Prediction Model for Corrosion of Aluminum 1060 in Marine Atmospheric Environments

doi:10.11902/1005.4537.2015.145

Journal of Chinese Society for Corrosion and protection

2016, Vol. 36

Issue (4): 349-356 DOI: 10.11902/1005.4537.2015.145

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Prediction Model for Corrosion of Aluminum 1060 in Marine Atmospheric Environments

Haixia LIU¹,Xuequn CHENG^1,²(

),Xiaogang LI^1,^2,³,Kui XIAO^1,²,Chaofang DONG^1,²

1. Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, China
2. Key Laboratory for Corrosion and Protection (MOE), University of Science and Technology Beijing, Beijing 100083, China
3. Ningbo Institute of Material Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China

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Abstract

The corrosion behavior of pure aluminum A1060 in tropic marine environment was simulated by cyclic immersion test, while the correlation of the corresponding results of indoor cyclic immersion test and outdoor marine atmospheric corrosion test of A1060 was comparatively studied in terms of its corrosion morphology, corrosion products and corrosion kinetics by means of weight loss measurement scanning, electron microscope (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD). The results showed that the corrosion morphologies and phase constituents compositions of corrosion products after cyclic immersion test agreed fairly well with those after the real atmospheric test. Thereafter, a prediction model for the C corrosion prediction model of aluminum 1060 in two kinds of marine atmospheric environments, which aims to simulate the atmospheric environments at Wanning and Xisha areas in the South China Sea, was established built combined with Grey correlation method, while the corresponding arithmetic expressions could be described as follows i.e. T_WN=146.7t^1.29 and T_XS=862.3t^0.85 respectively.

Key words: A1060 marine atmosphere corrosion life prediction

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	Haixia LIU
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Cite this article:

Haixia LIU,Xuequn CHENG,Xiaogang LI,Kui XIAO,Chaofang DONG. Prediction Model for Corrosion of Aluminum 1060 in Marine Atmospheric Environments. Journal of Chinese Society for Corrosion and protection, 2016, 36(4): 349-356.

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https://www.jcscp.org/EN/10.11902/1005.4537.2015.145 OR https://www.jcscp.org/EN/Y2016/V36/I4/349

Table 1 Climatic parameters and atmospheric pollutants of atmospheric test station^[14,15]

Fig.1 SEM images of corrosion products formed on pure A1060 after cyclic immersion experiments for 720 h in 1% (a), 2% (b), 3.5% (c) and 5% (d) NaCl solutions

Fig.2 Surface images of pure A1060 after removing of corrosion products formed during cyclic experiment for 720 h in 1% (a), 2% (b), 3.5% (c) and 5% (d) NaCl solutions

Fig.3 EDS results of the surfaces of A1060 pure aluminum after cyclic immersion experiments in NaCl solutions

Fig.4 XRD spectrum of A1060 aluminum after 720 h cyclic immersion experiment in 5%NaCl solution

Fig.5 Weight loss curves of A1060 pure aluminum during cyclic immersion in 1% (a), 2% (b), 3.5% (c) and 5% (d) NaCl solutions

Table 2 Fitting data of corrosion kinetic curves

Table 3 Statistical magnitude of corrosion mass loss in Wanning

Table 4 Statistical magnitude of corrosion mass loss in isha

Table 5 Pretreatment results of corrosion mass loss in Wanning

Table 6 Pretreatment results of corrosion mass loss inXisha

Table 7 Grey correlations of atmospheric exposuretests and accelerated tests

Fig.6 γ and K of A1060 for the corrosion in various NaCl solutions used to simulate Wanning marine atmospheric environment

Fig.7 γ and K of A1060 for the corrosion in various NaCl solutions used to simulate Xisha marine atmospheric environment

Table 8 Indoor simulated accelerated timetable obtained based on prediction model for corrosion of A1060 in anning and Xisha

