|
|
INHIBITION OF 1-PROPYL-2-METHYL-3-ALKYL BENZIMIDAZOLE ON Q235 STEEL IN HCl SOLUTION |
LI Xiangxu, YANG Wenzhong |
College of Science, Nanjing University of Technology, Nanjing 210009 |
|
|
Abstract ANew corrosion inhibitors 1-propyl-2-methyl-3-alkyl benzimidazole salts were synthesized and their inhibition for Q235 steel in 1 mol/L HCl solution were investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Meanwhile, the surface morphology was studied by scanning electron microscopy(SEM). The results showed that benzimidazole salts had excellent inhibiting efficiency at very low concentration and the inhibiting efficiency increased with the increase of alkyl chain. 1-propyl-2-methyl-3-tetradecyl benzimidazole salts had the highest efficiency among four inhibitors, in which the inhibition efficiency reached up to 98.6% at the concentration of 10 mg/L. These inhibitors acted as mixed inhibitors with cathodic inhibition as dominative action.
|
Received: 18 January 2011
|
|
Corresponding Authors:
YANG Wenzhong
E-mail: yangwz@njut.edu.cn
|
[1] Zhou X X, Liu J P. Present state of the application of corrosion inhibitors to acid pickling and its development trend[J].Industr. Water Treatment, 2002, 22(1): 16-19 (周晓湘, 刘建平.酸洗缓蚀剂的应用研究现状及发展趋势[J]. 工业水处理, 2002, 22(1):16-19)[2] Zhang S T, Xue M Y, Wang Y B, et al. Study on covering behavior of BTA inhibitor on pure copper surface[J]. Corros. Sci.Prot. Technol., 2006, 18(5): 313-316 (张胜涛, 薛名月,王艳波等.苯并三氮唑在铜表面覆盖行为的研究[J]. 腐蚀科学与防护技术,2006, 18(5): 313-316)[3] Zhao W, Zhang J P, Yin C X, et al. Corrosion inhibition mechanism of benzotriaole derivatives for N80 steel in HCl solution [J]. Corros. Sci. Prot. Technol., 2007, 19(4): 251-254 (赵雯,张军平, 尹成先等. 盐酸介质中苯并三氮唑衍生物的缓蚀机理研究[J].腐蚀科学与防护技术, 2007, 19(4): 251-254)[4] Raicheva S N, Aleksiev B V, Sokolova E I. The effect of the chemical structure of some nitrogen and sulphur containing organic compounds on their corrosion inhibiting action [J]. Corros.Sci., 1992, (2): 343-350[5] Khaled K F. The inhibition of benzimidazole derivatives on corrosion of iron in 1 M HCl solutions [J]. Electrochim. Acta, 2003,48: 2493-2503[6] Shi Z L, Pang Z Z. Efficiency of arylsubstituted-benz-imidazoles as copper corrosion inhibitors in HCl solution [J]. J. Beijing Univ. Chem. Technol., 2002, 29(2):52-54 (史志龙, 庞正智. 新型铜酸洗缓蚀剂烷基苯并咪唑的研究[J].北京化工大学学报, 2002, 29 (2): 52-54)[7] Ashassi-Sorkhabi H, Majidi M R, Seyyedi K. Investigation of inhibition effect of some amino acids against steel corrosion in HCl solution [J]. Appl. Surf. Sci., 2004, 225: 176-185[8] Solmaz R, Kardas G, Yazici B, et al. Adsorption and corrosion inhibitive properties of 2-amino-5-mercapto-1, 3, 4-thiadiazole on mild steel in hydrochloric acid media [J]. Colloids Surf. A: Physicochem. Eng. Aspects, 2008, 312: 7-17[9] Aljourani J, Raeissi K, Golozar M A. Benzimidazole and its derivatives as corrosion inhibitors for mild steel in 1 mol/L HCl solution [J]. Corros. Sci., 2009, 51: 1836-1843 |
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|