Please wait a minute...
Journal of Chinese Society for Corrosion and protection  2015, Vol. 35 Issue (2): 99-105    DOI: 10.11902/1005.4537.2014.047
Current Issue | Archive | Adv Search |
Summary on Corrosion Behavior and Micro-arc Oxidation for Magnesium Alloys
LIU Yin1(), LIU Shimei2, YU Luping1, LIU Jun1, JIANG Wei1
1. Aerospace Science and Industry Corporation Inertia Technologies Co., Ltd., Beijing 100074, China
2. Beijing Institute of Automatic Control Equipment, Beijing 100074, China
Download:  HTML  PDF(1563KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

Corrosion phenomena such as galvanic corrosion, pitting, stress corrosion cracking and corrosion fatigue as well as the relevant anti-corrosion measures for magnesium alloys were summarized and analyzed. The micro-arc oxidation (MAO) technology for Mg-alloys was introduced in the aspects of process technique, film structure, corrosion resistance, abrasion resistance, sealing treatment, film inspection and post-repair processing etc., while, the effect of structure and thickness of films on their corrosion resistance was emphasized. The performance of sliding wear, fretting wear and impact wear of the MAO films was also introduced. It is noted that a proper sealing treatment can effectively improved the entire film density, and thereby the corrosion resistance of the MAO films.

Key words:  magnesium alloy      micro-arc oxidation      corrosion resistance      frictional wear      sealing     
Received:  30 March 2014     
ZTFLH:  TG146.2  

Cite this article: 

LIU Yin, LIU Shimei, YU Luping, LIU Jun, JIANG Wei. Summary on Corrosion Behavior and Micro-arc Oxidation for Magnesium Alloys. Journal of Chinese Society for Corrosion and protection, 2015, 35(2): 99-105.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2014.047     OR     https://www.jcscp.org/EN/Y2015/V35/I2/99

