Corrosion Inhibition on Carbon Steel in Acidic Solution by Carbon Dots Prepared from Waste Longan Shells

doi:10.11902/1005.4537.2021.214

Journal of Chinese Society for Corrosion and protection

2022, Vol. 42

Issue (4): 629-637 DOI: 10.11902/1005.4537.2021.214

Current Issue | Archive | Adv Search

Corrosion Inhibition on Carbon Steel in Acidic Solution by Carbon Dots Prepared from Waste Longan Shells

CHEN Jiaqi, HOU Daolin, XIAO Han, GAO Yuwei, DONG Sheying(

)

School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology, Xi'an 710311, China

Download:

HTML

PDF(4337KB)
Export: BibTeX | EndNote (RIS)

Abstract

In order to develop new environment-friendly corrosion inhibitors of high corrosion inhibition efficiency, longan shell carbon dots (ls-CDs) and nitrogen doped longan shell carbon dots (N-lsCDs) were synthesized by calcination and one-pot hydrothermal methods, respectively. Meantime, the structural, composition, optical property, and corrosion inhibition performance of ls-CDs and N-lsCDs were assessed by means of FT-IR, FL, XPS, TEM, electrochemical method, and static mass loss method. Results showed that when the concentration of ls-CDs and N-lsCDs was 100 and 20 mg·L^-1 in 1 mol·L^-1 HCl solution, the corresponding corrosion inhibition efficiency for Q235 steel reaches 89.49% and 92.41% respectively. Besides, the N-lsCDs present advantages, such as excellent corrosion inhibition performance in low dosage etc., and it is especially noticeable that the N-lsCDs could be produced from the longan shell as waste. The polarization curve test results showed that N-lsCDs is a mixed inhibitor, and the adsorption of N-lsCDs on the surface of carbon steel conforms to the Langmuir adsorption isotherm. Using biomass as raw material to prepare new environment-friendly corrosion inhibitor can turn waste into resources, which has attractive potential application prospects.

Key words: carbon steel corrosion inhibitor biomass carbon dot adsorption

Received: 26 August 2021

ZTFLH:

TG174.42

Fund: National Innovation and Entrepreneurship Training Program for College Students(202010703056);Shaanxi Province Key R&D Program(2020GY-306)

Corresponding Authors: DONG Sheying E-mail: dongsyy@126.com

About author: DONG Sheying, E-mail: dongsyy@126.com

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Jiaqi CHEN
	Daolin HOU
	Han XIAO
	Yuwei GAO
	Sheying DONG

Cite this article:

CHEN Jiaqi, HOU Daolin, XIAO Han, GAO Yuwei, DONG Sheying. Corrosion Inhibition on Carbon Steel in Acidic Solution by Carbon Dots Prepared from Waste Longan Shells. Journal of Chinese Society for Corrosion and protection, 2022, 42(4): 629-637.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2021.214 OR https://www.jcscp.org/EN/Y2022/V42/I4/629

Fig.1 Fluorescence spectra of ls-CDs (a) and N-lsCDs (b) with different concentrations and FT-IR spectra of ls-CDs and N-lsCDs (c)

Fig.2 EIS of Q235 steel in 1 mol·L^-1 HCl solutions containing different concentrations of ls-CDs (a) and N-lsCDs (b)

Table 1 Fitting impedance parameters of Q235 steel in 1 mol·L^-1 HCl solutions containing different concentrations of ls-CDs and N-lsCDs

Fig.3 Polarization curves of Q235 steel in 1 mol·L^-1 HCl solutions containing different concentrations of ls-CDs (a) and N-lsCDs (b)

Table 2 Fitting parameters of polarization curves of Q235 steel in 1 mol·L^-1 HCl solutions containing different concentrations of ls-CDs and N-lsCDs

Fig.4 TEM image and particle size distribution of N-lsCDs

Fig.5 General XPS spectra of N-lsCDs (a) and fine spectra of C1s (b), O1s (c) and N1s (d)

Fig.6 Variations of corrosion rate (a) and inhibition efficiency (b) with the concentration of N-lsCDs

Table 3 Corrosion rates and inhibition efficiencies of Q235 steel in 1 mol·L^-1 HCl solutions containing different concentrations of N-lsCDs at different temperatures

Table 4 Impedance parameters of Q235 steel in 1 mol·L^-1 HCl solution containing 20 mg·L^-1 N-lsCDs at different temperatures

