Please wait a minute...
Just Accepted | Current Issue | Archive | Featured Articles | Special Issue | Most Read | Most Downloaded | Most Cited
Journal of Chinese Society for Corrosion and protection  2016, Vol. 36 Issue (3): 253-259    DOI: 10.11902/1005.4537.2015.128
Orginal Article Current Issue | Archive | Adv Search |
Corrosion Behavior of Low Alloy Steels in High-mineralized Mine Water
Junyan PAN1,Huahui CHEN1(),Feng MA1,Bo XIE2,Yingfei WU1,Fu ZHAO1,Zuowei ZHANG1
1. Department of Materials Science and Engineering, School of Mechanical Electronic and Information Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China
2. Management Center of Synthesizing Mining Equipment, Yanzhou Co., LTD., Yanzhou 272100, China
Download:  HTML  PDF(4034KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

The corrosion behavior of low alloy steels, such as 27SiMn, 30CrMnSi, 30CrMnTi, 40Cr and Q550 was studied comparatively in high-mineralized coal mine water, tap water and NaCl solution by means of immersion test, salt spray test and electrochemical methods as well as XRD and SEM with EDS. The results showed that elements Cr and Si can significantly affect the corrosion resistance of low alloy steels: in chloride containing media, Si exhibits stronger effect than Cr on the corrosion; whereas in the presence of oxygen (water and gas phase), Cr exhibits stronger effect than Si. Therefore, 30CrMnTi and 40Cr have better corrosion resistance in the coal mine water. The corrosion behavior of the low alloy steels in the coal mine water depend not only on the role of alloying elements but also on the compactness of the formed limescale induced by mineral ions. The limescale, on one hand, can fill the porous rust layer, which slows down the corrosion rate of the steel, however, on the other hand, due to the low concentration of oxygen at the zone below the limescale, where the corrosion of the steel can be accelerated. Finally the corrosivity of three corrosive media can be ranked as the order from severe to mild: 3.5%NaCl solution, high mineralized mine water and tap water.
Key words:  low alloy steel      mine water      corrosion     
Received:  22 July 2015     
Service
E-mail this article
Add to citation manager
E-mail Alert
RSS
（）
Articles by authors
Junyan PAN
Huahui CHEN
Feng MA
Bo XIE
Yingfei WU
Fu ZHAO
Zuowei ZHANG

Cite this article: 

Junyan PAN,Huahui CHEN,Feng MA,Bo XIE,Yingfei WU,Fu ZHAO,Zuowei ZHANG. Corrosion Behavior of Low Alloy Steels in High-mineralized Mine Water. Journal of Chinese Society for Corrosion and protection, 2016, 36(3): 253-259.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2015.128     OR     https://www.jcscp.org/EN/Y2016/V36/I3/253

