Corrosion Behavior of W Particles/Zr41.2Ti13.8Cu12.5Ni10Be22.5 Metallic Glass Matrix Composite in 3%NaCl Solution

doi:10.11902/1005.4537.2019.225

Journal of Chinese Society for Corrosion and protection

2020, Vol. 40

Issue (1): 70-74 DOI: 10.11902/1005.4537.2019.225

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Corrosion Behavior of W Particles/Zr_41.2Ti_13.8Cu_12.5Ni₁₀Be_22.5 Metallic Glass Matrix Composite in 3%NaCl Solution

SU Xiaohong,HU Huie(

),KONG Xiaodong

Department of Basic Course, Naval University of Engineering, Wuhan 430033, China

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Abstract

The corrosion behavior of 50% (volume fraction) W particles/Zr_41.2Ti_13.8Cu_12.5Ni₁₀Be_22.5 metallic glass matrix composite in 3% (mass fraction) NaCl solution was studied by electrochemical test, immersion test and surface analysis. The result showed that: in 3%NaCl solution, local corrosion microcells were formed on the surface of the composite due to the coupling effect of W particles and metallic glass matrix, the corrosion dissolution on the surface of metallic glass matrix is intensified as a local anodic zone, the corrosion current density of the composite increased, and the corrosion resistance of the composite is significantly lower than that of Zr_41.2Ti_13.8Cu_12.5Ni₁₀Be_22.5 metallic glass. The incorporation of 50%W particles have no effect on the pitting resistance of the composite, the uniform corrosion dissolution occurs in the metallic glass site of the composite in 3%NaCl solution, and the composite has better pitting resistance.

Key words: metallic glass matrix composite corrosion behavior galvanic couple pitting resistance

Received: 05 May 2019

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(51575522)

Corresponding Authors: Huie HU E-mail: huhuie_nue@163.com

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SU Xiaohong,HU Huie,KONG Xiaodong. Corrosion Behavior of W Particles/Zr_41.2Ti_13.8Cu_12.5Ni₁₀Be_22.5 Metallic Glass Matrix Composite in 3%NaCl Solution. Journal of Chinese Society for Corrosion and protection, 2020, 40(1): 70-74.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2019.225 OR https://www.jcscp.org/EN/Y2020/V40/I1/70

Fig.1 Open circuit potential-time curves of the two mater-ials in 3%NaCl solution

Fig.2 Polarization curves of the two materials

Table 1 Electrochemical data of the two materials in 3% NaCl solution

Fig.3 Nyquist (a) and Bode diagrams of metallic glass matrix composite (b) and metallic glass materials (c)

Fig.4 SEM images of the metallic glass matrix composite (a, b) and metallic glass (c, d) after immer-sion in 3%NaCl solution for 21 d

Fig.5 EDS analysis of metallic glass matrix composite (a) and metallic glass (b) after immersion in 3%NaCl solution for 21 d

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