Effect of Magnetic Field on Corrosion Behavior of X52 Pipeline Steel in NaCl Solution

doi:10.11902/1005.4537.2021.117

Journal of Chinese Society for Corrosion and protection

2022, Vol. 42

Issue (3): 501-506 DOI: 10.11902/1005.4537.2021.117

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Effect of Magnetic Field on Corrosion Behavior of X52 Pipeline Steel in NaCl Solution

YANG Yong¹(

), ZHANG Qingbao¹, ZHU Wancheng², LUO Yanlong¹

^1.China Special Equipment Inspection and Research Institute, Beijing 100029, China
^2.Yingmai Oil and Gas Development Department, Petro China Tarim Oilﬁeld Company, Korla 841000, China

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Abstract

Magnetic flux leakage internal inspection is the main method for detecting metal damage in oil and gas pipelines. After the magnetic flux leakage testing is implemented, there will exist a residual magnetic field in the pipeline for a long time. The influence of such residual magnetic field on the corrosion behavior of the pipeline steel is not completely clear yet. Therefore, the influence of different magnetic field intensities (0.9, 1.9 and 2.8 kA/m respectively) on the corrosion behavior of X52 pipeline steel in 3.5%NaCl solution was investigated by means of open circuit potential, polarization curves, electrochemical impedance spectroscopy and corrosion morphology observation techniques. The results indicated that the presence of magnetic field can shift negatively the corrosion potential, increased the corrosion current density, reduced the charge transfer resistance, and changed the corrosion morphology to a certain extent. The greater the magnetic field intensity, the greater the influence on the electrochemical corrosion behavior. Through mechanism analysis, it follows that the influence of magnetic field on the electrochemical reaction process may comprehensively be determined by multiple factors such as the magnetic flux intensity near the electrode surface, the magnetic field gradient, the ion-magnetism and -concentration in the electrolyte. The Loren magnetic force can accelerate the diffusion of Fe²⁺and reduce the thickness of the electric double layer, while the Kelvin force can increase the oxygen content of the electrode interface, all the above factors could promote the corrosion process, the effect of which may be stronger than the corrosion inhibition effect induced by that the Kelvin force causing Fe²⁺ to accumulate on the electrode surface, so that the electrochemical corrosion process was generally promoted.

Key words: magnetic field magnetic flux intensity 3.5%NaCl solution corrosion behavior

Received: 24 May 2021

ZTFLH:

TG174

Fund: Science and Technology Plan Projects of State Administration for Market Regulation(2019MK136);CSEI Research Program(2019-Youth-03)

Corresponding Authors: YANG Yong E-mail: 39530354@qq.com

About author: YANG Yong, E-mail: 39530354@qq.com

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Cite this article:

YANG Yong, ZHANG Qingbao, ZHU Wancheng, LUO Yanlong. Effect of Magnetic Field on Corrosion Behavior of X52 Pipeline Steel in NaCl Solution. Journal of Chinese Society for Corrosion and protection, 2022, 42(3): 501-506.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2021.117 OR https://www.jcscp.org/EN/Y2022/V42/I3/501

Fig.1 Effect of magnetic field on the corrosion potential of X52 pipeline steel: (a) corrosion potential of samples under different magnetic field strengths, (b) the change of sample corrosion potential with different magnetic field strength

Fig.2 Potentiostatic (a) and potentiodynamic (b) polarization curves with magnetic fields

Fig.3 Nyquist (a) and Bode (b) plots of EIS with magnetic fields and equivalent circuit of EIS (c)

Table 1 Equivalent circuit ?tting for the EIS data of samples in NaCl Solution

Fig.4 Optical photographs of X52 steel in 3.5%NaCl solution for 10 d under 0 kA/m (a1, a2), 0.9 kA/m (b1, b2) and 1.9 kA/m (c1, c2) magnetic fields

Fig.5 Schematic diagram of the magnetic flux intensity distribution on the surface of the sample

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