Please wait a minute...
Just Accepted | Current Issue | Archive | Featured Articles | Special Issue | Most Read | Most Downloaded | Most Cited
Journal of Chinese Society for Corrosion and protection  2016, Vol. 36 Issue (4): 375-380    DOI: 10.11902/1005.4537.2015.162
Current Issue | Archive | Adv Search |
Influence of Short-term Storage on Corrosion Behavior of Copper
Lin FENG,Yanhua WANG(),Lian ZHONG,Jia WANG,Aijiao LI,Xiaoxiao JIN
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China
Download:  HTML  PDF(1802KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

The influence of short-term storage in dry atmosphere on the corrosion behavior of copper was investigated by means of potentiodynamic polarization, electrochemical impedance spectroscopy, capacitance measurement and array electrode technique. It was found that the surface film on copper presented a p-type semiconductor structure, and the carrier concentration decreased after short-term storage. At the same time, the corrosion potential increased, the corrosion current density decreased, and the surface film inhibited both the cathodic and anodic process. Copper displayed the typical characteristics of localized corrosion beneath a NaCl droplet. After storage, the wet-ability, the corrosion activity as well as the overall average corrosion intensity are reduced, but the local corrosion intensity enhanced.
Key words:  array electrode      short-term storage      copper      mott-schottky plot      droplet      corrosion     
Service
E-mail this article
Add to citation manager
E-mail Alert
RSS
（）
Articles by authors
Lin FENG
Yanhua WANG
Lian ZHONG
Jia WANG
Aijiao LI
Xiaoxiao JIN

Cite this article: 

Lin FENG,Yanhua WANG,Lian ZHONG,Jia WANG,Aijiao LI,Xiaoxiao JIN. Influence of Short-term Storage on Corrosion Behavior of Copper. Journal of Chinese Society for Corrosion and protection, 2016, 36(4): 375-380.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2015.162     OR     https://www.jcscp.org/EN/Y2016/V36/I4/375

