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Corrosion Inhibition on Carbon Steel in Acidic Solution by Carbon Dots Prepared from Waste Longan Shells |
CHEN Jiaqi, HOU Daolin, XIAO Han, GAO Yuwei, DONG Sheying() |
School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology, Xi'an 710311, China |
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Abstract In order to develop new environment-friendly corrosion inhibitors of high corrosion inhibition efficiency, longan shell carbon dots (ls-CDs) and nitrogen doped longan shell carbon dots (N-lsCDs) were synthesized by calcination and one-pot hydrothermal methods, respectively. Meantime, the structural, composition, optical property, and corrosion inhibition performance of ls-CDs and N-lsCDs were assessed by means of FT-IR, FL, XPS, TEM, electrochemical method, and static mass loss method. Results showed that when the concentration of ls-CDs and N-lsCDs was 100 and 20 mg·L-1 in 1 mol·L-1 HCl solution, the corresponding corrosion inhibition efficiency for Q235 steel reaches 89.49% and 92.41% respectively. Besides, the N-lsCDs present advantages, such as excellent corrosion inhibition performance in low dosage etc., and it is especially noticeable that the N-lsCDs could be produced from the longan shell as waste. The polarization curve test results showed that N-lsCDs is a mixed inhibitor, and the adsorption of N-lsCDs on the surface of carbon steel conforms to the Langmuir adsorption isotherm. Using biomass as raw material to prepare new environment-friendly corrosion inhibitor can turn waste into resources, which has attractive potential application prospects.
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Received: 26 August 2021
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Fund: National Innovation and Entrepreneurship Training Program for College Students(202010703056);Shaanxi Province Key R&D Program(2020GY-306) |
Corresponding Authors:
DONG Sheying
E-mail: dongsyy@126.com
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About author: DONG Sheying, E-mail: dongsyy@126.com
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1 |
Nabatipour S, Mohammadi S, Mohammadi A. Synthesis and comparison of two chromone based Schiff bases containing methoxy and acetamido substitutes as highly sustainable corrosion inhibitors for steel in hydrochloric acid [J]. J. Mol. Struct., 2020, 1217: 128367
doi: 10.1016/j.molstruc.2020.128367
|
2 |
Zadeh A R H, Danaee I, Maddahy M H. Thermodynamic and adsorption behaviour of medicinal nitramine as a corrosion inhibitor for AISI steel alloy in HCl solution [J]. J. Mater. Sci. Technol., 2013, 29: 884
doi: 10.1016/j.jmst.2013.06.006
|
3 |
Mourya P, Banerjee S, Singh M M. Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor [J]. Corros. Sci., 2014, 85: 352
doi: 10.1016/j.corsci.2014.04.036
|
4 |
Bai P K, Xu P. Synthesis and modification of green environment-friendly scale inhibitors in the field of water treatment: the state-of-art technological advances [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 87
|
|
白鹏凯, 许萍. 水处理领域中的绿色环保阻垢剂及其研究进展 [J]. 中国腐蚀与防护学报, 2020, 40: 87
|
5 |
Liu Q, Zhou T Y. Inhibition behavior of graphene quantum dots for carbon steel in HCl solution [J]. Corros. Prot., 2015, 36: 152
|
|
刘青, 周桃玉. 盐酸溶液中石墨烯量子点对碳钢的缓蚀性能 [J]. 腐蚀与防护, 2015, 36: 152
|
6 |
Yang D P, Ye Y W, Su Y, et al. Functionalization of citric acid-based carbon dots by imidazole toward novel green corrosion inhibitor for carbon steel [J]. J. Clean. Prod., 2019, 229: 180
doi: 10.1016/j.jclepro.2019.05.030
|
7 |
Cen H Y, Chen Z Y, Guo X P. Corrosion inhibition performance and mechanism of carbon dots as corrosion inhibitors [J]. Surf. Technol., 2020, 49(11): 13
|
|
岑宏宇, 陈振宇, 郭兴蓬. 碳量子点缓蚀剂的缓蚀行为与机理研究 [J]. 表面技术, 2020, 49(11): 13
|
8 |
Saraswat V, Yadav M. Carbon dots as green corrosion inhibitor for mild steel in HCl solution [J]. ChemistrySelect, 2020, 5: 7347
doi: 10.1002/slct.202000625
|
9 |
Li L Y, Xu J L, Mu Y, et al. Chemical characterization and anti-hyperglycaemic effects of polyphenol enriched longan (Dimocarpus longan Lour.) pericarp extracts [J]. J. Funct. Foods, 2015, 13: 314
