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STUDY ON ATMOSPHERIC CORROSION OF LOW ALLOY STEEL |
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Abstract The corrosion of 7 kinds of mild steel and low alloy steelin immersion-wet-dry cycle test environment and the electrochemical feature of rusted metals after test were studied by using EIS and SEM et al.The solution containing HSO-3 and Cl-,was used for wetting and immersion specimens at circumstance emperature 40℃ for 4 min respectively.The drying cycle was maintained for 12 min at temperature 12℃.The results indicated that,the weight loss all followed exponential decay function:Y=Y0+Ae-t/B.The corrosion rate of mild steel was 2.49 times than that of the most corrosion resistant low alloy after 120 h test.The results of electrochemical measurement showed that,the further corrosion rate would be controlled by cathodic diffusion process.The impedance of 7 kinds of steels after corrosion test was linear with the annual corrosion rate.
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Received: 29 September 2002
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[1]TownsendHE .Effectofalloyingelementsonthecorrosionofsteelinindustrialatmospheres[J].Corrosion,2001,57(6):497-501 [2]AsamiK ,KikuchiM .Characterizationofrustlayersonweatheringsteelsair-exposedforalongperiod[J].J .TheJapanInstituteofMetals,2002,66(6):649-656 [3]IshikawaT ,KumagaiM ,etal.Characterizationofrustonweather ingsteelbygasadsorption[J].Corrosion,2001,57(4):346-352 [4]KamimuraT ,NasuS ,etal.Mossbauerspectroscopicstudyofrustformedonaweatheringsteelandmildsteelexposedforalongterminanindustrialenvironment[J].Mater.Trans.,2002,43(4):694-703 [5]YamamotoM ,KatayamaH ,KodamaT .Microstructuralanalysisofrustlayersonweatheringsteelsexposedatruralandcoastalareas[J].TetsutoHagane,2000,86(9):578-583 |
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