镍基合金Inconel617B在700 ℃超临界水环境中的氧化行为研究

doi:10.11902/1005.4537.2021.145

中国腐蚀与防护学报

2022, Vol. 42

Issue (4): 655-661 DOI: 10.11902/1005.4537.2021.145

研究报告

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镍基合金Inconel617B在700 ℃超临界水环境中的氧化行为研究

朱忠亮¹(

), 马辰昊¹, 李宇旸¹, 肖博¹, 袁小虎²^,³, 王硕⁴, 徐鸿¹, 张乃强¹

^1.华北电力大学电站能量传递转化与系统教育部重点实验室北京 102206
^2.重庆大学材料科学与工程学院重庆 400044
^3.东方电气集团东方汽轮机有限公司长寿命高温材料国家重点实验室德阳 618000
^4.哈尔滨锅炉厂有限责任公司高效清洁燃煤电站锅炉国家重点实验室哈尔滨 150046

Oxidation Behavior of Nickel-based Alloy Inconel617B in Supercritical Water at 700 ℃

ZHU Zhongliang¹(

), MA Chenhao¹, LI Yuyang¹, XIAO Bo¹, YUAN Xiaohu²^,³, WANG Shuo⁴, XU Hong¹, ZHANG Naiqiang¹

^1.Key Laboratory of Power Station Energy Transfer, Conversion and System, Ministry of Education, North China Electric Power University, Beijing 102206, China
^2.School of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
^3.State Key Laboratory of Long-Life High Temperature Materials, Dongfang Electric Corporation Dongfang Turbing Co. Ltd., Deyang 618000, China
^4.State Key Laboratory of Efficient and Clean Coal-fired Utility Boilers, Harbin Boiler Company Limited, Harbin 150046, China

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摘要:

开展了镍基合金Inconel617B在700 ℃/25 MPa超临界水环境氧化实验研究。利用电子天平、SEM、XRD、XPS以及AFM对金属氧化动力学、氧化膜微观形貌、物相成分进行了分析。结果表明：700 ℃时镍基合金Inconel617B的氧化动力学介于抛物线和直线规律之间。氧化物主要为NiO、NiCr₂O₄以及Cr₂O₃,同时存在少量的Ni(OH)₂、CoO以及TiO₂。随着氧化时间的增加,氧化膜物相发生变化。三维形貌观察表明,氧化膜的生长源于金属离子的向外扩散。

关键词 ：镍基合金, 氧化, 超临界水, 生长机理, 氧化膜

Abstract：

Oxidation behavior of nickel-based alloy Inconel617B in 700 ℃/25 MPa supercritical water was studied by means of electron balance, SEM, XRD, XPS and AFM. The results show that the oxidation kinetics of Inconel617B at 700 ℃ obeys regulation in between parabolic and straight-line law, the formed oxide scales are composed mainly of NiO, NiCr₂O₄ and Cr₂O₃, and a small amount of Ni(OH)₂, CoO and TiO₂ are also detected. The phase constituents of the formed oxide scales varied with oxidation time. The three-dimensional morphology shows that the growth of the oxide scale can be attributed to the outward diffusion of metal ions. The growth mechanism of the oxide scale of Inconel617B in supercritical water was further discussed.

Key words： nickel-based alloy oxidation supercritical water oxidation mechanism oxide film

收稿日期: 2021-06-25

ZTFLH:

TK245

基金资助:国家重点研发计划(2020YFF0218101);国家自然科学基金(52071140);中央高校基本科研业务费(2020MS007)

通讯作者: 朱忠亮 E-mail: zhzl@ncepu.edu.cn

Corresponding author: ZHU Zhongliang E-mail: zhzl@ncepu.edu.cn

作者简介: 朱忠亮,男,1987年生,博士,讲师

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引用本文:

朱忠亮, 马辰昊, 李宇旸, 肖博, 袁小虎, 王硕, 徐鸿, 张乃强. 镍基合金Inconel617B在700 ℃超临界水环境中的氧化行为研究[J]. 中国腐蚀与防护学报, 2022, 42(4): 655-661.
Zhongliang ZHU, Chenhao MA, Yuyang LI, Bo XIAO, Xiaohu YUAN, Shuo WANG, Hong XU, Naiqiang ZHANG. Oxidation Behavior of Nickel-based Alloy Inconel617B in Supercritical Water at 700 ℃. Journal of Chinese Society for Corrosion and protection, 2022, 42(4): 655-661.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2021.145 或 https://www.jcscp.org/CN/Y2022/V42/I4/655

