XPS Analysis of Corrosion Product Scale on Surface of Silver-bearing Antibacterial Duplex Stainless Steel

doi:10.11902/1005.4537.2017.042

Journal of Chinese Society for Corrosion and protection

2018, Vol. 38

Issue (6): 533-542 DOI: 10.11902/1005.4537.2017.042

Current Issue | Archive | Adv Search

XPS Analysis of Corrosion Product Scale on Surface of Silver-bearing Antibacterial Duplex Stainless Steel

Dong LIU,Hongliang XIANG(

),Chunyu LIU

1. School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou 350116, China

Download:

HTML

PDF(5152KB)
Export: BibTeX | EndNote (RIS)

Abstract

Silver-bearing antibacterial duplex stainless steels were prepared by adding silver granules (code name A) or 150~300 μm Cu-Ag particles (code name B) respectively. The two steels were then subjected to solid solution treatment at 1150 ℃. The surface passive films formed on the two steels after potentiodynamic polarization test in bacteria bearing liquid were analyzed by X-ray photoelectron spectroscopy (XPS). The results indicated that there exist silver as atomic Ag and oxide AgO, while chromium as CrO₂, CrO₃and Cr(OH)₃in the surface passive film of the steel A. However silver as oxides of AgO, Ag₂O and Ag₃O, while Cr as chromic oxides of multi-valence present in the surface passive film of the steel B. In comparison with the passive film on the steel A, that on the steel B has higher amount of Cr₂O₃, molybdenum oxides and MoO₄^2-, but lower amount of hydroxides/hydrates, meaning that the stability of the passive film on the steel B is better.

Key words: silver-bearing antibacterial duplex stainless steel passive film XPS technology

Received: 17 March 2017

ZTFLH:

TG174.3

Fund: Supported by Major Projects Fund from Fujian(2017HZ0001);Industrial Technology Joint-Innovation Projects of Fujian(FG-2016001);Young and Middle-aged Scientific Research Project from Fujian Education Department(JAT160066);Science and Technology Project of Fuzhou(2018-G-68);Marine High-tech Industry Development of Fujian ((2014)14)

Corresponding Authors: Hongliang XIANG E-mail: hlxiang@fzu.edu.cn

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Dong LIU
	Hongliang XIANG
	Chunyu LIU

Cite this article:

Dong LIU,Hongliang XIANG,Chunyu LIU. XPS Analysis of Corrosion Product Scale on Surface of Silver-bearing Antibacterial Duplex Stainless Steel. Journal of Chinese Society for Corrosion and protection, 2018, 38(6): 533-542.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2017.042 OR https://www.jcscp.org/EN/Y2018/V38/I6/533

Fig.1 Potentiodynamic polarization curves of the specimens A and B in bacteria-free (a) and bacteria environments (b)

Table 1 Binding energies and relative contents of O1s

Fig.2 Narrow XPS of O1s in passive film for samples A (a~d) and B (e~h) after sputtering for 0 s (a, e), 10 s (b, f), 20 s (c, g) and 30 s (d, h)

Fig.3 Narrow XPS of Ag3d_5/2in passive film for samples A (a~d) and B (e~h) after sputtering for 0 s (a, e), 10 s (b, f), 20 s (c, g) and 30 s (d, h)

Table 2 Binding energies and relative contents of Ag3d_5/2

Table 3 Binding energies and relative contents of Fe2p_3/2

Fig.4 Narrow XPS of Fe2p_3/2in passive film for samples A (a~d) and B (e~h) after sputtering for 0 s (a, e), 10 s (b, f), 20 s (c, g) and 30 s (d, h)

Fig.5 Narrow XPS of Cr2p in passive film for samples A (a~d) and B (e~h) after sputtering for 0 s (a, e), 10 s (b, f), 20 s (c, g) and 30 s (d, h)

Table 4 Binding energies and relative contents of Cr2p

Fig.6 Narrow XPS of Mo3d_5/2in passive film for samples A (a~d) and B (e~h) after sputtering for 0 s (a, e), 10 s (b, f), 20 s (c, g) and 30 s (d, h)

