Synthesis and Performance of New Benzotriazole Derivatives with Long Alkyl Chain as Corrosion Inhibitors

doi:10.11902/1005.4537.2015.214

Journal of Chinese Society for Corrosion and protection

2016, Vol. 36

Issue (5): 415-420 DOI: 10.11902/1005.4537.2015.214

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Synthesis and Performance of New Benzotriazole Derivatives with Long Alkyl Chain as Corrosion Inhibitors

Xiang ZUO^1,²(

),Yufeng JIANG¹,Ting CHI¹,Xin HU¹,Dongmei CAO¹,Feng CAI²

1. National Engineering Research Center of Water Resources Efficient Utilization and Engineering Safety, Nanjing 210019, China
2. College of Materials Science and Engineering, Nanjing University of Technology, Nanjing 210009, China

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Abstract

A series of new corrosion inhibitors named 1-(2'-alkylsulfanylacetyl)-benzotriazole derivatives were synthesized by alkyl sulfhydryls of different lengths, sodium chloroacetate and benzotriazole. The corrosion inhibition effect of benzotriazole derivatives on copper was evaluated in 3.5%NaCl solution by means of weight loss and electrochemical testing methods, while the adsorption pattern of corrosion inhibitor molecules on the surface of copper was studied. The results show that the benzotriazole derivatives act as mixed type inhibitors with anode inhibition as dominative action. The adsorption of corrosion inhibitor molecules on copper surface obey Langmuir adsorption isotherm, including both physical and chemical adsorption. The synthesized benzotriazole derivatives possess high corrosion inhibition efficiency and excellent temperature resistance.

Key words: 1-(2'-alkylsulfanylacetyl)-benzotriazole copper corrosion inhibitor anode inhibition Langmuir adsorption isotherm

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	Xiang ZUO
	Yufeng JIANG
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	Xin HU
	Dongmei CAO
	Feng CAI

Cite this article:

Xiang ZUO,Yufeng JIANG,Ting CHI,Xin HU,Dongmei CAO,Feng CAI. Synthesis and Performance of New Benzotriazole Derivatives with Long Alkyl Chain as Corrosion Inhibitors. Journal of Chinese Society for Corrosion and protection, 2016, 36(5): 415-420.

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https://www.jcscp.org/EN/10.11902/1005.4537.2015.214 OR https://www.jcscp.org/EN/Y2016/V36/I5/415

Fig.1 Corrosion rate of copper immersed in 3.5%NaCl solutions (a) and corrosion inhibition efficiency of inhibitors (b)at different temperatures

Table 1 Mass loss results of copper immersed in 3.5%NaCl solutions with different concentrations of corrosioninhibitors

Table 2 Fitting parameters of Langmuir adsorptionisotherms for corrosion inhibitors

Fig.2 Fitting lines of Langmuir adsorption isotherms forcorrosion inhibitors at 25 ℃

Fig.3 Polarization curves of copper in 3.5%NaCl solutions with different concentrations of corrosion inhibitor A2

Table 3 Polarization parameters of copper in 3.5%NaCl solutions with different concentrations of corrosion inhibitor A2

Fig.4 Nyquist diagrams for copper in 3.5%NaCl solutions with different concentrations of corrosion inhibitor A2

Table 4 Impedance data of copper in 3.5%NaCl solutionswith different concentrations of corrosion inhibitor A2

