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中国腐蚀与防护学报  2025, Vol. 45 Issue (5): 1253-1264     CSTR: 32134.14.1005.4537.2024.408      DOI: 10.11902/1005.4537.2024.408
  研究报告 本期目录 | 过刊浏览 |
表面粗糙度以及NaOH溶液的浓度和温度对锆基非晶合金腐蚀行为的影响
王涛涛1, 薛荣洁1(), 马晓伟1, 万皓锋1, 王冬朋2, 刘珍光2
1 江苏理工学院材料工程学院 常州 213001
2 江苏科技大学材料科学与工程学院 镇江 212100
Effect of Surface Roughness, Concentration and Temperature of NaOH Solution on Corrosion Behavior of a Zr-based Metallic Glass
WANG Taotao1, XUE Rongjie1(), MA Xiaowei1, WAN Haofeng1, WANG Dongpeng2, LIU Zhenguang2
1 School of Materials Engineering, Jiangsu Institute of Technology, Changzhou 213001, China
2 School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212100, China
引用本文:

王涛涛, 薛荣洁, 马晓伟, 万皓锋, 王冬朋, 刘珍光. 表面粗糙度以及NaOH溶液的浓度和温度对锆基非晶合金腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2025, 45(5): 1253-1264.
Taotao WANG, Rongjie XUE, Xiaowei MA, Haofeng WAN, Dongpeng WANG, Zhenguang LIU. Effect of Surface Roughness, Concentration and Temperature of NaOH Solution on Corrosion Behavior of a Zr-based Metallic Glass[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(5): 1253-1264.

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摘要: 

通过自然浸泡失重法、电化学技术和扫描电镜(SEM/EDS)等手段，研究了温度、浓度、粗糙度及自然浸泡对Zr41.2Ti13.8Cu12.5Ni10Be22.5 (Vit1)非晶合金在NaOH溶液中耐蚀性的影响。结果表明，Vit1在0.1 mol/L的NaOH溶液中的自然腐蚀速率是0.01 mol/L的NaOH溶液中的1.22倍。随着温度、浓度和粗糙度增加，Vit1的自腐蚀电流密度变大，阻抗变小，耐蚀性下降，表面生成的ZrO2、TiO2、NiO、CuO基底氧化物和Be(OH)2腐蚀产物增多，腐蚀产物覆盖面积增大。温度升高，分子和离子的活动能力增强，更易发生化学反应，促进合金溶解和腐蚀。高浓度的NaOH，腐蚀速率加快，是由于高浓度碱性溶液中的OH-能更有效地与非晶合金表面发生反应，从而加快腐蚀。粗糙度增加，参与腐蚀反应的表面暴露有效面积增大，腐蚀反应速率加快。浸泡处理后，腐蚀液在合金表面积累，导致局部浓度增加，这些局部浓度差异导致腐蚀的不均匀性，产生腐蚀疤痕。
关键词 ： 锆基非晶合金,  电化学,  NaOH溶液,  腐蚀性能    
Abstract：