Table 5 Binding energies and relative contents of Mo3d_5/2

[1]	Zhang Y,Li Q,Wang S G.Corrosion resistance of 2507 duplex stainless steel in NaClO solution[J]. J. Mater. Eng.,2016,44(1):108
[1]	张艳,李倩,王胜刚.2507双相不锈钢在NaClO溶液中的腐蚀性能[J].材料工程,2016,44(1):108
[2]	Santamaria M,Di Franco F,Di Quarto F,et al.Photoelectrochemical and XPS characterisation of oxide layers on 316L stainless steel grown in high-temperature water[J]. J. Solid State Electrochem.,2015,19(2):3511
[3]	Tardio S,Abel M L,Carr R H.Comparative study of the native oxide on 316L stainless steel by XPS and ToF-SIMS[J]. J Vac. Sci. Technol. A,2015,33(5):1
[4]	Wang Y W,Jiang R J,Zhao J M.The properties of passive films formed on 316L and 316LN stainless steel in high-temperature and high-salinity solution[J]. J Univ Beijing. Chem. Tech. (Nat. Sci.),2017,44(5):72
[4]	王育武,姜瑞景,赵景茂.316L和316LN不锈钢在高温高盐溶液中钝化膜的性能研究[J].北京化工大学学报 (自然科学版),2017,44(5):72
[5]	Xiang H L,Guo P P,Liu D.Microstructure and antibacterial properties of Ag-bearing duplex stainless steel[J].Acta Metall. Sin.,2014,50:1210
[5]	向红亮,郭培培,刘东.含Ag抗菌双相不锈钢组织及抗菌性能研究[J].金属学报,2014,50:1210
[6]	Feng D M,Wang J Q,Wu W H.Introduction to Electronic Spectroscopy (XPS/XAES/UPS)[M].Beijing:National Defence Industry Press,1992
[6]	冯大明,王建祺,吴文辉.电子能谱学 (XPS/XAES/UPS) 引论[M].北京:国防工业出版社,1992)
[7]	Liu S H.X-ray Photoelectron Spectroscopy Analysis[M].Beijing:Science Press,1988
[7]	刘世宏.X射线光电子能谱分析[M].北京:科学出版社,1988)
[8]	Liu G Q,Zhu Z Y,Ke W.The pitting of stainless and nickel-based alloys in acetic acid solution containing bromine ion[J].Acta Metall. Sin.,2001,37:275
[8]	刘国强,朱自勇,柯伟.不锈钢及镍基合金在含溴醋酸中的点蚀行为[J].金属学报,2001,37:275
[9]	Zhang L,Han E-H,Zhang Z E,et al.The corrosion of stainless steel and nickel base alloys in subcritical water condition[J].Acta Metall.Sin.,2003,39:649
[9]	张丽,韩恩厚,张召恩等.不锈钢及镍基合金在亚临界水环境中的腐蚀[J].金属学报,2003,39:649
[10]	Wang Z C,Zhang Y Z,Zhou S M,et al.Corrosion compositions of carbon steel under ion-selective coatings by XPS[J]. J Chin. Soc. Corros. Prot., 2001,21:273
[10]	王周成, 张瀛洲, 周绍民等. 离子选择性涂层下碳钢表面腐蚀产物的XPS分析[J].中国腐蚀与防护学报,2001,21:273
[11]	Kumagai M,Myung S,Asaishi R,et al.High nitrogen stainless steel as bipolar plates for proton exchange membrane fuel cells[J]. J. Power Sources,2008,54(3):815
[12]	He G,Gao Q W.Corrosion performance of enviroment-friendly chemical conversion films on mild steel[J].Corros. Sci. Prot. Technol.,2009,21:66
[12]	何刚,高勤卫.钢铁表面环保型杂多酸化学转化膜的耐蚀性[J].腐蚀科学与防护技术,2009,21:66
[13]	Huang C,Shih C.Effects of nitrogen and high temperature aging onσphase precipitation of duplex stainless steel[J].Mater. Sci. Eng.,2005,A402(1/2):66
[14]	Maurice V,Yang W P,Marcus P.X-Ray photoelectron spectroscopy and scanning tunneling microscopy study of passive films formed on (100) Fe-18Cr-13Ni single-crystal surfaces[J]. J. Electrochem. Sci.,1998,145(3):909
[15]	Xu C C,Wu X M.Mechanism of MoO42-retarding the development of the local corrosion in 304 stainless steel/Cl-solution[J].Chin. J. Mater. Res.,2002,16:354
[15]	许淳淳,吴小梅.MoO42-抑制AISI304不锈钢局部腐蚀的机理[J].材料研究学报,2002,16:354

