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IN-SITU STM STUDY ON DYNAMIC BEHAVIOR OF CORROSIONAND INHIBITION OF REBAR STEEL IN DIFFERENTSIMULATED CONCRETE PORE SOLUTION |
Ronggang Hu;Ronggui Du;Minhua Shao |
厦门大学化学化工学院 固体表面物理化学国家重点实验室 |
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Abstract In this paper,in situ scanning tunneling microscopy (STM)was employed to investigate morphological changes on the surface of reinfo rcing steel immersed in simulated concrete pore solutions(saturated calcium hyd roxide).The effect of chloride,pH value and LD-2 compound inhibitor on surface m orphology were studied.The sequence of images recorded in different solutions tr acked the process of formation and breakdown of passive film on steel surface.Th e result with spatial resolution in the order of nanometer obtained from STM exp eriment is able to provide additional information beyond electrochemical paramet ers and beneficial to better understanding of the mechanism of growth and breaki ng down of passive film on the surface of reinforcing steel.
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Received: 03 June 2002
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Corresponding Authors:
Ronggang Hu
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[1]HuYL ,HuRG ,ShaoMH ,LinCJ.InsituECSTMinvestigationonformationandbreakdownofpassivefilmforpolycrystallinestain lesssteel[J].ActaMetall.Sin.,2001,37(9):965-970(胡艳玲,胡融刚,邵敏华,林昌健.不锈钢钝化膜形成和破坏过程的原位ECSTM研究[J].金属学报,2001,37(9):965-970) [2]MauriceV ,StrehblowHH ,MarcusP .InsituSTMstudyoftheini tialstagesofoxidationofCu(111)inaqueoussolution[J].Surf.Sci.,2000,458(1-3):185-194 [3]VogtMR ,LachenwitzerR ,MagnussenOM ,BehmRJ.In-situSTMstudyoftheinitialstagesofcorrosionofCu(100)electrodesinsulfuricandhydrochloricacidsolution[J].Surf.Sci.,1998,399(1):49-69 [4]SzirakiL ,SzocsE ,PilbathZs,PappK ,KalmanE .Studyoftheini tialstageofwhiterustformationonzincsinglecrystalbyEIS .STM/AFMandSEM/EDStechniques[J].Electrochim.Acta,2001,46(24-25):3743-3754 [5]DuRG ,WangZC ,HuangRS ,etal.StudyontheanticorrosionofLD -2compoundinhibitoronreinforcingsteelinseawater[J].Electrochemistry,2001,7(4):494-500(杜荣归,王周成,黄若双等.LD -2复合缓蚀剂对海水介质混凝土中钢筋阻锈作用研究[J].电化学,2001,7(4):494-500) [6]HongDH .Corrosionandprotectionofreinforcingsteelinconcrete[M].Beijing:ChineseRailwayPress,1998:16(洪定海.混凝土中钢筋的腐蚀与防护[M ].北京:中国铁道出版社,1998:16) [7]ChineseSocietyforCorrosionandProtection,YangW ,GuXJ,LiQS ,XiaoJX .LocalizationCorrosionofMetals[M ].Beijing:ChemicalIndustryPress.1993:45(中国腐蚀与防护学会,杨武,顾祥氵睿,黎樵焱木,肖京先.金属的局部腐蚀[M].北京:化学工业出版社,1993:45) |
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