图1 700 ℃超临界水环境下Inconel617B合金氧化增重与时间关系

图2 超临界水环境下不同氧化时间后Inconel617B合金表面形貌

图3 Inconel617B合金在超临界水环境下氧化200和600 h后的表面元素分布

表1 图2中A~E位置点处的原子分数

图4 700 ℃超临界水环境中Inconel617B合金氧化不同时间后表面氧化物的XPS谱

图5 Inconel617B合金在700 ℃超临界水环境中氧化不同时间后的XRD谱

图6 Inconel617B合金在超临界水中氧化1000 h后的横截面形貌及元素分布图

图7 Inconel617B合金在超临界水中氧化200和1000 h后的二维和三维表面形貌特征

1	Wang Q, Wang W L, Liu M, et al. Development and prospect of (ultra) supercritical coal-fired power generation technology [J]. Therm. Power Generat., 2021, 50(2): 1
1	王倩, 王卫良, 刘敏等. 超 (超) 临界燃煤发电技术发展与展望 [J]. 热力发电, 2021, 50(2): 1
2	Fang X D, Liu X, Xu F H, et al. Oxidation behavior in supercritical water of domestic austenitic steel C-HRA-5 for uultra-supercritical power stations [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 266
2	方旭东, 刘晓, 徐芳泓等. 超超临界电站国产奥氏体钢C-HRA-5在超临界水中的氧化特性 [J]. 中国腐蚀与防护学报, 2020, 40: 266
3	Liu X, Wang H, Zhu Z L, et al. Oxidation characteristics of austenitic heat-resistant steel HR3C and sanicro25 in supercritical water for power station [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 529
3	刘晓, 王海, 朱忠亮等. 电站用奥氏体耐热钢HR3C与Sanicro25在超临界水中的氧化特性 [J]. 中国腐蚀与防护学报, 2020, 40: 529
4	Liu R W, Xiao P, Zhong L, et al. Research progress of advanced 700 ℃ ultra-supercritical coal-fired power generation technology [J]. Therm. Power Generat., 2017, 46(9): 1
4	刘入维, 肖平, 钟犁等. 700 ℃超超临界燃煤发电技术研究现状 [J]. 热力发电, 2017, 46(9): 1
5	Zhang Y P, Cai X Y, Huang S H. Materials in 700 ℃ advanced ultra-supercritical coal-fired units [J]. Electr. Power, 2012, 45(2): 16
5	张燕平, 蔡小燕, 黄树红. 700 ℃超超临界燃煤发电机组材料研发现状 [J]. 中国电力, 2012, 45(2): 16
6	Xu H, Deng B, Zhu Z L, et al. Oxidation characteristics of Haynes 282 nickel-based alloy in supercritical water at 600-700 ℃ [J]. Mater. Mech. Eng., 2018, 42(3): 1
6	徐鸿, 邓博, 朱忠亮等. Haynes 282镍基合金在600~700 ℃超临界水中的氧化特性 [J]. 机械工程材料, 2018, 42(3): 1
7	Zhang Q, Tang R, Yin K J, et al. Corrosion behavior of Hastelloy C-276 in supercritical water [J]. Corros. Sci., 2009, 51: 2092 doi: 10.1016/j.corsci.2009.05.041
8	Tan L, Ren X, Sridharan K, et al. Corrosion behavior of Ni-base alloys for advanced high temperature water-cooled nuclear plants [J]. Corros. Sci., 2008, 50: 3056 doi: 10.1016/j.corsci.2008.08.024
9	Chang K H, Chen S M, Yeh T K, et al. Effect of dissolved oxygen content on the oxide structure of Alloy 625 in supercritical water environments at 700 ℃ [J]. Corros. Sci., 2014, 81: 21 doi: 10.1016/j.corsci.2013.11.034
10	Rodriguez D, Merwin A, Karmiol Z, et al. Surface chemistry and corrosion behavior of Inconel 625 and 718 in subcritical, supercritical, and ultrasupercritical water [J]. Appl. Surf. Sci., 2017, 404: 443 doi: 10.1016/j.apsusc.2017.01.119
11	Zhong X Y, Han E-H, Wu X Q. Corrosion behavior of Alloy 690 in aerated supercritical water [J]. Corros. Sci., 2013, 66: 369 doi: 10.1016/j.corsci.2012.10.001
12	Behnamian Y, Mostafaei A, Kohandehghan A, et al. A comparative study of oxide scales grown on stainless steel and nickel-based superalloys in ultra-high temperature supercritical water at 800 ℃ [J]. Corros. Sci., 2016, 106: 188 doi: 10.1016/j.corsci.2016.02.004
13	Kim D, Sah I, Lee H J, et al. Hydrogen effects on oxidation behaviors of Haynes 230 in high temperature steam environments [J]. Solid State Ionics, 2013, 243: 1 doi: 10.1016/j.ssi.2013.04.010