Fig.1  Mott-Schottky plots of fresh and passivated samples in 0.05 mol/L Na2SO4 solution
Sample a b N / cm-3 Efb / V
Fresh 2.09×1014 -9.41×1015 3.21×1019 -3.45×10-3
Passivated 2.71×1014 -1.52×1016 1.98×1019 -7.92×10-3
Table 1  Electrochemical parameters of fresh and passivated samples in 0.05 mol/L Na2SO4 solution
Fig.2  Potentiodynamic polarization curves (a) and electrochemical impedance spectra (b) of fresh and passivated samples in 0.6 mol/L NaCl solution
Fig.3  Galvanic current distributions on the surfaces of fresh (a, c, e, g) and passivated (b, d, f, h) WBE electrodes after corrosion under the droplet of 25 μL 0.6 mol/L NaCl solution for 2 h (a, b), 6 h (c, d), 8 h (e, f) and 12 h (g, h)
Fig.4  Variations of iAverage (a), IAverage (b), Ia,max (c) and local corrosion intensity index LCII (d) of fresh and passivated samples with corrosion time
[1] Wu J, Zhou X L, Dong C F, et al.Research progress on atmospheric corrosion of copper and its alloys[J]. Corros. Sci. Prot. Technol., 2010, 22(5): 464
[1] (吴军, 周贤良, 董超芳等. 铜及铜合金大气腐蚀研究进展[J]. 腐蚀科学与防护技术, 2010, 22(5): 464
[2] Vera R, Delgado D, Rosales B M.Effect of atmospheric pollutants on the corrosion of high power electrical conductors-Part 2. Pure copper[J]. Corros. Sci., 2007, 49(5): 2329
[3] Kear G, Barker B D, Walsh F C.Electrochemical corrosion of unalloyed copper in chloride media—A critical review[J]. Corros. Sci., 2004, 46(1): 109
[4] Duran B, Turhan M C, Bereket G, et al.Electropolymerization, characterization and corrosion performance of poly (N-ethylaniline) on copper[J]. Electrochim. Acta, 2009, 55(1): 104
[5] Mendoza A R, Corvo F, Gómez A, et al.Influence of the corrosion products of copper on its atmospheric corrosion kinetics in tropical climate[J]. Corros. Sci., 2004, 46(5): 1189
[6] Fonseca I T E, Picciochi R, Mendon?a M H, et al. The atmospheric corrosion of copper at two sites in Portugal: A comparative study[J]. Corros. Sci., 2004, 46(3): 547
[7] Zou S, Li X, Dong C, et al.Electrochemical migration, whisker formation, and corrosion behavior of printed circuit board under wet H2S environment[J]. Electrochim. Acta, 2013, 114: 363
[8] Huang H, Guo X, Zhang G, et al.Effect of direct current electric field on atmospheric corrosion behavior of copper under thin electrolyte layer[J]. Corros. Sci., 2011, 53(10): 3446
[9] Hernández R D P B, Aoki I V, Tribollet B, et al. Electrochemical impedance spectroscopy investigation of the electrochemical behaviour of copper coated with artificial patina layers and submitted to wet and dry cycles[J]. Electrochim. Acta, 2011, 56(7): 2801
[10] Watanabe M, Higashi Y, Tanaka T.Differences between corrosion products formed on copper exposed in Tokyo in summer and winter[J]. Corros. Sci., 2003, 45(7): 1439
[11] Lin C, Li X G, Wang G Y.Research progress on initial stage of atmospheric corrosion behavior of metals in pollutant atmospherics[J]. Corros. Sci. Prot. Technol., 2004, 16(2): 89
[11] (林翠, 李晓刚, 王光雍. 金属材料在污染大气环境中初期腐蚀行为和机理研究进展[J]. 腐蚀科学与防护技术, 2004, 16(2): 89)
[12] Chen Z Y, Persson D, Samie F, et al.Effect of carbon dioxide on sodium chloride-induced atmospheric corrosion of copper[J]. J. Electrochem. Soc., 2005, 152(12): B502
[13] Cole I S, Ganther W D.Experimental determination of time taken for openly exposed metal surfaces to dry[J]. Corros. Eng. Sci. Technol., 2006, 41(2): 161
[14] Sato N.Toward a more fundamental understanding of corrosion processes[J]. Corrosion, 1989, 45(5): 354
[15] Szklarska-Smialowska Z.Mechanism of pit nucleation by electrical breakdown of the passive film[J]. Corros. Sci., 2002, 44(5): 1143
[16] Stimming U.Photoelectrochemical studies of passive films[J]. Electrochim. Acta, 1986, 31(4): 415
[17] Knauth P, Massiani Y.Mott-Schottky analysis of polycrystalline copper (I) bromide in aqueous electrolytes[J]. J. Electroanal. Chem., 1998, 42(1/2): 229
[18] Fattah-Alhosseini A, Soltani F, Shirsalimi F, et al.The semiconducting properties of passive films formed on AISI 316 L and AISI 321 stainless steels: A test of the point defect model (PDM)[J]. Corros. Sci., 2011, 53(10): 3186
[19] Young K F, Frederikse H P R. Compilation of the static dielectric constant of inorganic solids[J]. Phys. Chem. Ref. Data, 1973, 2(2): 2313
[20] Ye W, Li Y, Wang F.Effects of nanocrystallization on the corrosion behavior of 309 stainless steel[J]. Electrochim. Acta, 2006, 51(21): 4426
[21] Macdonald D D.The point defect model for the passive state[J]. J. Electrochem. Soc., 1992, 139(12): 3434
[22] Li C T, Cheng X Q, Dong C F, et al.Influence of Cl- on the corrosion electrochemical behavior of Alloy 690[J]. J. Univ. Sci. Technol. Beijing, 2011, 33(4): 444
[22] (李成涛, 程学群, 董超芳等. Cl-对690合金腐蚀电化学行为的影响[J]. 北京科技大学学报, 2011, 33(4): 444
[23] Kang J, Yang Y, Jiang X, et al.Semiconducting properties of passive films formed on electroplated Ni and Ni-Co alloys[J]. Corros. Sci., 2008, 50(12): 3576
[24] Alves V A, Brett C M A. Influence of alloying on the passive behaviour of steels in bicarbonate medium[J]. Corros. Sci., 2002, 44(9): 1949
[25] Ningshen S, Kamachi M U, Mittal V K, et al.Semiconducting and passive film properties of nitrogen-containing type 316LN stainless steels[J]. Corros. Sci., 2007, 49(2): 481
[26] Muster T H, Bradbury A, Trinchi A, et al.The atmospheric corrosion of zinc: The effects of salt concentration, droplet size and droplet shape[J]. Electrochim. Acta, 2011, 56(4): 1866
[27] Xu R, Wang Y H, Wang J, et al.Influence of spreadability of seawater droplet on electrochemical characteristics of carbon steel[J].Chin. J. Mater. Res., 2015, 29(2): 95
[27] (续冉, 王燕华, 王佳等. 海水液滴铺展因子对碳钢表面电化学特性的影响[J]. 材料研究学报, 2015, 29(2): 95
[28] Tan Y, Aung N N, Liu T.Evaluating localised corrosion intensity using the wire beam electrode[J]. Corros. Sci., 2012, 63: 379
[29] Yang M, Wang Z Y.Review of atmospheric corrosion of copper[J]. Equip. Environ. Eng., 2006, 3(4): 38
[29] (杨敏, 王振尧. 铜的大气腐蚀研究[J]. 装备环境工程, 2006, 3(4): 38
[30] Gao Q, Mao L, Wu L C, et al.Atmospheric corrosion of copper[J]. J. Hebei Univ. Sci. Technol., 2003, 24(4):29
[30] (高青, 毛磊, 吴立成等. 铜在大气中的腐蚀[J]. 河北科技大学学报, 2003, 24(4): 29)
[1] ZHENG Li, WANG Meiting, YU Baoyi. Research Progress of Cold Spraying Coating Technology for Mg-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 22-28.
[2] WEI Zheng, MA Baoji, LI Long, LIU Xiaofeng, LI Hui. Effect of Ultrasonic Rolling Pretreatment on Corrosion Resistance of Micro-arc Oxidation Coating of Mg-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 117-124.
[3] YU Hongfei, SHAO Bo, ZHANG Yue, YANG Yange. Preparation and Properties of Zr-based Conversion Coating on 2A12 Al-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 101-109.
[4] HUANG Peng, GAO Rongjie, LIU Wenbin, YIN Xubao. Fabrication of Superamphiphobic Surface for Nickel-plate on Pipeline Steel by Salt Solution Etching and Its Anti-corrosion Properties[J]. 中国腐蚀与防护学报, 2021, 41(1): 96-100.
[5] DONG Xucheng, GUAN Fang, XU Liting, DUAN Jizhou, HOU Baorong. Progress on the Corrosion Mechanism of Sulfate-reducing Bacteria in Marine Environment on Metal Materials[J]. 中国腐蚀与防护学报, 2021, 41(1): 1-12.
[6] TANG Rongmao, ZHU Yichen, LIU Guangming, LIU Yongqiang, LIU Xin, PEI Feng. Gray Correlative Degree Analysis of Q235 Steel/conductive Concrete Corrosion in Three Typical Soil Environments[J]. 中国腐蚀与防护学报, 2021, 41(1): 110-116.
[7] HAN Yuetong, ZHANG Pengchao, SHI Jiefu, LI Ting, SUN Juncai. Surface Modification of TA1 Bipolar Plate for Proton Exchange Membrane Fuel Cell[J]. 中国腐蚀与防护学报, 2021, 41(1): 125-130.
[8] ZHANG Yuxuan, CHEN Cuiying, LIU Hongwei, LI Weihua. Research Progress on Mildew Induced Corrosion of Al-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 13-21.
[9] RAN Dou, MENG Huimin, LIU Xing, LI Quande, GONG Xiufang, NI Rong, JIANG Ying, GONG Xianlong, DAI Jun, LONG Bin. Effect of pH on Corrosion Behavior of 14Cr12Ni3WMoV Stainless Steel in Chlorine-containing Solutions[J]. 中国腐蚀与防护学报, 2021, 41(1): 51-59.
[10] BAI Yunlong, SHEN Guoliang, QIN Qingyu, WEI Boxin, YU Changkun, XU Jin, SUN Cheng. Effect of Thiourea Imidazoline Quaternary Ammonium Salt Corrosion Inhibitor on Corrosion of X80 Pipeline Steel[J]. 中国腐蚀与防护学报, 2021, 41(1): 60-70.
[11] ZUO Yong, CAO Mingpeng, SHEN Miao, YANG Xinmei. Effect of Mg on Corrosion of 316H Stainless Steel in Molten Salts MgCl2-NaCl-KCl[J]. 中国腐蚀与防护学报, 2021, 41(1): 80-86.
[12] WANG Yating, WANG Kexu, GAO Pengxiang, LIU Ran, ZHAO Dishun, ZHAI Jianhua, QU Guanwei. Inhibition for Zn Corrosion by Starch Grafted Copolymer[J]. 中国腐蚀与防护学报, 2021, 41(1): 131-138.
[13] WANG Xintong, CHEN Xu, HAN Zhenze, LI Chengyuan, WANG Qishan. Stress Corrosion Cracking Behavior of 2205 Duplex Stainless Steel in 3.5%NaCl Solution with Sulfate Reducing Bacteria[J]. 中国腐蚀与防护学报, 2021, 41(1): 43-50.
[14] SHI Kunyu, WU Weijin, ZHANG Yi, WAN Yi, YU Chuanhao. Electrochemical Properties of Nb Coating on TC4 Substrate in Simulated Body Solution[J]. 中国腐蚀与防护学报, 2021, 41(1): 71-79.
[15] ZHANG Hao, DU Nan, ZHOU Wenjie, WANG Shuaixing, ZHAO Qing. Effect of Fe3+ on Pitting Corrosion of Stainless Steel in Simulated Seawater[J]. 中国腐蚀与防护学报, 2020, 40(6): 517-522.
No Suggested Reading articles found!

Copyright © 2017 Journal of Chinese Society for Corrosion and protection, All Rights Reserved.
Editorial Office: Journal of Chinese Society for Corrosion and Protection, 72 Wenhua Rd., Shenyang 110016, China
Tel: +86- 024-23971318, Fax: +86-024-23971819 　E-mail: jcscp@imr.ac.cn
Powered by Beijing Magtech