[1]	SHI Kunyu, WU Weijin, ZHANG Yi, WAN Yi, YU Chuanhao. Electrochemical Properties of Nb Coating on TC4 Substrate in Simulated Body Solution[J]. 中国腐蚀与防护学报, 2021, 41(1): 71-79.
[2]	ZHANG Rui,LI Yu,GUAN Lei,WANG Guan,WANG Fuyu. Effect of Heat Treatment on Electrochemical Corrosion Behavior of Selective Laser Melted Ti6Al4V Alloy[J]. 中国腐蚀与防护学报, 2019, 39(6): 588-594.
[3]	Shaokun YAN,Dajiang ZHENG,Jiang WEI,Guangling SONG,Lian ZHOU. Electrochemical Activation of Passivated Pure Titanium in Artificial Seawater[J]. 中国腐蚀与防护学报, 2019, 39(2): 123-129.
[4]	Ming LIU,Xuequn CHENG,Xiaogang LI,Tianjian LU. Corrosion Resistance Mechanisms of Passive Films Formed on Low Alloy Rebar Steels in Liquor of Cement Extract[J]. 中国腐蚀与防护学报, 2018, 38(6): 558-564.
[5]	Zihan LIAO, Bo SONG, Ze REN, Chuan HE, Xu CHEN. Electrochemical Corrosion Behavior of Matrix and Weld Seam of X70 Steel in Na₂CO₃+NaHCO₃ Solutions[J]. 中国腐蚀与防护学报, 2018, 38(2): 158-166.
[6]	Guangyu LI, Mingkai LEI. Composition and Semi-conductive Characteristic of Passive Film Formed on γ_Ν-phase in a Borax Buffer Solution[J]. 中国腐蚀与防护学报, 2018, 38(1): 47-53.
[7]	Tianyi ZHANG,Junsheng WU,Hailong GUO,Xiaogang LI. Influence of HSO₃^- on Passive Film Composition and Corrosion Resistance of 2205 Duplex Stainless Steelin Simulated Seawater[J]. 中国腐蚀与防护学报, 2016, 36(6): 535-542.
[8]	Jianchun ZHANG,Jingyang JIANG,Yang LI,Jinjie SHI,Longfei ZUO,Danqian WANG,Han MA. Passive Films Formed on Seawater Corrosion Resistant Rebar 00Cr10MoV in Simulated Concrete Pore Solutions[J]. 中国腐蚀与防护学报, 2016, 36(5): 441-449.
[9]	Xinqiang WU,Yao FU,Wei KE,Song XU,Bing FENG,Botao HU,Jiazheng LU. Corrosion Behavior of High Nitrogen Austenitic Stainless Steels[J]. 中国腐蚀与防护学报, 2016, 36(3): 197-204.
[10]	Yangheng LI,Yu ZUO,Yuming TANG,Xuhui ZHAO. Pitting Corrosion Behavior of Q235 Carbon Steel in NaHCO₃+NaCl Solution under Strain[J]. 中国腐蚀与防护学报, 2016, 36(3): 238-244.
[11]	ZHAO Yang,LIANG Ping,SHI Yanhua,WANG Bingxin,LIU Feng,WU Zhanwen. Comparison of Passive Films on X100 and X80 Pipeline Steels in NaHCO₃ Solution[J]. 中国腐蚀与防护学报, 2013, 33(6): 455-462.
[12]	LIU Zuojia,CHENG Xuequn,LI Xiaogang,LIU Xiaohui. Application of PDM (Point Defect Model) on 2205 Duplex Stainless Steel[J]. 中国腐蚀与防护学报, 2013, 33(2): 90-96.
[13]	FAN Lin,LI Xiaogang,DU Cuiwei,LIU Zhiyong. ELECTROCHEMICAL BEHAVIOR OF PASSIVE FILMS FORMED ON X80 PIPELINE STEEL IN VARIOUS CONCENTRATED NaHCO₃ SOLUTIONS[J]. 中国腐蚀与防护学报, 2012, 32(4): 322-326.
[14]	QIAO Yanxin, REN Ai, LIU Feihua. ELECTROCHEMICAL BEHAVIOR OF ALLOY 690 IN NaCl SOLUTION[J]. 中国腐蚀与防护学报, 2012, 32(2): 146-150.
[15]	ZHANG Shenghan, LIAN Jia, TAN Yu. SEMICONDUCTOR CHARACTER OF PASSIVE FILMS FORMED ON 304L STAINLESS STEEL IN ZINC CONTAINED HIGH TEMPERATURE WATER[J]. 中国腐蚀与防护学报, 2011, 31(6): 483-487.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed