The corrosion behavior of 50% (volume fraction) W particles/Zr41.2Ti13.8Cu12.5Ni10Be22.5 metallic glass matrix composite in 3% (mass fraction) NaCl solution was studied by electrochemical test, immersion test and surface analysis. The result showed that: in 3%NaCl solution, local corrosion microcells were formed on the surface of the composite due to the coupling effect of W particles and metallic glass matrix, the corrosion dissolution on the surface of metallic glass matrix is intensified as a local anodic zone, the corrosion current density of the composite increased, and the corrosion resistance of the composite is significantly lower than that of Zr41.2Ti13.8Cu12.5Ni10Be22.5 metallic glass. The incorporation of 50%W particles have no effect on the pitting resistance of the composite, the uniform corrosion dissolution occurs in the metallic glass site of the composite in 3%NaCl solution, and the composite has better pitting resistance.
SU Xiaohong,HU Huie,KONG Xiaodong. Corrosion Behavior of W Particles/Zr41.2Ti13.8Cu12.5Ni10Be22.5 Metallic Glass Matrix Composite in 3%NaCl Solution. Journal of Chinese Society for Corrosion and protection, 2020, 40(1): 70-74.
Conner R D, Choi-Yim H, Johnson W L. Mechanical properties of Zr57Nb5Al10Cu15.4Ni12.6 metallic glass matrix particulate composites [J]. J. Mater. Res., 1999, 14(8): 3292
[6]
Conner R D, Dandliker R B, Johnson W L. Mechanical properties of tungsten and steel fiber reinforced Zr41.25Ti13.75Cu12.5Ni10Be22.5 metallic glass matrix composites [J]. Acta Mater., 1998, 46(17): 6089
[7]
Inoue A, Kimura H. High-strength aluminum alloys containing nanoquasicrystalline particles [J]. Mater. Sci. Eng., 2000, A286(1): 1
[8]
Hays C C, Kim C P, Johnson W L. Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions [J]. Phys. Rev. Lett., 2000, 84(13): 2901
[9]
Zhang Z F, He G, Zhang H, et al. Rotation mechanism of shear fracture induced by high plasticity in Ti-based nano-structured composites containing ductile dendrites [J]. Scr. Mater., 2005, 52(9): 945
[10]
Srivastava A K, Das K, Toor S K, et al. Corrosion behavior of TiC and (Ti, W) C-reinforced Fe-17Mn and Fe-17Mn-3Al austenitic steel matrix in situ composites [J]. Metallogr., Microstruct., Anal., 2015, 4(5): 371
[11]
Tiwari S, Balasubramaniam R, Gupta M. Corrosion behavior of SiC reinforced magnesium composites [J]. Corros. Sci., 2007, 49(2): 711
[12]
Choi-Yim H, Conner R D, Szuecs F, et al. Quasistatic and dynamic deformation of tungsten reinforced Zr57Nb5Al10Cu15.4Ni12.6 bulk metallic glass matrix composites [J]. Scr. Mater., 2001, 45(9): 1039
[13]
Gostin P F, Sueptitz R, Gebert A, et al. Comparing the corrosion behaviour of Zr66/Ti66-Nb13Cu8Ni6.8Al6.2 bulk nanostructure-dendrite composites [J]. Intermetallics, 2008, 16(10): 1179
[14]
Wang Y H, Yang Y S. Amorphous Metallic Alloys [M]. Beijing: Metallurgical Industry Press, 1989
[14]
(王一禾, 杨鹰善. 非晶态合金 [M]. 北京: 冶金工业出版社, 1989)
[15]
Liu G F, Li H F, Zheng J S, et al. Corrosion behavior of 55% Al-Zn coating in salt solution containing hydrogen sulfide [J]. Mater. Prot., 2002, 35(5): 13
Ma H J, Gu Y H, Liu S J, et al. Local corrosion behavior and model of micro-arc oxidation HA coating on AZ31 magnesium alloy [J]. Surf. Coat. Technol., 2017, 331: 179