GEMINI SURFACTANTS CONTAINING HYDROXYL GROUP AS CORROSION INHIBITORS FOR Q235 STEEL IN BRINE SOLUTION SATURATED BY CO2

J Chin Soc Corr Pro

2012, Vol. 32

Issue (4): 349-352 DOI:

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GEMINI SURFACTANTS CONTAINING HYDROXYL GROUP AS CORROSION INHIBITORS FOR Q235 STEEL IN BRINE SOLUTION SATURATED BY CO₂

ZHAO Jingmao, LI Jun

School of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029

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Abstract Four gemini surfactants n-3OH-n (n=12, 14, 16, 18) were synthesized and their corrosion inhibition performance for Q235 steel in brine solution saturated by CO₂ was investigated by mass loss method, polarization curves and electrochemical impedance spectroscopy (EIS). The results indicated that gemini surfactants act as good corrosion inhibitor. Among four surfactants, 12-3OH-12 and 14-3OH-14 are better than the others. Potentiodynamic polarization curves clearly reveal that the gemini surfactants belong to mixed type inhibitors which preferentially restrain the anodic process of corrosion. The values of inhibition efficiency obtained from mass loss measurements, potentiodynamic polarization measurements and EIS measurements are in good agreement.

Key words: gemini surfactants CO₂ corrosion corrosion inhibitor adsorption

Received: 20 June 2011

ZTFLH:

TG174.42

Corresponding Authors: ZHAO Jingmao E-mail: jingmaozhao@126.com

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Cite this article:

ZHAO Jingmao, LI Jun. GEMINI SURFACTANTS CONTAINING HYDROXYL GROUP AS CORROSION INHIBITORS FOR Q235 STEEL IN BRINE SOLUTION SATURATED BY CO₂. J Chin Soc Corr Pro, 2012, 32(4): 349-352.

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https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y2012/V32/I4/349

[1] Ai J Z, Mei P, Guo X P. Adsorption behavior of imidazoline inhibition on carbon steel in CO₂ saturated NaCl solution[J]. J. Chin. Soc. Corros. Prot., 2012, 31(4): 305-308

    (艾俊哲, 梅平, 郭兴蓬. 饱和CO₂盐水溶液中咪唑啉缓蚀剂在碳钢表面上的吸附行为[J]. 中国腐蚀与防护学报, 2011, 31(4): 305-308)

[2] Ma W H, Pei X H, Gao F, et al. Corrosion behaviors of N80 in simulated water from deep gaswell containing CO₂[J]. J. Chin. Soc. Corros. Prot., 2007, 27(1): 8-13

    (马文海, 裴晓含, 高飞等. N80钢在模拟深层气井水溶液中的CO₂腐蚀行为[J]. 中国腐蚀与防护学报, 2007, 27(1): 8-13)

[3] Li X W, Gao Y M. Present situation and protection methods of CO₂ corrosion [J]. Corros. Sci. Prot. Technol., 2009, 21(6): 553-555

    (李晓伟, 高延敏. CO₂腐蚀的研究现状及其控制措施[J]. 腐蚀科学与防护技术, 2009, 21(6): 553-555)

[4] Tajima K, Imai Y, Ikeda I. Specific surface activity of gemini surfactants: mixing effects of alanine-type and sulfate-type surfactants [J]. J. Oleo. Sci., 2001, 50(5): 453-462

[5] Menger F M, Keiper J S. Gemini surfactants [J]. Angew. Chem. Int. Ed., 2000, 39(11): 1906-1920

[6] Qiu L G, Wang Y M, Jiang X. Synergistic effect between cationic gemini surfactant and chloride ion for the corrosion inhibition of steel in sulphuric acid [J]. Corros. Sci., 2008, 50(2): 576-582

[7] Morsi M S, Barakat Y F, El-Sheikh R, et al. Corrosion inhibition of mild steel by amploteric surfactants derived from aspartic acid [J]. Mater. Corros., 1993, 44(7): 304-308

[8] El Achouri M, Kertit S, Gouttaya H M, et al. Synthesis of some cationic gemini surfactants and their inhibitive effect on iron corrosion in hydrochloric acid medium [J]. Corros. Sci., 2001, 43: 19-35

[9] Yang J Z, Miao Z C, Xu L. Synthesis of 18-3-18 gemini cationic surfactant with novel way [J]. Fine Chem., 2005, 22(suppl.1): 50-52

    (杨建洲, 苗宗成, 徐亮. 18-3-18型Gemini阳离子表面活性剂的合成[J]. 精细化工, 2005, 22(suppl.1): 50-52)

[10] Fu W, Liang L, Zheng J S, et al. Synthesis and properties of Gemini imidazoline quaternary ammonium salts as corrosion inhibitor [J]. Chin. Appl. Chem., 2009, 26(12): 1422-1427

     (付薇, 梁亮, 郑敬生等. Gemini型咪唑啉双季铵盐金属缓蚀剂的合成及其性能[J]. 应用化学, 2009, 26(12): 1422-1427)

[11] Cao C N. Corrosion Electrochemistry [M]. Beijing: Chemistry Industry Press, 1994

     (曹楚南. 腐蚀电化学[M]. 北京: 化学工业出版社, 1994)

[12] Suzuki K. The study of inhibitor for sour gas service [J]. Corrosion, 1982, 38(7): 384-389

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