14	Gorman D M, Higginson R L, Du H, et al. Microstructural analysis of IN617 and IN625 oxidised in the presence of steam for use in ultra-supercritical power plant [J]. Oxid. Met., 2013, 79: 553 doi: 10.1007/s11085-012-9342-2
15	Xie D B, Zhou Y Y, Lu J T, et al. Effect of Cr content on oxidation of Ni-based alloy in supercritical water [J]. J. Chin. Soc. Corros. Prot., 2018, 38: 358
15	谢冬柏, 周游宇, 鲁金涛等. Cr对镍基合金在超临界水中氧化行为的影响研究 [J]. 中国腐蚀与防护学报, 2018, 38: 358
16	Liu Y Y, Zhu L H, Zhou R Y, et al. Effect of microstructure evolution on properties of Inconel617B alloy welded joint creep tested at 750 ℃ [J]. Heat Treat. Met., 2017, 42(5): 62
16	刘岩岩, 朱丽慧, 周任远等. Inconel617B合金焊接接头750 ℃持久微观组织演变对性能的影响 [J]. 金属热处理, 2017, 42(5): 62
17	McIntyre N S, Rummery T E, Cook M G, et al. X‐ray photoelectron spectroscopic study of the aqueous oxidation of monel-400 [J]. J. Electrochem. Soc., 1976, 123: 1164 doi: 10.1149/1.2133027
18	Huang J B, Wu X Q, Han E-H. Electrochemical properties and growth mechanism of passive films on alloy 690 in high-temperature alkaline environments [J]. Corros. Sci., 2010, 52: 3444 doi: 10.1016/j.corsci.2010.06.016
19	Xue T, Wang X, Lee J M. Dual-template synthesis of Co(OH)₂ with mesoporous nanowire structure and its application in supercapacitor [J]. J. Power Sources, 2012, 201: 382 doi: 10.1016/j.jpowsour.2011.10.138
20	Wang Y, Liu Y, Tang H P, et al. Oxidation behaviors of porous Haynes 214 alloy at high temperatures [J]. Mater. Charact., 2015, 107: 283 doi: 10.1016/j.matchar.2015.07.026
21	Reddy B M, Khan A, Yamada Y, et al. Structural characterization of CeO₂-TiO₂ and V₂O₅/CeO₂-TiO₂ catalysts by Raman and XPS techniques [J]. J. Phys. Chem. B, 2003, 107: 5162 doi: 10.1021/jp0344601
22	Machet A, Galtayries A, Zanna S, et al. XPS and STM study of the growth and structure of passive films in high temperature water on a nickel-base alloy [J]. Electrochim. Acta, 2004, 49: 3957 doi: 10.1016/j.electacta.2004.04.032
23	Sennour M, Marchetti L, Martin F, et al. A detailed TEM and SEM study of Ni-base alloys oxide scales formed in primary conditions of pressurized water reactor [J]. J. Nucl. Mater., 2010, 402: 147 doi: 10.1016/j.jnucmat.2010.05.010
24	McIntyre N S, Zetaruk D G, Owen D. X-ray photoelectron studies of the aqueous oxidation of Inconel-600 alloy [J]. J. Electrochem. Soc., 1979, 126: 750 doi: 10.1149/1.2129132
25	Sun M C, Wu X Q, Zhang Z E, et al. Analyses of oxide films grown on Alloy 625 in oxidizing supercritical water [J]. J. Supercrit. Fluids, 2008, 47: 309 doi: 10.1016/j.supflu.2008.07.010
26	Chang K H, Huang J H, Yan C B, et al. Corrosion behavior of Alloy 625 in supercritical water environments [J]. Prog. Nucl. Energy, 2012, 57: 20 doi: 10.1016/j.pnucene.2011.12.015
27	Pérez-González F A, Garza-Montes-de Oca N F, Colás R. High temperature oxidation of the Haynes 282^© nickel-based superalloy [J]. Oxid. Met., 2014, 82: 145 doi: 10.1007/s11085-014-9483-6
28	Haugsrud R. On the high-temperature oxidation of nickel [J]. Corros. Sci., 2003, 45: 211 doi: 10.1016/S0010-938X(02)00085-9

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