Correlation of Corrosion Information Aquired by Indoor Acceleration Testing and by Real Low Temperature Marine Atmosphere Exposure in Polar Region for Ni-Cr-Mo-V Steel

doi:10.11902/1005.4537.2023.057

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (1): 91-99 DOI: 10.11902/1005.4537.2023.057

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Correlation of Corrosion Information Aquired by Indoor Acceleration Testing and by Real Low Temperature Marine Atmosphere Exposure in Polar Region for Ni-Cr-Mo-V Steel

LENG Wenjun¹^,², SHI Xizhao¹, XIN Yonglei², YANG Yange³, WANG Li², CUI Zhongyu¹(

), HOU Jian²

^1.School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
^2.Science and Technology on Marine Corrosion and Protection Laboratory, Luoyang Ship Material Research Institute, Qingdao 266237, China
^3.Shi -changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

Cite this article:

LENG Wenjun, SHI Xizhao, XIN Yonglei, YANG Yange, WANG Li, CUI Zhongyu, HOU Jian. Correlation of Corrosion Information Aquired by Indoor Acceleration Testing and by Real Low Temperature Marine Atmosphere Exposure in Polar Region for Ni-Cr-Mo-V Steel. Journal of Chinese Society for Corrosion and protection, 2024, 44(1): 91-99.

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Abstract

In order to investigate the applicability of the proposed indoor accelerated test spectrum, which aims to simulate the low temperature marine environment in the polar region, and the corrosion mechanism of low alloy steel exposed in the real polar low temperature atmospheric environment, therefore, the Ni-Cr-Mo-V steels were subjected to indoor accelerated test in lab and to outdoor exposure test in Zhongshan station at the polar region respectively, then the corrosion behavior of the tested steels was comparatively studied by means of mass loss measurement, scanning electron microscope, and laser confocal microscope. The results revealed that the corrosion rate of the steel is 11.3 μm/a, and the corrosion products are composed of Fe₃O₄, γ-FeOOH, α-FeOOH and β-FeOOH. The presence of the large amount of β-FeOOH indicates that the rust scale formed in low temperature environment has poor protectiveness. The low temperature atmospheric corrosion is mainly uniform corrosion. The freeze-thaw cycle causes the alteration of electrolyte concentration on the surface of test steel, which results in the formation of pitting corrosion beneath the rust scale. During the freeze-thaw cycle, the alternation of stresses caused by the cyclical solid-liquid phase transition of the water in the rust scale and the difference of the thermal expansion coefficient between the rust scale and the metal matrix could lead to the cracking of the rust scale.

Key words: polar environment accelerated corrosion corrosion products freeze-thaw cycle

Received: 03 March 2023 32134.14.1005.4537.2023.057

ZTFLH:

TG174

Fund: Key Research and Development Program of Shandong Province(2020CXGC010305);Natural Science Foundation of Shandong Province(ZR2022YQ44)

Corresponding Authors: CUI Zhongyu, E-mail: cuizhongyu@ouc.edu.cn

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	LENG Wenjun
	SHI Xizhao
	XIN Yonglei
	YANG Yange
	WANG Li
	CUI Zhongyu
	HOU Jian

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https://www.jcscp.org/EN/10.11902/1005.4537.2023.057 OR https://www.jcscp.org/EN/Y2024/V44/I1/91

Fig.1 Environmental parameters of Zhongshan station during 2019 to 2021: (a) annual average temperature data, (b) annual average humidity data

Fig.2 Schematic diagram of indoor simulation and acceleration environment test device (a) and environmental spectrum period (b)

Fig.3 Comparison of corrosion rates of Ni-Cr-Mo-V Steel: (a) one period of indoor accelerated corrosion test, (b) outdoor at Zhongshan station in Antarctica for 1 a

Table 1 Corrosion rate of steel materials in different atmospheric environments

Fig.4 Surface morphologies of corrosion products of Ni-Cr-Mo-V steel under accelerated corrosion environment spectrum (a, b) and atmospheric corrosion of Zhongshan station (c, d)

Fig.5 Section morphologies of corrosion products of Ni-Cr-Mo-V steel under accelerated corrosion environment spectrum (a, b) and atmospheric corrosion of Zhongshan station (c, d)

Fig.6 Surface corrosion morphology of Ni-Cr-Mo-V steel under accelerated corrosion environment spectrum (a, b) and atmospheric corrosion of Zhongshan station (c, d)

Fig.7 XRD (a) and the semi-quantitative analysis (b) of corrosion products formed on Ni-Cr-Mo-V steel under indoor simulation and Antarctic atmospheric environment

Fig.8 Atmospheric corrosion mechanism under low temperature and ice freeze-thaw environment

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