Table 5 Polarization parameters of Q235 steel in 1 mol·L^-1 HCl solution containing 20 mg·L^-1 N-lsCDs at different temperatures

Fig.7 Arrhenius diagrams of Q235 steel in 1 mol·L^-1 HCl solution containing different concentrations of N-lsCDs

Fig.8 Transition state diagrams of Q235 steel in 1 mol·L^-1 HCl solution containing different concent-rations of N-lsCDs

Fig.9 Adsorption isotherms of N-lsCDs on Q235 steel in 1 mol·L^-1 HCl solution

Fig.10 Contact angles of pure water drop on Q235 steel immersed for 8 h in 1 mol·L^-1 HCl solutions containing free (a) and 20 mg·L^-1 N-lsCDs (b)

1	Nabatipour S, Mohammadi S, Mohammadi A. Synthesis and comparison of two chromone based Schiff bases containing methoxy and acetamido substitutes as highly sustainable corrosion inhibitors for steel in hydrochloric acid [J]. J. Mol. Struct., 2020, 1217: 128367 doi: 10.1016/j.molstruc.2020.128367
2	Zadeh A R H, Danaee I, Maddahy M H. Thermodynamic and adsorption behaviour of medicinal nitramine as a corrosion inhibitor for AISI steel alloy in HCl solution [J]. J. Mater. Sci. Technol., 2013, 29: 884 doi: 10.1016/j.jmst.2013.06.006
3	Mourya P, Banerjee S, Singh M M. Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor [J]. Corros. Sci., 2014, 85: 352 doi: 10.1016/j.corsci.2014.04.036
4	Bai P K, Xu P. Synthesis and modification of green environment-friendly scale inhibitors in the field of water treatment: the state-of-art technological advances [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 87
	白鹏凯, 许萍. 水处理领域中的绿色环保阻垢剂及其研究进展 [J]. 中国腐蚀与防护学报, 2020, 40: 87
5	Liu Q, Zhou T Y. Inhibition behavior of graphene quantum dots for carbon steel in HCl solution [J]. Corros. Prot., 2015, 36: 152
	刘青, 周桃玉. 盐酸溶液中石墨烯量子点对碳钢的缓蚀性能 [J]. 腐蚀与防护, 2015, 36: 152
6	Yang D P, Ye Y W, Su Y, et al. Functionalization of citric acid-based carbon dots by imidazole toward novel green corrosion inhibitor for carbon steel [J]. J. Clean. Prod., 2019, 229: 180 doi: 10.1016/j.jclepro.2019.05.030
7	Cen H Y, Chen Z Y, Guo X P. Corrosion inhibition performance and mechanism of carbon dots as corrosion inhibitors [J]. Surf. Technol., 2020, 49(11): 13
	岑宏宇, 陈振宇, 郭兴蓬. 碳量子点缓蚀剂的缓蚀行为与机理研究 [J]. 表面技术, 2020, 49(11): 13
8	Saraswat V, Yadav M. Carbon dots as green corrosion inhibitor for mild steel in HCl solution [J]. ChemistrySelect, 2020, 5: 7347 doi: 10.1002/slct.202000625
9	Li L Y, Xu J L, Mu Y, et al. Chemical characterization and anti-hyperglycaemic effects of polyphenol enriched longan (Dimocarpus longan Lour.) pericarp extracts [J]. J. Funct. Foods, 2015, 13: 314 doi: 10.1016/j.jff.2015.01.006
10	Rakariyatham K, Zhou D Y, Rakariyatham N, et al. Sapindaceae (Dimocarpus longan and Nephelium lappaceum) seed and peel by-products: potential sources for phenolic compounds and use as functional ingredients in food and health applications [J]. J. Funct. Foods, 2020, 67: 103846 doi: 10.1016/j.jff.2020.103846
11	Yan J, Fang Y Y, Wang S W, et al. Nitrogen-doped oxygen-rich activated carbon derived from Longan shell for supercapacitors [J]. Int. J. Electrochem. Sci., 2020, 15: 1982
12	Zhang Q, Wang Y Y, Wang Z, et al. Active biochar support nano zero-valent iron for efficient removal of U (VI) from sewage water [J]. J. Alloy. Compd., 2021, 852: 156993 doi: 10.1016/j.jallcom.2020.156993