Steel C Si Mn Mo Cr B Ti Fe
27SiMn 0.24~0.34 1.10~1.40 1.10~1.40 --- --- --- --- Bal.
30CrMnSi 0.27~0.34 0.90~1.20 0.80~1.10 --- 0.80~1.10 --- --- Bal.
30CrMnTi 0.27~0.34 0.19~0.37 0.80~1.10 --- 1.00~1.30 --- 0.04~1.10 Bal.
40Cr 0.37~0.44 0.17~0.37 0.50~0.80 --- 0.80~1.10 --- --- Bal.
Q550 ≤0.18 ≤0.55 1.00~1.60 ≤0.40 ≤0.40 ≤0.003 --- Bal.
Table 1  Chemical compositions of tested steels (mass fraction / %)
Fig.1  Calculated atmospheric corrosion rate of tested steels
Fig.2  Corrosion morphologies of 27SiMn (a), 30CrMnSi (b), 30CrMnTi (c), 40Cr (d) and Q550 (e) low alloy steels after 5%NaCl salt spray test for 150 h
Fig.3  XRD pattern of surface rust layer of Q550 steel after 5%NaCl salt spray test for 150 h
Fig.4  Corrosion morphologies of 27SiMn (a, f), 30CrMnSi (b, g), 30CrMnTi (c, h), 40Cr (d, i) and Q550 (e, j) steels in mine water (a~e) and water (f~j) for 900 h
Fig.5  SEM images of 27SiMn (a), 30CrMnSi (b), 30CrMnTi (c), 40Cr (d) and Q550 (e) low alloy steels immersed in mine water for 900 h
Fig.6  SEM image (a) and EDS analysis (b) of surface corrosion products of 30CrMnTi steel immersed in mine water for 900 h
Fig.7  Impedance spectroscopies of low alloy steels immersed in mine water (a), water (b) and 3.5%NaCl solution (c)
[1] Zhu Y M.Statistics and analyst of coal mine safe accidents [D]. Fuxin: Liaoning Technical University, 2011
[1] (朱月敏. 煤矿安全事故统计及分析 [D]. 阜新: 辽宁工程技术大学, 2011)
[2] Wang Z H.Corrosion mechanism and protection techniques of columns of hydraulic supports[J]. Min. Mach., 2011, 39(9): 16
[2] (王志华. 液压支架立柱的腐蚀机理及其防护[J]. 矿山机械, 2011,39(9): 16)
[3] Guo H J, Sun Z P.Introduction to the quality control of hydraulic support[J]. Technol. Innov. Appl., 2012, (3): 9
[3] (郭红娟, 孙志平. 浅谈液压支架的质量控制[J]. 科技创新与应用, 2012, (3): 9)
[4] Shan Q, LI S, Liu L Z, et al.The influence on the corrosion of hydraulic support system of chloride ions in the transmission medium and preventive measures[J]. Procedia Eng., 2011, 26: 1214
[5] Melchers R E.The effects of water pollution on the immersion corrosion of mild and low alloy steels[J]. Corros. Sci., 2007, 49(8): 3149
[6] Liu S S, Yang L G, Huang X Z.To investigate the surface treatment systems of hydraulic support[J]. Coal Eng., 2007, (9): 95
[6] (刘双双, 杨雷岗, 黄孝章. 液压支架表面处理方法探讨[J]. 煤炭工程, 2007, (9): 95)
[7] Du X Y.Research of electroless plating Ni-P-based protection system on hydraulic support [D]. Fuxin: Liaoning Technical University, 2012
[7] (杜学芸. 液压支架立柱化学镀Ni-P基防护体系研究 [D]. 阜新: 辽宁工程技术大学, 2012)
[8] Hung J Z, Zuo Y.Corrosion Resistance & Corrosion Data of Materials [M]. Beijing: Chemical Industry Press, 2002
[8] (黄建中, 左禹. 材料的耐蚀性和腐蚀数据 [M]. 北京: 化学工业出版社, 2002)
[9] Chandler K A, Kilcullen M B.Corrosion-resistant low-alloy steels: A review with particular reference to atmospheric conditions in the united kingdom[J]. Br. Corros., 1970, 5(1): 24
[10] Lu Y L, Cao M X.Discussion on influencing factors of neutral salt spray test[J]. Mei Shan Technol., 2012, (1): 56
[10] (陆永亮, 曹美霞. 中性盐雾试验影响因素探讨[J]. 梅山科技, 2012, (1): 56)
[11] Cheng H P, Wang D J.Corrosion mechanisms of oxygen concentration cell in oil wells[J]. Corros. Prot. Petrochem. Ind., 2014, 31(1): 46
[11] (程海鹏, 王东江. 氧浓差电池在油井的腐蚀机理[J]. 石油化工腐蚀与防护, 2014, 31(1): 46)
[12] Jia H L, Zhao C P, Wang H.Phenomenon of oxygen concentration cell in pipeline[J]. Pipeline Tech. Equip., 2012, (3): 51
[12] (贾恒磊, 赵春平, 汪浩. 管线的氧浓差电池现象[J]. 管道技术与设备, 2012, (3): 51)
[13] He Y Q, Sun B, Liu Z Y, et al.Effects of oxide scale on industrial atmosphere corrosion of low carbon steels[J]. J. Northeastern Univ.(Nat. Sci.), 2013, 34(10): 1416
[13] (何永全, 孙彬, 刘振宇等. 氧化铁皮对低碳钢大气腐蚀行为的影响[J]. 东北大学学报 (自然科学版), 2013, 34(10): 1416
