Please wait a minute...
J Chin Soc Corr Pro  2004, Vol. 24 Issue (5): 306-310     DOI:
Research Report Current Issue | Archive | Adv Search |
Corrosion Inhibition Effect of Triazole Derivatives to Carbon Steel in Hydrochloric Acid Solution
Huilong Wang
大连理工大学化学系288信箱
Download:  PDF(173KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  Two kinds of new triazole compounds were synthesized. Their inhibiting behavior on carbon steel in 1.0mol/L hydrochloric acid solutio was investigated by means of weight loss, potentiodynamic polarization and AC impedance methods. The results show that the triazole derivatives suppress both the anosic and cathodic process and the inhibition effect is caused by geometrical blocking of the metal surface by adsorbed inhibiting species. The investigated triazole compounds inhibit corrosion by adsorption mechanis and the adsorption leads to the formation of a protective chemisorbed film on the metal surface which suppresses the corresponding corrosion reaction. The synthesized triazole compounds are found to be excellent corrosion inhibitor for carbon steel in hydrochloric acid.
Key words:  triazole compound      carbon steel      corrosion      inhibitor      
Received:  28 April 2003     
ZTFLH:  TG174.42  
Corresponding Authors:  Huilong Wang     E-mail:  hlwang@dlut.edu.cn

Cite this article: 

Huilong Wang. Corrosion Inhibition Effect of Triazole Derivatives to Carbon Steel in Hydrochloric Acid Solution. J Chin Soc Corr Pro, 2004, 24(5): 306-310 .

URL: 