The effect of temperature and concentration of NaOH solution, as well as the roughness of material on the electrochemical properties of a Zr-based metallic glass in NaOH solution were studied by means of mass loss measurement, electrochemical technology and scanning electron microscopy (SEM/EDS). The free corrosion rate of Zr-based metallic glass in 0.1 mol/L NaOH is 1.22 times that in 0.01 mol/L NaOH solution. With the increase of temperature, concentration and roughness, the Icorr of Zr-based metallic glass increases, the impedance and the corrosion resistance decrease. The corrosion products on the surface of Zr-based metallic glass increased, and the product corroded area increased. ZrO2, TiO2, NiO, CuO substrate oxides and Be(OH)2 corrosion products were formed on the surface of Vit1 after corrosion. As the temperature increases, the mobility of molecules and ions increases, making chemical reactions more likely to occur, and accelerating the dissolution and corrosion of metallic glasses. The increase of NaOH concentration and the acceleration of corrosion rate may be due to the fact that hydroxide ions (OH-) in highly concentrated alkaline solutions can react more effectively with the surface of metallic glasses, thereby accelerating corrosion. With the increase of roughness, the effective area of surface exposure involved in the corrosion reaction increases, and the corrosion reaction rate accelerates. After immersion, corrosion fluids accumulate on the surface of the alloy, resulting in an increase in local concentration differences, which lead to non-uniform corrosion and corrosion scarring.
Key words： Zr-based metallic glass    electrochemistry    NaOH solution    corrosion property
收稿日期: 2024-12-25      32134.14.1005.4537.2024.408
ZTFLH:  TG172.5  
基金资助:国家自然科学基金(51801083);江苏省大学生创新创业训练计划(202411463092Y)
通讯作者: 薛荣洁，E-mail：xuerongjie@jsut.edu.cn，研究方向为非晶合金和高熵合金
Corresponding author: XUE Rongjie, E-mail: xuerongjie@jsut.edu.cn
作者简介: 王涛涛，男，2000年生，硕士生
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链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2024.408      或      https://www.jcscp.org/CN/Y2025/V45/I5/1253

图1  Vit1在0.01、0.1 mol/L NaOH溶液中浸泡648 h的失重率和腐蚀速率
图2  不同表面粗糙度的Vit1样品在不同条件的NaOH溶液浸泡后的动电位极化曲线
Experiment conditionsIcorr / A·cm-2Ecorr / mVRs / kΩ·cm2Rct / kΩ·cm2CPE / μF·cm2α
1: 0.01 mol/L-25 ℃2.6 × 10-9-3740.4025322.704.02280.91285
2: 0.01 mol/L-35 ℃3.6 × 10-9-3330.7885154.703.93630.90021
3: 0.1 mol/L-25 ℃9.3 × 10-9-3070.0402132.706.68470.90352
4: 0.1 mol/L-35 ℃1.13 × 10-8-1460.033517.727.17760.89177
5: IC 0.01 mol/L-25 ℃6.2 × 10-9-3710.220365.549.66450.90692
6: IC 0.01 mol/L-35 ℃8.1 × 10-9-1250.170211.8011.0130.91269
7: IC 0.1 mol/L-25 ℃8.35 × 10-8-2230.027201.1810.540.93691
8: IC 0.1 mol/L-35 ℃9.12 × 10-8-2300.031142.476.80360.93684
9: 0.01 mol/L-180#3.16 × 10-7-6020.263417.157.00380.87587
10: 0.01 mol/L-400#2.76 × 10-7-4710.008454.496.16130.94270
11: 0.01 mol/L-1200#1.54 × 10-7-4300.272494.228.58450.89133
12: 0.01 mol/L-3000#5.93 × 10-8-2710.060525.494.16020.93659
13: 0.01 mol/L-5000#3.29 × 10-8-4730.060647.695.18290.86688
14: 0.1 mol/L-180#4.05 × 10-7-4630.054222.779.18760.91008
15: 0.1 mol/L-400#3.00 × 10-7-4300.484256.695.85580.93849
16: 0.1 mol/L-1200#2.05 × 10-7-3400.051291.745.05110.92293
17: 0.1 mol/L-3000#1.27 × 10-7-4090.008358.466.13160.90838
18: 0.1 mol/L-5000#4.43 × 10-8-6040.016390.806.70740.94493
表1  图2中动电位极化曲线以及图3中电化学阻抗谱拟合参数
图3  不同表面粗糙度的Vit1样品在不同条件的NaOH溶液浸泡后的EIS及等效电路图
图4  不同表面粗糙度的Vit1样品在不同条件的NaOH溶液浸泡后表面SEM图
图5  IC 0.1 mol/L-35 ℃样品的SEM图和能谱色散图，不同表面粗糙度的Vit样品在不同条件的NaOH溶液浸泡后基底平整区与腐蚀产物区的单位原子百分比
图6  0.1 mol/L-25 ℃样品的表面XPS全谱和主要元素的精细谱图
图7  腐蚀反应机理示意图
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