Fig.5 Equivalent circuit model used to fit the EISexperimental data

[1]	Qi D M, Ceng R Y, Du X Q, et al.Review on atmospheric corrosion of copper and copper alloys[J]. J. Chin. Soc. Corros. Prot., 2014, 34(5): 389
[1]	(齐东梅, 成若义, 杜小青等. Cu及其合金的大气腐蚀研究现状[J]. 中国腐蚀与防护学报, 2014, 34(5): 389)
[2]	Zhuang L H, Lv Z B, Tian Y W, et al.Present situation on research of corrosion inhibition technology for copper and its alloys[J]. Corros. Sci. Prot. Technol., 2005, 17(6): 418
[2]	(庄丽宏, 吕振波, 田彦文等. 铜腐蚀及其缓蚀技术应用研究现状[J]. 腐蚀科学与防护技术, 2005, 17(6): 418)
[3]	Dugdale I, Cotton J B.An electrochemical investigation on the prevention of staining of copper by benzotriazole[J]. Corros. Sci., 1963, 3(2): 69
[4]	Hashemia T, Hogarth C A.The mechanism of corrosion inhibition of copper in NaCl solution by benzotriazole studied by electron spectroscopy[J]. Electrochim. Acta, 1988, 33(8): 1123
[5]	Wu Y X, Liu M J, He G Q, et al.Synthesis of some carbonyl derivatives of BTA and determination of their inhibitive properties for copper in 3%NaCl solution[J]. Corros. Sci. Prot. Technol., 1997, 9(3): 201
[5]	(吴永炘, 刘呜江, 何国强等. BTA酰基衍生物的合成及对Cu在3%NaCl水溶液中缓蚀性能的研究[J]. 腐蚀科学与防护技术, 1997, 9(3): 201
[6]	Fleischmann M, Hill I R, Mengoli G, et al.A comparative study of the efficiency of some organic inhibitors for the corrosion of copper in aqueous chloride media using electrochemical and surface enhanced Raman scattering techniques[J]. Electrochim. Acta, 1985, 30(7): 879
[7]	Kunitsugu A, Takehiro K, Takashi S.Surface enhanced Raman scattering and impedance studies on the inhibition of copper corrosion in sulfate solution 5-substituted benzotriazole[J]. Corros. Sci., 1991, 32(5/6): 593
[8]	Raicheva S N, Aleksiev B V, Sokolova E I.The effect of the chemical- structure of some nitrogen-containing and sulfur-containing organic-compounds on their corrosion inhibiting action[J]. Corros. Sci., 1993, 34(2): 343
[9]	El Sayed H, El Ashry, Ahmed E N, et al.QSAR of benzimidazole and 2-substituted derivatives as corrosion inhibitors by using the quantum chemical parameters[J]. Prog. Org. Coat., 2008, 61(1): 11
[10]	Xiao X S, Yen P T, Simo O P.Evaluation of an organic corrosion inhibitor on abiotic corrosion and microbiologically influenced corrosion of mild steel[J]. Ind. Eng. Chem. Res., 2007, 46(22): 7117
[11]	Obot I B, Obi-Egbedi N O. Theoretical study of benzimidazole and its derivatives and their potential activity as corrosion inibitors[J]. Corros. Sci., 2010, 52(2): 657
[12]	Zhang T L, Cao S R, Dai S S, et al.Corrosion inhibition performance and mechanism of (1-tetradecyl-1H-[1,2,3]triazol-4-yl)-methanol[J]. Corros. Sci. Prot. Technol., 2014, 26(4): 329
[12]	(张太亮, 曹舒然, 戴珊珊等. 1-十四烷基-4-羟甲基-1,2,3-三唑盐酸缓蚀剂的性能及机理研究[J]. 腐蚀科学与防护技术, 2014, 26(4): 329)
[13]	Zhang T L, Cao S R, Quan H P, et al.Synthesis and corrosion inhibition performance of alkyl triazole derivatives[J]. Res. Chem. Intermed., 2015, 41(5): 2709
[14]	Solmaz R, Kardas G, Yazici B, et al. Adsorption and corrosion inhibitive properties of 2-amino-5-mercapto-l, 3,4- thiadiazole on mild steel in hydrochloric acid media [J]. Colloids Surf., 2008, 312(1)A: 7
[15]	Tang Y M, Yang X Y, Yang W Z, et al.A preliminary investigation of corrosion inhibition of mild steel in 0.5 M H2SO4 by 2-amino-5- (n-pyridyl)-1,3,4-thiadiazole: Polarization, EIS and molecular dynamics simulations[J]. Corros. Sci., 2010, 52(5): 1801

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