[1]	An B G, Zhang X Y, Han E-H, et al.Current status of atmospheric corrosion of aluminium and aluminium alloys[J]. Chin. J. Nonferrous Met., 2001, 11(z2): 11
[1]	(安百刚, 张学元, 韩恩厚. 铝和铝合金的大气腐蚀研究现状[J]. 中国有色金属学报, 2001, 11(z2): 11)
[2]	Li T, Li X G, Dong C F, et al.Characterization of atmospheric corrosion of 2A12 aluminum alloy in tropical marine environment[J]. J. Mater. Eng. Perform., 2010, 19(4): 591
[3]	Sun S, Zheng Q, Li D, et al.Exfoliation corrosion of extruded 2024-T4 in the coastal environments in China[J]. Corros. Sci., 2011, 53(8): 2527
[4]	Sun S, Zheng Q, Li D, et al.Long-term atmospheric corrosion behaviour of aluminium alloys 2024 and 7075 in urban, coastal and industrial environments[J]. Corros. Sci., 2009, 51(4): 719
[5]	Luo L.Method of salt spray test[J]. Equip. Environ. Eng., 2011, 8(4): 77
[5]	(罗兰. 盐雾试验方法探讨[J]. 装备环境工程, 2011, 8(4): 77)
[6]	Xu N X, Zhang C D, Ding C H.A new scheme to accelerate the atmospheric corrosion test[J]. J. Chin. Soc. Corros. Prot., 1990,10(3): 228
[6]	(徐乃欣, 张承典, 丁翠红. 加速大气腐蚀试验的一个新方案[J]. 中国腐蚀与防护学报, 1990, 10(3): 228)
[7]	Li J L M S Z. Development of an artificial climatic complex accelerated corrosion tester and investigation of complex accelerated corro ion test methods[J]. Environ. Technol., 1999, 55(5): 498
[8]	Wang J, Wang Z Y, Ke W.Corrosion behaviour of weathering steel in diluted Qinghai salt lake water in a laboratory accelerated test that involved cyclic wet/dry condition[J]. Mater. Chem. Phys., 2010, 124(2): 952
[9]	Wei J, Fu X X, Dong J H, et al.Corrosion evolution of reinforcing steel in concrete under dry/wet cyclic conditions contaminated with chloride[J]. J. Mater. Sci. Technol., 2012, 28(10): 905
[10]	Lyon S B, Thompson G E.Accelerated atmospheric corrision testing using a cyclic wet/dry exposure test: alunimum, galvanized steel, and steel[J]. Corrosion, 1987, 43(12): 719
[11]	Wang Z Y, Yu G C, Han W.Correlation between atmospheric exposure corrosion and indoor accelerated corrosion simulation of steel[J]. Corros. Sci. Prot. Technol., 2004, 16(2): 70
[11]	(王振尧, 于国才, 韩薇. 钢的大气暴露腐蚀与室内模拟加速腐蚀的相关性[J]. 腐蚀科学与防护技术, 2004, 16(2): 70)
[12]	Zheng Q F, Sun S Q, Wen J G.Atmospheric corrosion and it's influence factors in aluminum and aluminum alloys in China[J]. Corros. Prot., 2009, 30(6): 359
[12]	(郑弃非, 孙霜青, 温军国. 铝及铝合金在我国的大气腐蚀及其影响因素分析[J]. 腐蚀与防护, 2009, 30(6): 359)
[13]	Montoya P, Díaz I, Granizo N, et al.An study on accelerated corrosion testing of weathering steel[J]. Mater. Chem. Phys., 2013, 142(1): 220
[14]	Cui Z Y, Li X G, Xiao K, et al.Atmospheric corrosion behaviour of pure Al 1060 in tropical marine environment[J]. Corros. Eng. Sci. Technol., 2015, 50(6): 438
[15]	Cao C N.Natural Environmental Corrosion of Chinese Materials[M]. Beijing: Chemical Industry Press, 2005
[15]	(曹楚南. 中国材料的自然环境腐蚀 [M]. 北京: 化学工业出版社, 2005)
[16]	Cai J P, Liu M, Luo Z H, et al.Study on accelerated tests for aluminum alloy atmospheric corrosion[J]. J. Chin. Soc. Corros. Prot.,2005, 25(5): 262
[16]	(蔡建平, 刘明, 罗振华等. 航空铝合金大气腐蚀加速试验研究[J]. 中国腐蚀与防护学报, 2005, 25(5): 262)
[17]	Lin C, Wang F P, Li X G.Progress of atmospheric corrosion research[J]. J. Chin. Soc. Corros. Prot., 2004, 24(4): 245
[17]	(林翠, 王凤平, 李晓刚. 大气腐蚀研究方法进展[J]. 中国腐蚀与防护学报, 2004, 24(4): 245)
[18]	Wang L, Mou X L, Zhu L.Review of atmospheric corrosivity classification. Equipment environmental engineering[J]. 2010, 7(6): 24
[18]	(王玲, 牟献良, 朱蕾等. 大气环境腐蚀性分类分级研究综述[J]. 装备环境工程, 2010, 7(6): 24)
[19]	Wang Z Y, Ma T, Han W, et al.Corrosion behavior on aluminum alloy LY 12 in simulated atmospheric corrosion process[J]. Trans. Nonferrous Met. Soc. China, 2007, 17: 326
[20]	Boxley C J.Al203 film dissolution in aqueous chloride solutions[J]. Electrochem. Solid State Lett., 2003, 6(10): 38
[21]	El-Mahdy G A, Kim K B. AC impedance study on the atmospheric corrosion of aluminum under periodic wet-dry conditions[J]. Electrochim. Acta, 2004, 49(12): 1937
[22]	Szklarska-Smialowska Z.Pitting corrosion of aluminum[J]. Corros. Sci., 1999, 41(9): 1743
[23]	Boag A, Taylor R J, Muster T H, et al.Stable pit formation on AA2024-T3 in a NaCl environment[J]. Corros. Sci., 2010, 52(1): 90
[24]	Zhu H M, Zheng Q F, Xie S S.Atmospheric corrosion of Al and Al alloy in wanning area[J]. Rare Met., 2002, 26(6): 456
[24]	(朱红嫚, 郑弃非, 谢水生. 万宁地区铝及铝合金不同距海点的大气腐蚀研究[J]. 稀有金属, 2002, 26(6): 456)
[25]	Grilli R, Baker M A, Castle J E, et al.Localized corrosion of a 2219 aluminium alloy exposed to a 3.5%NaCl solution[J]. Corros. Sci., 2010, 52(9): 2855
[26]	Zhou H R, Li X G, Dong C F.Review of atmospheric corrosion behavior and mechanism of aluminum alloys and it's anodic film[J]. Equip. Environ. Eng., 2006, 3(1): 1
[26]	(周和荣, 李晓刚, 董超芳. 铝合金及其氧化膜大气腐蚀行为与机理研究进展[J]. 装备环境工程, 2006, 3(1): 1)
[27]	Pyun S I, Moon S M, Ahn S H, et al.Effects of Cl-, NO3- and SO42- ions on anodic dissolution of pure aluminum in alkaline solution[J]. Corros. Sci., 1999, 41: 653
[28]	Mou X L,Tian Y E, Wang X H.Correlation between accelerated test and atmospheric corrosion test for carbon steel and low alloy steel[J]. Environ. Technol., 2001, (4): 14
[28]	(牟献良, 田月娥, 汪学华. 碳钢和低合金钢模拟加速试验与大气腐蚀试验的相关性[J]. 环境技术, 2001, (4): 14)
[29]	Tian Y W, Cheng X Q, Li X G.A study of simulated indoor accelerated testing method for marine atmospheric corrosion[J]. Corros. Prot., 2014, 35(8): 781
[29]	(田玉琬, 程学群, 李晓刚. 海洋大气腐蚀的室内模拟加速试验方法研究[J]. 腐蚀与防护, 2014, 35(8): 781)

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