新型F级船用低温钢表面氧化物对其耐磨性能影响研究

doi:10.11902/1005.4537.2021.254

中国腐蚀与防护学报

2022, Vol. 42

Issue (3): 395-402 DOI: 10.11902/1005.4537.2021.254

中国腐蚀与防护学会杰出青年学术成就奖论文专栏

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新型F级船用低温钢表面氧化物对其耐磨性能影响研究

王超逸¹, 夏呈祥², 王东胜², 强强², 赵子铭², 常雪婷²(

)

^1.鞍钢集团北京研究院北京 102200
^2.上海海事大学海洋科学与工程学院上海 201306

Effect of Surface Oxides on Wear Resistance of New F-Class Marine Low Temperature Steel

WANG Chaoyi¹, XIA Chengxiang², WANG Dongsheng², QIANG Qiang², ZHAO Ziming², CHANG Xueting²(

)

^1.Ansteel Beijing Research Institute Co. Ltd. , Beijing 102200, China
^2.College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China

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摘要:

分别测试了新型F级船用低温钢板表面生成不同氧化物后的往复摩擦行为,并结合白光干涉仪以及扫描电子显微镜分别对钢样的显微组织形貌和磨痕形貌进行了表征。结果表明：γ-FeOOH氧化层钢样、原始钢样、Fe₃O₄氧化层钢样的耐磨蚀性能依次变高。其中，致密完整的Fe₃O₄氧化层钢样的磨损量最低，磨痕轮廓深度和尺寸都最小，表面以粘着磨蚀为主，耐蚀性也最好；γ-FeOOH氧化层微观结构较为疏松，摩擦系数最小，但是在摩擦腐蚀的协同作用下磨损量最大，磨损机理皆以磨粒磨损为主；未处理钢样的耐磨蚀性能处于两种预氧化钢样之间，以磨粒磨损为主，且表面有更多的犁沟和凹坑。

关键词 ：低碳合金钢, 氧化物, 极地船舶, 摩擦腐蚀, 耦合作用

Abstract：

A new F-class marine low-temperature steel plate was firstly pre-corroded to form different oxide scales. Then their reciprocating friction behavior was characterized by means of white light interferometer and scanning electron microscope in terms of the microstructure and wear morphology of the worn steel samples. The results show that the corrosion resistance of the steel samples with γ-FeOOH oxide scale, the original steel samples, and the steel samples with Fe₃O₄ oxide scale become higher in turn. Among them, the steel sample with the dense and complete Fe₃O₄ oxide scale has the lowest amount of wear, the wear scar profile is the shallowest and narrowest, and the surface is dominated by adhesive abrasion, and the corrosion resistance is also the best; the γ-FeOOH oxide scale on the steels is relatively loose with smallest friction coefficient, but the amount of wear is the largest by the coupling of friction and corrosion; the wear mechanism of the steels with the two oxide scales is mainly abrasive wear, and the surface of the untreated steel presents more furrows and pits.

Key words： low-carbon alloy steel oxide polar ship friction corrosion coupling action

收稿日期: 2021-09-23

ZTFLH:

TG174

基金资助:上海市科委技术标准项目(21DZ2205700);上海市教委“曙光”计划(19SG46);科技部国际合作交流项目(CU03-29);上海深海材料工程技术中心(19DZ2253100)

通讯作者: 常雪婷 E-mail: xtchang@shmtu.edu.cn

Corresponding author: CHANG Xueting E-mail: xtchang@shmtu.edu.cn

作者简介: 王超逸，男，1983年生，硕士，高级工程师

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引用本文:

王超逸, 夏呈祥, 王东胜, 强强, 赵子铭, 常雪婷. 新型F级船用低温钢表面氧化物对其耐磨性能影响研究[J]. 中国腐蚀与防护学报, 2022, 42(3): 395-402.
Chaoyi WANG, Chengxiang XIA, Dongsheng WANG, Qiang QIANG, Ziming ZHAO, Xueting CHANG. Effect of Surface Oxides on Wear Resistance of New F-Class Marine Low Temperature Steel. Journal of Chinese Society for Corrosion and protection, 2022, 42(3): 395-402.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2021.254 或 https://www.jcscp.org/CN/Y2022/V42/I3/395

图1 表面氧化处理前后钢样的宏观形貌

图2 预氧化生成不同氧化产物的XRD谱

图3 预氧化生成不同氧化产物的SEM像

图4 裸钢样和两种预氧化钢样的极化曲线

表1 裸钢和预氧化钢样的极化曲线拟合数据

图5 裸钢样和两种预氧化钢样的Nyquist曲线

图6 裸钢和预氧化钢样电化学阻抗谱拟合的等效电路图

表2 裸钢和预氧化钢样电化学阻抗谱拟合参数

图7 裸钢样和两种预氧化钢样的摩擦系数及平均摩擦系数

图8 裸钢样和两种预氧化钢样的磨痕轮廓截面

图9 裸钢样和两种预氧化钢样的磨损量

图10 裸钢样和两种预氧化钢样的摩擦磨损形貌

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