Adsorption and Inhibition Action of Dodecyl Dimethyl Benzyl Ammonium Chloride on Cold-rolled Steel in Trichloroacetic Acid

doi:10.11902/1005.4537.2023.010

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (1): 82-90 DOI: 10.11902/1005.4537.2023.010

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Adsorption and Inhibition Action of Dodecyl Dimethyl Benzyl Ammonium Chloride on Cold-rolled Steel in Trichloroacetic Acid

ZHOU Da, LI Xianghong, LEI Ran, DENG Shuduan(

)

College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China

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ZHOU Da, LI Xianghong, LEI Ran, DENG Shuduan. Adsorption and Inhibition Action of Dodecyl Dimethyl Benzyl Ammonium Chloride on Cold-rolled Steel in Trichloroacetic Acid. Journal of Chinese Society for Corrosion and protection, 2024, 44(1): 82-90.

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Abstract

The corrosion inhibition performance of the cationic surfactant dodecyl dimethyl lbenzyl ammonium chloride (1227) on cold rolled steel in 0.10 mol/L Cl₃CCOOH trichloroacetic acid solution was investigated by mass loss measurement, electrochemical test, scanning electron microscopy (SEM), atomic force microscopy (AFM) and contact angle tester. The results show that 1227 can effectively suppress the corrosion of cold rolled steel in 0.10 mol/L Cl₃CCOOH solution. The inhibition efficiency of 40 mg/L 1227 is as high as 97.4% at 20^oC. The higher the corrosion inhibitor concentration, the higher the corrosion inhibition efficiency, and the higher the temperature, the lower the corrosion inhibition efficiency. The adsorption of 1227 on CRS surface follows Langmuir adsorption isotherm, and the type of adsorption is a mixture of physical and chemical adsorption while chemisorption as the main effect. The potentiodynamic polarization curve shows that 1227 can simultaneously inhibit both the cathodic- and anodic-reactions, and so 1227 is a mixed inhibitor and its action mechanism is "geometric covering effect". In the Nyquist diagram, along with the increase of 1227 concentration, the capacitance arc and the charge transfer resistance all increase, therewith, the inhibition effect increases. The result of SEM and AFM analysis proves also that 1227 can effectively retard the corrosion of the steel in Cl₃CCOOH solution. The contact angle results show that the addition of 1227 enhances the hydrophobicity of CRS surface.

Key words: dodecyl dimethyl benzyl ammonium chloride inhibition steel trichloroacetic acid adsorption

Received: 14 January 2023 32134.14.1005.4537.2023.010

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(52161016);National Natural Science Foundation of China(51761036);Fundamental Research Project for Distinguished Young Scholars in Yunnan Province(202001AV070008);Special Project of "Top Young Talents" of Yunnan Ten Thousand Talents Plan(51900109);Special Project of "Industry Leading Talents" of Yunnan Ten Thousand Talents Plan(80201408)

Corresponding Authors: DENG Shuduan, E-mail: dengshuduan@163.com

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https://www.jcscp.org/EN/10.11902/1005.4537.2023.010 OR https://www.jcscp.org/EN/Y2024/V44/I1/82

Fig.1 Relation curves between corrosion rate (v) and 1227 concentration (c) in 0.10 mol/L Cl₃CCOOH solution

Fig.2 Relation curves between inhibition efficiency (η_w ) and 1227 concentration (c) in 0.10 mol/L Cl₃CCOOH solution

Fig.3 Langmuir adsorption isotherm of 1227 on steel surface

Table 1 Linear regression parameters for the fitted lines of c/θ-c

Fig.4 Fitted line of lnK and 1/T

Table 2 Thermodynamic parameters of the adsorption of 1227 of steel surface in 0.10 mol/L Cl₃CCOOH solution

Fig.5 Potentiodynamic polarization curves of cold rolled steel without and with different concentrations of 1227 in 0.10 mol/L Cl₃CCOOH solution at 20^oC

Table 3 Fitted parameters of potentiodynamic polarization curves

Fig.6 Nyquist spectra (a), Bode modulus graphs (b) and Bode phase angle graphs (c) of steel in 0.10 mol/L Cl₃CCOOH solution with different concentrations of 1227 at 20^oC

Fig.7 Equivalent circuit diagrams: (a) R(QR)(LR_L), (b) R(QR)

Table 4 EIS parameters of cold rolled steel in 0.10 mol/L Cl₃CCOOH solutions with different 1227 concentrations at 20^oC

Fig.8 SEM microscopic image of steel sheet surface: (a) polished surface, (b) after corrosion in 0.10 mol/L Cl₃CCOOH solution for 6 h at 20^oC, (c) after corrosion in 100 mg/L 1227 + 0.10 mol/L Cl₃CCOOH solution for 6 h at 20^oC

Fig.9 3D-AFM microscopic images of steel sheet surfaces: (a) polished surface, (b) after corrosion in 0.10 mol/L Cl₃CCOOH solution for 6 h at 20^oC, (c) after corrosion in 100 mg/L 1227 + 0.10 mol/L Cl₃CCOOH solution for 6 h at 20^oC

Table 5 Surface rough parameters of 3D-AFM micrographs of steel surfaces

Fig.10 Analysis of contact angles of steel sheet surface: (a) polished surface, (b) after corrosion in 0.10 mol/L Cl₃CCOOH solution for 6 h at 20^oC, (c) after corrosion in 100 mg/L 1227 + 0.10 mol/L Cl₃CCOOH solution for 6 h at 20^oC

Fig.11 Schematic diagram of 1227 adsorption on steel surface

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