1991,11(4):319-326(宋光铃,曹楚南.交变电场对不锈钢钝化膜性质的影响[J].中国腐蚀与防护学报,1991,11(4):319-326)
[6]FunjimotoS ,ShibataT .TheelectrochemicalconditionsforcoloredfilmformationonSS304withsquarewavepolarization[J].Corros.Sci.,1993,35(1):147-152
[7]JiaFL ,GuoZH ,LiZM .Colorationofstainlesssteelbysquare-wavecurrentoflowfrequency[J].Corrosion&Protection,2001,22(3):105-108(贾法龙,郭稚弧,李卓民.低频方波电流进行不锈钢电解着色的研究[J].腐蚀与防护2001,22(3):105-108)
[8]ZhangJX ,ChenJ ,QiaoYN ,etal.ColoredpassivefilmonSS304[J].J.ChineseSocietyforCorrosionandProtection,1998,18(4):311-315(张均喜,陈健,乔亦男等.载波钝化电场条件对不锈钢着色膜的影响[J].中国腐蚀与防护学报,1998,18(4):311-315)
[9]ZhangJX ,ChenJ,QiaoYN ,etal.GrowthmechanismofcoloredpassivefilmformedonSS304[J].J.ChineseSocietyforCorrosionandProtection,1999,19(3):167-172(张均喜,陈健,乔亦男等.不锈钢载波钝化着色膜的形成机理研究[J].中国腐蚀与防护学报,1999,19(3):167-172)
[10]CaoCN ,WangJ ,LinHC .FeatureofA .Cimpedanceofpittingcorrodedelectrodesduringpitspropagation[J].J.ChineseSocietyforCorrosionandProtection,1989,9(4):261-269(曹楚南,王佳,林海潮.孔蚀发展期的电极阻抗频谱特征[J].中国腐蚀与防护学报,1989,9(4):261-269)
[11]SongGL ,CaoCN ,LinHC .EffectsofA .Vpassivationandpost-treatmentonthecompositionandstabilityofpassivefilmonstainlesssteels[J].J .ChineseSocietyforCorrosionandProtection,1992,12(1):77-82(宋光铃,曹楚南,林海潮.载波钝化及其后处理对不锈钢钝化膜组成及稳定性的影响[J].中国腐蚀与防护学报,1992,12(1):77-82)
[12]CzachorMJ.AESinvestigationsofpassivefilmsonironandironbasealloy[J].Corrosion,1979,35(8):360-366
[13]PaolaAD ,QuartoFD ,SunseriCA .Photoelectrochemicalcharac terizationofpassivefilmsonstainlesssteels[J].Corros.Sci.,1986,26:935-948
[14]BroocksAR ,ClaytonCR ,DossK ,LuYC .OntheroleofCrinthepassivityofstainlesssteel[J].J .Electrochem.Soc.,1986,133:2459-2463
[15]CleslakWR ,DuquettDJ.PropertiesofthepassivefilmsformedonferriticstainlesssteelinCl- solution[J].Corros.Sci.,1984,40(10):545-550
[16]CahanBD ,ChenCT .Thenatureofpassivefilmoniron—Ⅲ.Thechemi-conductormodelandfurthersupportingevidence[J].J .Electrochem.Soc.,1982,129(5):921-925
[17]HuRG ,LinCJ .XPS/SERSstudyfortheelectrochemicalmodi fiedpassivefilmon188-stainlesssteel[J].J.ChineseSocietyforCorrosionandProtection,2000,20(3):149-153(胡融刚,林昌健..电化学改性不锈钢钝化膜的XPS/SERS研究[J].中国腐蚀与防护学报,2000,20(3):149-153)
[18]SatoNorio.ThePassivityofMetalsandPassiveFilms[M].Prince tonNJ :TheElectrochem.Soc.Inc.,1978,29
[19]PanCS .StudyofthepropertiesofpassivefilmonstainlesssteelsformedunderA .V .electricfield[D].MSdegreethesisofICPM ,1990(潘春生.交变电场作用下不锈钢钝化膜性能的研究[D].中国科学院金属腐蚀与防护研究所硕士论文,1989)
[20]SunseeriC ,PiazzaS ,PaolandAD ,QuartoDA .Photocurrentspec troscopicinvestigationofpassivefilmsonferriticstainlesssteel[J].J.Electrochem.Soc.,1987,134:2410-2416
[21]BurleighTD ,LatanisionRM .Theuseofphotocurrentstocharac terizationanodicfilmspassiveonTi,Zn,CuandSS 304[J].J .Electrochem.Soc.,1987,134:135-141
[22]PaolaAD ,ShuklaD ,StimmingU .Photoelectrochemicalstudyofpassivefilmsonstainlesssteelsinneutralsolution[J].Electro chemicalActa,1991,136:345-351
[23]FunjimotoS ,NakatsuH .Extraordinarythickpassivefilmforma tiononNi-Cralloywithsquarewavepotentialpulsepolarization[J].Corros.Sci.,1996,38:1473-1483
[24]SongGL .StudyoftheeffectofA .V .modulatedpassivationforstainlesssteels[D].MSdegreethesisofICPM ,1990(宋光铃.不锈钢载波钝化的研究[D].中国科学院金属腐蚀与防护研究所硕士论文,1990)

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