https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2004/V24/I5/306

[1]BentissF ,TraisnelM ,GengembreL ,etal.Inhibitionofacidiccorro sionofmildsteelby3,5-diphenyl-4H -1,2,4-triazole[J].Ap pl.Surf.Sci.,2000,161:194-202
[2]ElHajjajiS ,LgarnriA ,AzianeD ,etal.Synthesisandevaluationoftheinhibitioneffectofanewclassoftriazolecompounds[J].ProgressinOrganicCoatings,2000,38(3/4):207-212
[3]MernariB ,El-AttariH ,TraisnelM ,etal.Inhibitingeffectsof3,5-bis(n-pyridyl)-4-amino-1,2,4-triazoleonthecorrosionformildsteelin1MHClmedia[J].Corros.Sci.,1998,40(2/3):391-399
[4]QuraishiMA ,MuralidharanS ,IyerSVK .Influenceof4-amino-5-mercapto-3n-propyl-1,2,4-triazoleonthecorrosionandpermeationthroughmildsteelinacidicsolutions[J].Anti-Cor rosionMethodsandMaterials,2000,47(6):354-358
[5]VaralakshmiC ,RaoBVAppa.Inhibitionofcorrosionofcopperby5-mercapto-3-p-nitrophenyl-1,2,4-triazoleinaqueousen vironment[J].Anti-CorrosionMethodsandMaterials,2001,48(3):171-180
[6]QuraishiMA ,AhmadS ,AnsariMQ .Inhibitionofsteelcorrosionbysomenewtriazolederivativesinboilinghydrochloricacid[J].Br.Corros.J.,1997,32(4):297-300
[7]QuraishiMA ,JamalDanish.CorrosioninhibitionofN -80steelandmildsteelin15%boilinghydrochloricacidbyatriazolecom pound-SAHMT [J].MaterialsChemistryandPhysics,2001,68:283-287
[8]BentissF ,LagreneeM ,TraisnelM .Thecorrosioninhibitionofmildsteelinacidicmediabyanewtriazolederivative[J].Corros.Sci.,1999,41(4):789-803
[9]DubeySN ,KaushikB .Triazolesascomplexingagent:synthesis&characterisationofcobalt(Ⅱ),nickel(Ⅱ),copper(Ⅰ),copper(Ⅱ),zinc(Ⅱ)&cadmium(Ⅱ)complexeswith4-amino-5-mercapto-3-n-propyl-5-triazole&5-mercapto-3-n-propyl-4-salicylidineamino-s-triazole[J].Ind.J .Chem.,1985,24A(11):950-953
[10]CaoChu’nan.Ontheelectrochemicaltechniquesforinvestigationofinhibitors[J].Corros.Sci.Prot.Technol.,1990,2(1):1-8(曹楚南.关于缓蚀剂研究的电化学方法[J].腐蚀科学与防护技术,1990,2(1):1-8)
[11]CaoChu’nan.Studyontheelectrodeprocessesatmixedpotentials[J].Corros.Sci.Prot.Technol.,1998,10(1):1-5(曹楚南.混合电位下的电极过程研究[J].腐蚀科学与防护技术,1998,10(1):1-5)
[12]BastidasJM ,DeDamboreneaJ ,V偄zquezAJ.Butylsubstituentsinn-butylamineandtheirinfluenceonmildsteelcorrosioninhibitioninhy drochloricacid[J].J.Appl.Electrochem.,1997,27(3):345-349
[1] HUANG Peng, GAO Rongjie, LIU Wenbin, YIN Xubao. Fabrication of Superamphiphobic Surface for Nickel-plate on Pipeline Steel by Salt Solution Etching and Its Anti-corrosion Properties[J]. 中国腐蚀与防护学报, 2021, 41(1): 96-100.
[2] DONG Xucheng, GUAN Fang, XU Liting, DUAN Jizhou, HOU Baorong. Progress on the Corrosion Mechanism of Sulfate-reducing Bacteria in Marine Environment on Metal Materials[J]. 中国腐蚀与防护学报, 2021, 41(1): 1-12.
[3] TANG Rongmao, ZHU Yichen, LIU Guangming, LIU Yongqiang, LIU Xin, PEI Feng. Gray Correlative Degree Analysis of Q235 Steel/conductive Concrete Corrosion in Three Typical Soil Environments[J]. 中国腐蚀与防护学报, 2021, 41(1): 110-116.
[4] HAN Yuetong, ZHANG Pengchao, SHI Jiefu, LI Ting, SUN Juncai. Surface Modification of TA1 Bipolar Plate for Proton Exchange Membrane Fuel Cell[J]. 中国腐蚀与防护学报, 2021, 41(1): 125-130.
[5] ZHANG Yuxuan, CHEN Cuiying, LIU Hongwei, LI Weihua. Research Progress on Mildew Induced Corrosion of Al-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 13-21.
[6] RAN Dou, MENG Huimin, LIU Xing, LI Quande, GONG Xiufang, NI Rong, JIANG Ying, GONG Xianlong, DAI Jun, LONG Bin. Effect of pH on Corrosion Behavior of 14Cr12Ni3WMoV Stainless Steel in Chlorine-containing Solutions[J]. 中国腐蚀与防护学报, 2021, 41(1): 51-59.
[7] BAI Yunlong, SHEN Guoliang, QIN Qingyu, WEI Boxin, YU Changkun, XU Jin, SUN Cheng. Effect of Thiourea Imidazoline Quaternary Ammonium Salt Corrosion Inhibitor on Corrosion of X80 Pipeline Steel[J]. 中国腐蚀与防护学报, 2021, 41(1): 60-70.
[8] ZUO Yong, CAO Mingpeng, SHEN Miao, YANG Xinmei. Effect of Mg on Corrosion of 316H Stainless Steel in Molten Salts MgCl2-NaCl-KCl[J]. 中国腐蚀与防护学报, 2021, 41(1): 80-86.
[9] WANG Yating, WANG Kexu, GAO Pengxiang, LIU Ran, ZHAO Dishun, ZHAI Jianhua, QU Guanwei. Inhibition for Zn Corrosion by Starch Grafted Copolymer[J]. 中国腐蚀与防护学报, 2021, 41(1): 131-138.
[10] WANG Xintong, CHEN Xu, HAN Zhenze, LI Chengyuan, WANG Qishan. Stress Corrosion Cracking Behavior of 2205 Duplex Stainless Steel in 3.5%NaCl Solution with Sulfate Reducing Bacteria[J]. 中国腐蚀与防护学报, 2021, 41(1): 43-50.
[11] SHI Kunyu, WU Weijin, ZHANG Yi, WAN Yi, YU Chuanhao. Electrochemical Properties of Nb Coating on TC4 Substrate in Simulated Body Solution[J]. 中国腐蚀与防护学报, 2021, 41(1): 71-79.
[12] ZHENG Li, WANG Meiting, YU Baoyi. Research Progress of Cold Spraying Coating Technology for Mg-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 22-28.
[13] WEI Zheng, MA Baoji, LI Long, LIU Xiaofeng, LI Hui. Effect of Ultrasonic Rolling Pretreatment on Corrosion Resistance of Micro-arc Oxidation Coating of Mg-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 117-124.
[14] YU Hongfei, SHAO Bo, ZHANG Yue, YANG Yange. Preparation and Properties of Zr-based Conversion Coating on 2A12 Al-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 101-109.
[15] ZHANG Hao, DU Nan, ZHOU Wenjie, WANG Shuaixing, ZHAO Qing. Effect of Fe3+ on Pitting Corrosion of Stainless Steel in Simulated Seawater[J]. 中国腐蚀与防护学报, 2020, 40(6): 517-522.
No Suggested Reading articles found!