玄武岩/氧化铈改性PMMA涂层的防腐及耐磨性能的研究

doi:10.11902/1005.4537.2021.186

中国腐蚀与防护学报

2022, Vol. 42

Issue (4): 597-604 DOI: 10.11902/1005.4537.2021.186

研究报告

本期目录 | 过刊浏览

玄武岩/氧化铈改性PMMA涂层的防腐及耐磨性能的研究

类延华(

), 刘宁轩, 张玉良, 常雪婷, 刘涛

上海海事大学海洋科学与工程学院上海 201306

Preparation, Corrosion- and Wear-resistance of Polymethyl Methacrylate Coating Modified with Particles of Basalt/cerium Oxide Composite

LEI Yanhua(

), LIU Ningxuan, ZHANG Yuliang, CHANG Xueting, LIU Tao

College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China

全文: PDF(12569 KB) HTML

摘要:

在X70钢上构建了含有玄武岩/氧化铈粒子的聚甲基丙烯酸甲酯涂层 (PMMA),并研究了添加量对涂层防腐耐磨性能的影响。利用X射线衍射、扫描电镜/能谱仪、接触角测试仪分析了未添加和添加玄武岩/氧化铈粒子涂层的相与元素组成、表面形貌及亲疏水性,同时对改性后涂层进行了电化学阻抗谱、极化曲线、摩擦磨损测试。结果表明,玄武岩/氧化铈复合材料改性涂层展现出更明显的疏水性以及更为优异的耐蚀性和耐摩擦性能。

关键词 ：氧化铈, 玄武岩, 聚甲基丙烯酸甲酯, 涂层, 防腐, 摩擦磨损

Abstract：

A polymethyl methacrylate coating (PMMA) containing particles of basalt/cerium oxide composite was applied on X70 steel, then the effect of the addition amount of basalt/cerium oxide composite on the corrosion- and wear-resistance of the coating was studied. The synthesized basalt/cerium oxide composite material was characterized by X-ray diffractometer. The surface morphology, composition, hydrophilicity, and hydrophobicity of the coating before and after the addition of basalt/cerium oxide particles were assessed comparatively by scanning electron microscope with energy dispersive spectroscope and contact angle tester. At the same time, the anti-corrosion and friction behavior of the modified coating were studied by means of electrochemical impedance spectroscope, polarization curve measurement, friction- and wear-tester. The results show that the modified coating with basalt/cerium oxide composite exhibits much obvious hydrophobicity and better corrosion resistance and friction resistance.

Key words： cerium oxide basalt polymethyl methacrylate coating anti-corrosion friction and wear

收稿日期: 2021-08-05

ZTFLH:

TG178

基金资助:国家自然科学基金(516020195);国家自然科学基金(41976039)

通讯作者: 类延华 E-mail: yhlei@shmtu.edu.cn

Corresponding author: LEI Yanhua E-mail: yhlei@shmtu.edu.cn

作者简介: 类延华,男,1982年生,博士,副教授
刘宁轩,男,1997年生,硕士生

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引用本文:

类延华, 刘宁轩, 张玉良, 常雪婷, 刘涛. 玄武岩/氧化铈改性PMMA涂层的防腐及耐磨性能的研究[J]. 中国腐蚀与防护学报, 2022, 42(4): 597-604.
Yanhua LEI, Ningxuan LIU, Yuliang ZHANG, Xueting CHANG, Tao LIU. Preparation, Corrosion- and Wear-resistance of Polymethyl Methacrylate Coating Modified with Particles of Basalt/cerium Oxide Composite. Journal of Chinese Society for Corrosion and protection, 2022, 42(4): 597-604.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2021.186 或 https://www.jcscp.org/CN/Y2022/V42/I4/597

图1 玄武岩的SEM形貌和CeO2的TEM形貌

图2 玄武岩与BA/CeO2粒子的XRD图谱

图3 涂覆不同涂层样品的水接触角

图4 不同膜层的扫描形貌图

图5 不同样品的表面能谱分析结果

图6 不同样品在3.5%NaCl溶液中的Nyquist和Bode图

图7 电化学阻抗谱拟合等效电路图

表1 不同样品在3.5%NaCl溶液中电化学阻抗的拟合结果

图8 不同样品在3.5%NaCl溶液中的极化曲线图

表2 涂覆不同涂层的X70钢样品在3.5 % NaCl溶液中的腐蚀电化学参数

图9 涂层中玄武岩/氧化铈颗粒添加量对样品摩擦系数的影响

图10 涂覆不同涂层的X70钢样品的磨痕轮廓图

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