doi: 10.1016/j.jff.2015.01.006
|
10 |
Rakariyatham K, Zhou D Y, Rakariyatham N, et al. Sapindaceae (Dimocarpus longan and Nephelium lappaceum) seed and peel by-products: potential sources for phenolic compounds and use as functional ingredients in food and health applications [J]. J. Funct. Foods, 2020, 67: 103846
doi: 10.1016/j.jff.2020.103846
|
11 |
Yan J, Fang Y Y, Wang S W, et al. Nitrogen-doped oxygen-rich activated carbon derived from Longan shell for supercapacitors [J]. Int. J. Electrochem. Sci., 2020, 15: 1982
|
12 |
Zhang Q, Wang Y Y, Wang Z, et al. Active biochar support nano zero-valent iron for efficient removal of U (VI) from sewage water [J]. J. Alloy. Compd., 2021, 852: 156993
doi: 10.1016/j.jallcom.2020.156993
|
13 |
Li Z H, Wang Q M, Pan Y M. Study on the antioxidant compounds extracted from longan (Dimocarpus longan Lour.) shell [J]. Asian J. Chem., 2014, 26: 4602
doi: 10.14233/ajchem.2014.16130
|
14 |
Liu Y H, Qu X X, Huang G X, et al. 3-dimensional porous carbon with high nitrogen content obtained from longan shell and its excellent performance for aqueous and all-solid-state supercapacitors [J]. Nanomaterials, 2020, 10: 808
doi: 10.3390/nano10040808
|
15 |
Yang X X, Guo Y Z, Liang S, et al. Preparation of sulfur-doped carbon quantum dots from lignin as a sensor to detect Sudan I in an acidic environment [J]. J. Mater. Chem. B, 2020, 8: 10788
doi: 10.1039/D0TB00125B
|
16 |
Liu L J, Zhang S T, Zheng X D, et al. Carbon dots derived from Fusobacterium nucleatum for intracellular determination of Fe3+ and bioimaging both in vitro and in vivo [J]. Anal. Methods, 2021, 13: 1121
doi: 10.1039/D1AY00020A
|
17 |
Mathew S A, Saminathan D, Hubert Y S, et al. Facile single step preparation of carbon nanodots from chitosan by carbonization [J]. J. Indian Chem. Soc., 2019, 96: 180
|
18 |
Liu S Y, Zhao N, Cheng Z, et al. Amino-functionalized green fluorescent carbon dots as surface energy transfer biosensors for hyaluronidase [J]. Nanoscale, 2015, 7: 6836
doi: 10.1039/C5NR00070J
|
19 |
Wang Y L, Yan L P, Ji G Q, et al. Synthesis of N,S-doped carbon quantum dots for use in organic solar cells as the ZnO modifier to eliminate the light-soaking effect [J]. ACS Appl. Mater. Interfaces, 2019, 11: 2243
doi: 10.1021/acsami.8b17128
|
20 |
Tang R M, Liu G M, Shi C, et al. Inhibition and adsorption behavior of sodium dodecyl-benzene sulfonate on Q235 steel in simulated concrete pore fluid [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 857
|
|
唐荣茂, 刘光明, 师超 等. 十二烷基苯磺酸钠在模拟混凝土孔隙液中对Q235钢缓蚀及吸附行为研究 [J]. 中国腐蚀与防护学报, 2021, 41: 857
|
21 |
Xiao H, Dong S Y, Yuan X J, et al. Corrosion inhibition performance and mechanism of N-doped carbon dots to Q235 steel [J]. J. Funct. Mater., 2021, 52: 8138
|
|
肖晗, 董社英, 袁小静 等. 氮掺杂碳点对Q235钢的缓蚀性能及机理研究 [J]. 功能材料, 2021, 52: 8138
|
22 |
D'Elia L F, Torres F, Báez V. Voltammetric adsorption studies of commercial corrosion inhibitors. A first correlating approach to the corrosion inhibition efficiency [J]. Port. Electrochim. Acta, 2009, 27: 671
doi: 10.4152/pea.200906671
|
23 |
Wang J, Wang S Y, Zhang C, et al. Effect of nitrogen doping on corrosion inhibition performance of carbon nanoparticles [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 85
|
|
王晶, 王斯琰, 张崇 等. 氮掺杂对碳纳米颗粒缓蚀性能的影响 [J]. 中国腐蚀与防护学报, 2022, 42: 85
|
24 |
Hajideh M R, Farahani M, Pakravan M, et al. Corrosion resistance and hydrophilic properties of plasma sprayed Ni+5%Al coatings [J]. Heliyon, 2019, 5: e01920
doi: 10.1016/j.heliyon.2019.e01920
|
25 |
Fernandes B S, da Silva Souza K G, Aoki I V, et al. Evaluation of the influence of experimental parameters in the formation of a vinyltrimethoxysilane film on 1010 carbon steel through electrochemical impedance spectroscopy and contact angle techniques [J]. Electrochim. Acta, 2014, 124: 137
doi: 10.1016/j.electacta.2013.08.061
|
26 |
Cao S Y, Liu D, Ding H, et al. Task-specific ionic liquids as corrosion inhibitors on carbon steel in 0.5 M HCl solution: an experimental and theoretical study [J]. Corros. Sci., 2019, 153: 301
doi: 10.1016/j.corsci.2019.03.035
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