13	Li Z H, Wang Q M, Pan Y M. Study on the antioxidant compounds extracted from longan (Dimocarpus longan Lour.) shell [J]. Asian J. Chem., 2014, 26: 4602 doi: 10.14233/ajchem.2014.16130
14	Liu Y H, Qu X X, Huang G X, et al. 3-dimensional porous carbon with high nitrogen content obtained from longan shell and its excellent performance for aqueous and all-solid-state supercapacitors [J]. Nanomaterials, 2020, 10: 808 doi: 10.3390/nano10040808
15	Yang X X, Guo Y Z, Liang S, et al. Preparation of sulfur-doped carbon quantum dots from lignin as a sensor to detect Sudan I in an acidic environment [J]. J. Mater. Chem. B, 2020, 8: 10788 doi: 10.1039/D0TB00125B
16	Liu L J, Zhang S T, Zheng X D, et al. Carbon dots derived from Fusobacterium nucleatum for intracellular determination of Fe³⁺ and bioimaging both in vitro and in vivo [J]. Anal. Methods, 2021, 13: 1121 doi: 10.1039/D1AY00020A
17	Mathew S A, Saminathan D, Hubert Y S, et al. Facile single step preparation of carbon nanodots from chitosan by carbonization [J]. J. Indian Chem. Soc., 2019, 96: 180
18	Liu S Y, Zhao N, Cheng Z, et al. Amino-functionalized green fluorescent carbon dots as surface energy transfer biosensors for hyaluronidase [J]. Nanoscale, 2015, 7: 6836 doi: 10.1039/C5NR00070J
19	Wang Y L, Yan L P, Ji G Q, et al. Synthesis of N,S-doped carbon quantum dots for use in organic solar cells as the ZnO modifier to eliminate the light-soaking effect [J]. ACS Appl. Mater. Interfaces, 2019, 11: 2243 doi: 10.1021/acsami.8b17128
20	Tang R M, Liu G M, Shi C, et al. Inhibition and adsorption behavior of sodium dodecyl-benzene sulfonate on Q235 steel in simulated concrete pore fluid [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 857
	唐荣茂, 刘光明, 师超等. 十二烷基苯磺酸钠在模拟混凝土孔隙液中对Q235钢缓蚀及吸附行为研究 [J]. 中国腐蚀与防护学报, 2021, 41: 857
21	Xiao H, Dong S Y, Yuan X J, et al. Corrosion inhibition performance and mechanism of N-doped carbon dots to Q235 steel [J]. J. Funct. Mater., 2021, 52: 8138
	肖晗, 董社英, 袁小静等. 氮掺杂碳点对Q235钢的缓蚀性能及机理研究 [J]. 功能材料, 2021, 52: 8138
22	D'Elia L F, Torres F, Báez V. Voltammetric adsorption studies of commercial corrosion inhibitors. A first correlating approach to the corrosion inhibition efficiency [J]. Port. Electrochim. Acta, 2009, 27: 671 doi: 10.4152/pea.200906671
23	Wang J, Wang S Y, Zhang C, et al. Effect of nitrogen doping on corrosion inhibition performance of carbon nanoparticles [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 85
	王晶, 王斯琰, 张崇等. 氮掺杂对碳纳米颗粒缓蚀性能的影响 [J]. 中国腐蚀与防护学报, 2022, 42: 85
24	Hajideh M R, Farahani M, Pakravan M, et al. Corrosion resistance and hydrophilic properties of plasma sprayed Ni+5%Al coatings [J]. Heliyon, 2019, 5: e01920 doi: 10.1016/j.heliyon.2019.e01920
25	Fernandes B S, da Silva Souza K G, Aoki I V, et al. Evaluation of the influence of experimental parameters in the formation of a vinyltrimethoxysilane film on 1010 carbon steel through electrochemical impedance spectroscopy and contact angle techniques [J]. Electrochim. Acta, 2014, 124: 137 doi: 10.1016/j.electacta.2013.08.061
26	Cao S Y, Liu D, Ding H, et al. Task-specific ionic liquids as corrosion inhibitors on carbon steel in 0.5 M HCl solution: an experimental and theoretical study [J]. Corros. Sci., 2019, 153: 301 doi: 10.1016/j.corsci.2019.03.035