[14] Zhao H R.The form of corrosion and mechanism of action of under-deposit corrosion of boiler are researched[J]. Technol. Wind, 2015, (2): 140
[14] (赵海瑞. 锅炉垢下腐蚀的类型及其作用机理研究[J]. 科技风,2015, (2): 140)
[15] Xu S.Study of DZL2/4-1.0-W II boiler bottom under-deposit corrosion[J]. Equip. Manuf. Technol., 2013, (9): 79
[15] (徐松. DZL2/4-1.0-W II型锅炉锅筒底部垢下腐蚀探讨[J]. 装备制造技术, 2013, (9): 79)
[1] HUANG Peng, GAO Rongjie, LIU Wenbin, YIN Xubao. Fabrication of Superamphiphobic Surface for Nickel-plate on Pipeline Steel by Salt Solution Etching and Its Anti-corrosion Properties[J]. 中国腐蚀与防护学报, 2021, 41(1): 96-100.
[2] DONG Xucheng, GUAN Fang, XU Liting, DUAN Jizhou, HOU Baorong. Progress on the Corrosion Mechanism of Sulfate-reducing Bacteria in Marine Environment on Metal Materials[J]. 中国腐蚀与防护学报, 2021, 41(1): 1-12.
[3] TANG Rongmao, ZHU Yichen, LIU Guangming, LIU Yongqiang, LIU Xin, PEI Feng. Gray Correlative Degree Analysis of Q235 Steel/conductive Concrete Corrosion in Three Typical Soil Environments[J]. 中国腐蚀与防护学报, 2021, 41(1): 110-116.
[4] HAN Yuetong, ZHANG Pengchao, SHI Jiefu, LI Ting, SUN Juncai. Surface Modification of TA1 Bipolar Plate for Proton Exchange Membrane Fuel Cell[J]. 中国腐蚀与防护学报, 2021, 41(1): 125-130.
[5] ZHANG Yuxuan, CHEN Cuiying, LIU Hongwei, LI Weihua. Research Progress on Mildew Induced Corrosion of Al-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 13-21.
[6] RAN Dou, MENG Huimin, LIU Xing, LI Quande, GONG Xiufang, NI Rong, JIANG Ying, GONG Xianlong, DAI Jun, LONG Bin. Effect of pH on Corrosion Behavior of 14Cr12Ni3WMoV Stainless Steel in Chlorine-containing Solutions[J]. 中国腐蚀与防护学报, 2021, 41(1): 51-59.
[7] BAI Yunlong, SHEN Guoliang, QIN Qingyu, WEI Boxin, YU Changkun, XU Jin, SUN Cheng. Effect of Thiourea Imidazoline Quaternary Ammonium Salt Corrosion Inhibitor on Corrosion of X80 Pipeline Steel[J]. 中国腐蚀与防护学报, 2021, 41(1): 60-70.
[8] ZUO Yong, CAO Mingpeng, SHEN Miao, YANG Xinmei. Effect of Mg on Corrosion of 316H Stainless Steel in Molten Salts MgCl2-NaCl-KCl[J]. 中国腐蚀与防护学报, 2021, 41(1): 80-86.
[9] WANG Yating, WANG Kexu, GAO Pengxiang, LIU Ran, ZHAO Dishun, ZHAI Jianhua, QU Guanwei. Inhibition for Zn Corrosion by Starch Grafted Copolymer[J]. 中国腐蚀与防护学报, 2021, 41(1): 131-138.
[10] WANG Xintong, CHEN Xu, HAN Zhenze, LI Chengyuan, WANG Qishan. Stress Corrosion Cracking Behavior of 2205 Duplex Stainless Steel in 3.5%NaCl Solution with Sulfate Reducing Bacteria[J]. 中国腐蚀与防护学报, 2021, 41(1): 43-50.
[11] SHI Kunyu, WU Weijin, ZHANG Yi, WAN Yi, YU Chuanhao. Electrochemical Properties of Nb Coating on TC4 Substrate in Simulated Body Solution[J]. 中国腐蚀与防护学报, 2021, 41(1): 71-79.
[12] ZHENG Li, WANG Meiting, YU Baoyi. Research Progress of Cold Spraying Coating Technology for Mg-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 22-28.
[13] WEI Zheng, MA Baoji, LI Long, LIU Xiaofeng, LI Hui. Effect of Ultrasonic Rolling Pretreatment on Corrosion Resistance of Micro-arc Oxidation Coating of Mg-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 117-124.
[14] YU Hongfei, SHAO Bo, ZHANG Yue, YANG Yange. Preparation and Properties of Zr-based Conversion Coating on 2A12 Al-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 101-109.
[15] ZHANG Hao, DU Nan, ZHOU Wenjie, WANG Shuaixing, ZHAO Qing. Effect of Fe3+ on Pitting Corrosion of Stainless Steel in Simulated Seawater[J]. 中国腐蚀与防护学报, 2020, 40(6): 517-522.
No Suggested Reading articles found!

Copyright © 2017 Journal of Chinese Society for Corrosion and protection, All Rights Reserved.
Editorial Office: Journal of Chinese Society for Corrosion and Protection, 72 Wenhua Rd., Shenyang 110016, China
Tel: +86- 024-23971318, Fax: +86-024-23971819 　E-mail: jcscp@imr.ac.cn
Powered by Beijing Magtech