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中国腐蚀与防护学报  2025, Vol. 45 Issue (5): 1175-1186     CSTR: 32134.14.1005.4537.2024.382      DOI: 10.11902/1005.4537.2024.382
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在电解液中添加陶瓷颗粒对钛合金表面微弧氧化膜层改性的研究进展
何江海, 杨子钰, 刘琦, 马子骅, 何伟, 陈飞()
北京石油化工学院新材料与化工学院 北京 102617
Research Progress on Modification of Microarc Oxidation Coatings on Ti-alloy Surface by Adding Ceramic Particles to Electrolyte
HE Jianghai, YANG Ziyu, LIU Qi, MA Zihua, HE Wei, CHEN Fei()
School of New Materials and Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China
引用本文:

何江海, 杨子钰, 刘琦, 马子骅, 何伟, 陈飞. 在电解液中添加陶瓷颗粒对钛合金表面微弧氧化膜层改性的研究进展[J]. 中国腐蚀与防护学报, 2025, 45(5): 1175-1186.
Jianghai HE, Ziyu YANG, Qi LIU, Zihua MA, Wei HE, Fei CHEN. Research Progress on Modification of Microarc Oxidation Coatings on Ti-alloy Surface by Adding Ceramic Particles to Electrolyte[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(5): 1175-1186.

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摘要: 

钛合金微弧氧化(MAO)后在表面形成的涂层疏松多孔等物理缺陷，严重影响了钛合金相关性能及服役时间，针对这一问题，本文总结了利用二元化合物在电解液里的掺杂，提高钛合金MAO涂层的耐磨性、耐蚀性、高温抗氧化性、光催化性、抗菌性的相关性能研究。并在此基础上提出了未来二元化合物的掺杂来提高钛合金微弧氧化涂层性能的研究方向和思路，希望能为今后钛合金的研究提供参考和借鉴。
关键词 ： 微弧氧化,  钛合金,  缺陷,  二元化合物,  性能    
Abstract：

It is known that modification with micro arc oxidation (MAO) technique, the physical defects such as porosities or pinholes may commonly exist in the formed coatings on the Ti-alloy surface, which seriously affects the relevant properties and the service life-time of Ti-alloy parts or facilities, in view of this problem, herein it summarizes the research progress on the addition of binary compounds in the electrolyte to modify the relevant properties of MAO coatings on Ti-alloy in terms of the resistance to abrasion, corrosion and high temperature oxidation, as well as the photocatalytic and antimicrobial properties. Furthermore, the future research direction and ideas to create MAO coatings of peculiar performance for Ti-alloy, the utilizing different binary compounds with various function and particle size, even multiple binary compounds etc. are proposed, hoping to provide reference and reference for future research on titanium alloys.
Key words： microarc oxidation    Ti-alloy    defects    binary compounds    properties
收稿日期: 2024-11-26      32134.14.1005.4537.2024.382
ZTFLH:  TG174.45  
基金资助:北京市自然科学基金(2202017)
通讯作者: 陈飞，E-mail：chenfei@bipt.edu.cn，研究方向为金属材料腐蚀与防护
Corresponding author: CHEN Fei, E-mail: chenfei@bipt.edu.cn
作者简介: 何江海，男，2000年生，硕士生
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https://www.jcscp.org/CN/10.11902/1005.4537.2024.382      或      https://www.jcscp.org/CN/Y2025/V45/I5/1175

图1  在电解液中添加不同含量的ZrO2颗粒后钛合金MAO膜的表面与截面形貌[36]
SubstratesParticlesSize of particlesEcorr without particles / VEcorr with particles / VIcorr without particlesA·cm-2Icorr with particlesA·cm-2Refs.
TC4ZrO20.5-1 μm-0.2237-2.4 × 10-9[36]
Ti6Al4VMoS2< 2 μm-0.3830.0389.6 × 10-84.2 × 10-9[46]
TC4SiC400 nm--9.1 × 10-54.1 × 10-6[47]
TC4TaC1 μm-0.220.121.1 × 10-62.7 × 10-8[48]
Ti6Al4VZrO2/TiO21 μm-0.4470.1131.5 × 10-75.7 × 10-8[49]
Ti6Al4VGO/HA-0.290.615.0 × 10-81.6 × 10-8[50]
Ti6Al4VAlN--0.7311-0.38176.9 × 10-62.8 × 10-9[51]
表1  在电解液中添加二元化合物粒子对钛合金MAO膜层在3.5%NaCl溶液中耐蚀性的影响
图2  电解液中添加MoS2所制备的MAO涂层在3.5% (质量分数) NaCl溶液中的EIS谱和拟合曲线[46]
SubstratesParticlesDurometerFriction coefficientsRefs.
TC4ZrO2-0.35[35]
Ti6Al4VTaC965HV0.148[49]
TC11Er2O3(486.9 ± 11.8)HV0.5[54]
TC11Nd2O3-0.6[55]
Ti6Al4VSiC(443.5 ± 15.8)HV0.38[56]
TC4BN/ZrO2-0.45[57]
Ti6Al4VMoS2/TiO2(360 ± 15)HV0.49[58]
TB8BN-0.6[59]
TC4Al2O31261HV0.63[60]
TC4Cu2O-0.3[61]
TC4GO-0.36[62]
表2  二元化合物添加对钛合金的MAO膜层硬度及摩擦系数的影响
图3  电解液中添加不同含量的GO颗粒表面膜层的磨痕SEM形貌[64]
图4  添加不同含量的Nd2O3MAO层800 ℃氧化50 h的氧化增重及其对应的宏观形貌[55]
图5  MAO制备的TiO2薄膜和TiO2/Eu2O3复合薄膜的紫外-可见光谱[66]
图6  MAO制备的TiO2薄膜和TiO2/Eu2O3复合薄膜的光电流强度[66]
图7  MAO制备的TiO2薄膜及TiO2/Eu2O3复合薄膜的光催化活性[66]
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