[1]	LIU Yongqiang, LIU Guangming, FAN Wenxue, TANG Rongmao, GAN Hongyu, SHI Chao. Effect of Sodium Benzoate on Dissolution Behavior of Zn Anode in Acidic Zn-Ni Plating Bath[J]. 中国腐蚀与防护学报, 2022, 42(4): 605-612.
[2]	LI Jianyong, DAI Dianyu, QIAN Chen, DIAO Shulei, LIU Jinshan, LU Tongxin, SUN Yong, XIAO Fengjuan. Corrosion Behavior of PANI Nanofiber/Modified GO/Waterborne Epoxy Composite Coating on Stainless Steel[J]. 中国腐蚀与防护学报, 2022, 42(1): 156-162.
[3]	TANG Rongmao, LIU Guangming, SHI Chao, ZHANG Bangyan, TIAN Jihong, GAN Hongyu, LIU Yongqiang. Inhibition and Adsorption Behavior of Sodium Dodecyl-benzene Sulfonate on Q235 Steel in Simulated Concrete Pore Fluid[J]. 中国腐蚀与防护学报, 2021, 41(6): 857-863.
[4]	WANG Lizi, HUANG Miao, LI Xianghong. Synergistic Inhibition Effect of Walnut Green Husk Extract and Potassium Iodide on Corrosion of Steel in Citric Acid Solution[J]. 中国腐蚀与防护学报, 2021, 41(6): 819-827.
[5]	HU Huihui, CHEN Changfeng. Mechanism of Temperature Influence on Adsorption of Schiff Base[J]. 中国腐蚀与防护学报, 2021, 41(6): 786-794.
[6]	TAN Bochuan, ZHANG Shengtao, LI Wenpo, XIANG Bin, QIANG Yujie. Food Spices 2,5-Dihydroxy-1,4-dithiane as an Eco-friendly Corrosion Inhibitor for X70 Steel in 0.5 mol/L H₂SO₄ Solution[J]. 中国腐蚀与防护学报, 2021, 41(4): 469-476.
[7]	WANG Lizi, LI Xianghong. Adsorption and Inhibition Behavior of Imidazoline on Steel Surface in Trichloroacetic Acid Solution[J]. 中国腐蚀与防护学报, 2021, 41(3): 353-361.
[8]	CHEN Wen, HUANG Dexing, WEI Feng. *Inhibition Effect of Brainea Insignis* Extract Against Carbon Steel Corrosion in HCl Solution**[J]. 中国腐蚀与防护学报, 2021, 41(3): 376-382.
[9]	LI Xianghong, DENG Shuduan, XU Xin. Inhibition Action of Cassava Starch Ternary Graft Copolymer on Steel in H₂SO₄ Solution[J]. 中国腐蚀与防护学报, 2020, 40(2): 105-114.
[10]	LV Xianghong,ZHANG Ye,YAN Yali,HOU Juan,LI Jian,WANG Chen. Performance Evaluation and Adsorption Behavior of Two New Mannich Base Corrosion Inhibitors[J]. 中国腐蚀与防护学报, 2020, 40(1): 31-37.
[11]	Zheng LIU, Haiying LI, Hao WANG, Yong ZHAO, Siwei XIE, Shufen ZHANG. Molecular Dynamics Simulation of Adsorption Behavior of Schiff Base Surfactants on Zn Surface in Aqueous Solution[J]. 中国腐蚀与防护学报, 2018, 38(4): 381-390.
[12]	Wanjun PENG, Jiheng DING, Hao CHEN, Haibin YU. Corrosion Inhibition of Bio-based Inhibitor Furfuryl Glycidyl Ether[J]. 中国腐蚀与防护学报, 2018, 38(3): 303-308.
[13]	Tianyi ZHANG,Junsheng WU,Hailong GUO,Xiaogang LI. Influence of HSO₃^- on Passive Film Composition and Corrosion Resistance of 2205 Duplex Stainless Steelin Simulated Seawater[J]. 中国腐蚀与防护学报, 2016, 36(6): 535-542.
[14]	Xiang ZUO,Yufeng JIANG,Ting CHI,Xin HU,Dongmei CAO,Feng CAI. Synthesis and Performance of New Benzotriazole Derivatives with Long Alkyl Chain as Corrosion Inhibitors[J]. 中国腐蚀与防护学报, 2016, 36(5): 415-420.
[15]	Chunxia WANG,Jingping CHEN,Xiaohong ZHANG,Chengyin WANG. Corrosion Inhibition of Octyl Isoquinolinium Bromide on Q235 Carbon Steel in HCl Solution[J]. 中国腐蚀与防护学报, 2016, 36(3): 245-252.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed