盐溶液刻蚀-氟化处理制备X65管线钢镀镍超双疏表面及其耐蚀性研究

doi:10.11902/1005.4537.2020.008

中国腐蚀与防护学报

2021, Vol. 41

Issue (1): 96-100 DOI: 10.11902/1005.4537.2020.008

研究报告

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盐溶液刻蚀-氟化处理制备X65管线钢镀镍超双疏表面及其耐蚀性研究

黄鹏, 高荣杰(

), 刘文斌, 尹续保

中国海洋大学材料科学与工程学院青岛 266100

Fabrication of Superamphiphobic Surface for Nickel-plate on Pipeline Steel by Salt Solution Etching and Its Anti-corrosion Properties

HUANG Peng, GAO Rongjie(

), LIU Wenbin, YIN Xubao

School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China

全文: PDF(8439 KB) HTML

摘要:

通过盐溶液对X65管线钢镀镍表面进行化学刻蚀，然后经过全氟辛基三氯硅烷修饰，成功地在基底上制备出了超疏水疏油性能的表面，并通过电化学测试研究了双疏表面的耐腐蚀性能。结果表明：含钴镍离子的溶液80 ℃恒温刻蚀6 h后，再经过全氟辛基三氯硅烷修饰2 h，得到了与去离子水、乙二醇的接触角分别为160°和152°的超双疏表面。相较于镀镍试样表面，极化曲线表明超双疏表面的腐蚀速率明显降低，电化学阻抗测试图谱表明超双疏表面的耐蚀性得到了提高。

关键词 ：盐刻蚀, 镀镍, 超双疏, 接触角, 耐蚀性

Abstract：

A Ni-plate was firstly electrodeposited on X65 pipeline steel surface, which then was chemically etched by salt solution, and finally subjected to modification treatment with perfluorohexylethyltrichlorosilane, so that the surface of Ni-plate was endowed with super-hydrophobic and oil-phobic performance. The corrosion behavior of the modified Ni-plate was studied by potentiodynamic scanning. The result showed that after being etched for 6 h at 80 ℃ in the solution containing cobalt and nickel ions, and modified with perfluorooctyltrichlorosilane for 2 h, the modified Ni-plate surface presented contact angles of 160° and 152° for deionized water and glycol respectively. Compared with the original Ni-plate surface, the modified ones presented significantly lower corrosion rate, namely, better corrosion resistance.

Key words： salt solution etching Ni-plate superamphiphobic contact angle anti-corrosion property

收稿日期: 2020-02-17

ZTFLH:

TG174.4

基金资助:国家自然科学基金-山东省联合基金(U1706221)

通讯作者: 高荣杰 E-mail: dmh206@ouc.edu.cn

Corresponding author: GAO Rongjie E-mail: dmh206@ouc.edu.cn

作者简介: 黄鹏，男，1992年生，硕士生

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引用本文:

黄鹏, 高荣杰, 刘文斌, 尹续保. 盐溶液刻蚀-氟化处理制备X65管线钢镀镍超双疏表面及其耐蚀性研究[J]. 中国腐蚀与防护学报, 2021, 41(1): 96-100.
Peng HUANG, Rongjie GAO, Wenbin LIU, Xubao YIN. Fabrication of Superamphiphobic Surface for Nickel-plate on Pipeline Steel by Salt Solution Etching and Its Anti-corrosion Properties. Journal of Chinese Society for Corrosion and protection, 2021, 41(1): 96-100.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2020.008 或 https://www.jcscp.org/CN/Y2021/V41/I1/96

图1 盐溶液刻蚀6 h后的表面形貌和未刻蚀表面形貌

图2 为去离子水和乙二醇在X65管线钢镀镍原始表面和超双疏表面的接触角

图3 X65管线钢镀镍盐刻蚀表面的XRD谱

图4 原始试样、盐溶液刻蚀试样和超双疏表面试样在3.5%NaCl溶液中的动电位极化曲线

表1 原始试样、盐溶液刻蚀试样和超双疏试样的动电位极化曲线的拟合参数

图5 镀镍试样及超双疏试样在3.5%NaCl溶液中电化学阻抗谱

表2 镀镍试样以及超双疏试样电化学阻抗Nyquist谱的电路拟合参数

1	Nosonovsky M. Multiscale roughness and stability of superhydrophobic biomimetic interfaces [J]. Langmuir, 2007, 23: 3157
2	Erbil H Y, Demirel A L, Avcı Y, et al. Transformation of a simple plastic into a superhydrophobic surface [J]. Science, 2003, 299: 1377
3	Blossey R. Self-cleaning surfaces-virtual realities [J]. Nat. Mater., 2003, 2: 301
4	Xiu Y H, Zhu L B, Hess D W, et al. Hierarchical silicon etched structures for controlled hydrophobicity/superhydrophobicity [J]. Nano Lett., 2007, 7: 3388
5	Gao X F, Jiang L. Water-repellent legs of water striders [J]. Nature, 2004, 432: 36
6	Zheng Y M, Gao X F, Jiang L. Directional adhesion of superhydrophobic butterfly wings [J]. Soft Matter, 2007, 3: 178
7	Yamauchi Y, Tenjimbayashi M, Samitsu S, et al. Durable and flexible superhydrophobic materials: Abrasion/scratching/slicing/droplet impacting/bending/twisting-tolerant composite with porcupinefish-like structure [J]. ACS Appl. Mater. Interfaces, 2019, 11: 32381
8	Sun T L, Feng L, Gao X F, et al. Bioinspired surfaces with special wettability [J]. Acc. Chem. Res., 2005, 38: 644
9	Hu L T, Zhang L, Wang D R, et al. Fabrication of biomimetic superhydrophobic surface based on nanosecond laser-treated titanium alloy surface and organic polysilazane composite coating [J]. Colloids Surf., 2018, 555A: 515
10	Yin Y J, Huang R H, Zhang W, et al. Superhydrophobic-superhydrophilic switchable wettability via TiO₂ photoinduction electrochemical deposition on cellulose substrate [J]. Chem. Eng. J., 2016, 289: 99
11	Shirtcliffe N J, McHale G, Newton M I, et al. Intrinsically superhydrophobic organosilica sol-gel foams [J]. Langmuir, 2003, 19: 5626
12	Ozkan E, Crick C C, Taylor A, et al. Copper-based water repellent and antibacterial coatings by aerosol assisted chemical vapour deposition [J]. Chem. Sci., 2016, 7: 5126
13	Jin C D, Li J P, Han S J, et al. A durable, superhydrophobic, superoleophobic and corrosion-resistant coating with rose-like ZnO nanoflowers on a bamboo surface [J]. Appl. Surf. Sci., 2014, 320: 322
14	Mohammadi F, Eliyan F F, Alfantazi A. Corrosion of simulated weld HAZ of API X-80 pipeline steel [J]. Corros. Sci., 2012, 63: 323
15	Zhou N, Ding Y, Ma L Q. A study of Nickel plating on Q235 steel surface and its properties [J]. Electroplat. Pollut. Control, 2013, 33(1): 4
15	周楠, 丁毅, 马立群. Q235钢表面电镀镍及其性能的研究 [J]. 电镀与环保, 2013, 33(1): 4
16	Peng X, Zhang Y, Zhao J, et al. Electrochemical corrosion performance in 3.5%NaCl of the electrodeposited nanocrystalline Ni films with and without dispersions of Cr nanoparticles [J]. Electrochim. Acta, 2006, 51: 4922
17	Wenzel R N. Resistance of solid surfaces to wetting by water [J]. Ind. Eng. Chem., 1936, 28: 988
18	Cassie A B D, Baxter S. Wettability of porous surfaces [J]. Trans. Faraday Soc., 1944, 40: 546

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