Fig.1  Structure of oxide film formed on magnesium alloy
Fig.2  Surface (a) and sectional morphologies (b) of micro-arc oxidation coating of AZ91D[31]
[1] Ding W J, Fu P H, Peng L M, et al. Advanced magnesium alloys and their applications in aerospace[J]. Spacecraft Environ. Eng., 2011, 28(2): 103
(丁文江, 付彭怀, 彭立明等. 先进镁合金材料及其在航空航天领域中的应用[J]. 航天器环境工程, 2011, 28(2): 103)
[2] Xiao B, Kang F, Hu C K, et al. Application of the light structure material in the defense industry abroad[J]. Ordnance Mater. Sci. Eng.,2011, 34(1): 94
(肖冰, 康凤, 胡传凯等. 国外轻质结构材料在国防工业中的应用[J]. 兵器材料科学与工程, 2011, 34(1): 94)
[3] Wang F H, Du K Q, Zhang W. Progress in research of corrosion and protection of magnesium alloys[J]. Mater. China, 2011, 30(2): 29
(王福会, 杜克勤, 张伟. 镁合金的腐蚀与防护研究进展[J]. 中国材料进展, 2011, 30(2): 29)
[4] Xu H,Liu J A,Xie S S. Preparation and Processing of Magnesium Alloy Technology[M]. Beijing: Metallurgical Industry Press, 2007
(徐河,刘静安,谢水生. 镁合金制备与加工技术[M]. 北京: 冶金工业出版社, 2007)
[5] Chen Z H. Magnesium Alloy[M]. Beijing: Chemical Industry Press, 2004
(陈振华. 镁合金[M]. 北京: 化学工业出版社, 2004)
[6] Han E-H, Ke W. Corrosion and protection status and prospects of magnesium alloy [A]. China Magnesium Industry Annual Conference Proceedings [C]. Beijing: 2002, 83
(韩恩厚, 柯伟. 镁合金的腐蚀与防护现状与展望 [A]. 全国镁行业年会会议论文集 [C]. 北京: 2002, 83)
[7] Wei Y H,Xu B S. Theory and Practice of Magnesium Alloy Corrosion Protection[M]. Beijing: Metallurgical Industry Press, 2007
(卫英慧,许并社. 镁合金腐蚀防护的理论与实践[M]. 北京: 冶金工业出版社, 2007)
[8] Avedesian M M, Baker H. ASM Specialty Handbook Magnesium and Magnesium Alloys [M]. Ohio: ASM International, 1999
[9] Zhu R X. Research on corrosion of magnesium alloy in service environment[J]. Equip. Environ. Eng., 2006, 3(4): 50
(朱绒霞. 服役环境下镁合金材料腐蚀的研究[J]. 装备环境工程, 2006, 3(4): 50)
[10] Li Y, Song G L, Lin H C, et al. Study on the relationship between the corrosion interface structure and negative difference effect for pure magnesium[J]. Corros. Sci. Prot. Technol., 1999, 11(4): 202
(李瑛, 宋光铃, 林海潮等. 金属镁在腐蚀介质中界面结构特征与负差数效应关系研究[J]. 腐蚀科学与防护技术, 1999, 11(4):202)
[11] Xu H Y, Li Z Y. Galvanic corrosion of AZ91D magnesium alloy[J]. J. Chin. Soc. Corros. Prot., 2013, 33(4): 298
(徐宏妍, 李智勇. AZ91D镁合金电偶腐蚀的研究[J]. 中国腐蚀与防护学报, 2013, 33(4): 298)
[12] Miller P I, Shaw B A, Wendt R G, et al. Assessing the corrosion resistance of noneqilibrium magnesium-yttrium alloys[J]. Corrosion, 1995, 51(12): 922
[13] Daloz D, Steinmetz P, Michot G. Corrosion behavior of rapidly solidified magnesium-aluminum-zinc alloys[J]. Corrosion, 1997, 53(12): 944
[14] Zhang Y, Xu Y. Influencing factors and protective methods of stress corrosion cracking of magnesium alloys[J]. J. Harbin Inst. Technol., 2009, 41(6): 87
(张勇, 许越. 镁合金应力腐蚀开裂敏感性影响因素及防护措施[J]. 哈尔滨工业大学学报, 2009, 41(6): 87)
[15] Liu G L. Electronic theoretical study on the influence of rare earth on the stress corrosion in magnesium alloy[J]. Acta Phys. Sin., 2006, 55(12): 6570
(刘贵立. 稀土对镁合金应力腐蚀影响电子理论研究[J]. 物理学报, 2006, 55(12): 6570)
[16] Winzer N, Song G, Atrens A, et al. Evaluation of the delayed hydride cracking mechanism for transgranular stress corrosion cracking of magnesium alloys[J]. Mater. Sci. Eng., 2007, A466(1/2): 18
[17] Perer S P, You D K. Corrosion fatigue failure[J]. Ordnance Mater. Sci. Eng., 1990, 13(9): 54
(Peter S P, 尤东凯. 腐蚀疲劳失效[J]. 兵器材料科学与工程, 1990, 13(9): 54)
[18] Zhang A M, Quan G F. Prospect and research progress of fatigue properties of magnesium alloys[J]. Mater. Mech. Eng., 2010, 34(5): 1
(张爱民, 权高峰. 镁合金疲劳性能的研究现状及展望[J]. 机械工程材料, 2010, 34(5): 1)
[19] Chen L J, Liu Z, Hu Z Q. Present and development of research on fatigue behavior of magnesium alloys[J]. J. Shenyang Univ. Technol., 2005, 27(3): 253
(陈立佳, 刘正, 胡壮麒. 镁合金疲劳行为的研究现状及展望[J]. 沈阳工业大学学报, 2005, 27(3): 253)
[20] Liu M B, Lei J, Gao Y X, et al. Corrosion fatigue of die-cast magnesium alloys[J]. J. Aeronaut. Mater., 2007, 27(1): 76
(刘马宝, 雷军, 高玉侠. 压铸镁合金腐蚀疲劳性能的研究[J]. 航空材料学报, 2007, 27(1): 76)
[21] Zeng R C, Han E-H, Liu L, et al. Effect of rolled microstructure on fatigue properties of magnesium alloy AM60[J]. Chin. J. Mater. Res., 2003, 17(3): 241
(曾荣昌, 韩恩厚, 刘路等. 轧制组织对镁合金AM60疲劳性能的影响[J]. 材料研究学报, 2003, 17(3): 241)
[22] Yu G, Liu Y L, Li Y, et al. Corrosion and protection of magnesium alloys[J]. Chin. J. Nonferrous Met., 2002, 12(6): 1087
(余刚, 刘跃龙, 李瑛等. Mg合金的腐蚀与防护[J]. 中国有色金属学报, 2002, 12(6): 1087)
[23] Zhao Y F, Yang S Y, Han M W, et al. Technique of plasma microarc oxidation and its development[J]. Mater. Rev., 2006, 20(6): 102
(赵玉峰, 杨世彦, 韩明武等. 离子体MAO技术及其发展[J]. 材料导报, 2006, 20(6): 102)
[24] Jiang B L, Zhang X F. Growth process and corrosion resistance of ceramic coatings formed by micro-oxidation on magnesium alloy[J]. J. Chin. Soc. Corros. Prot., 2005, 25(2): 97
(蒋百灵, 张先锋. 镁合金MAO陶瓷层的生长过程及其耐蚀性[J]. 中国腐蚀与防护学报, 2005, 25(2): 97)
[25] Wang Y H. Studies on the growth process and corrosion behavior of micro-arc oxidation coatings on magnesium alloy [D]. Qingdao: Institute of Oceanology, Chinese Academy of Sciences, 2005
(王燕华. 镁合金MAO膜的形成过程及腐蚀行为研究 [D]. 青岛: 中国科学院海洋研究所, 2005)
[26] Duan G W, Gao X J, Man H, et al. Research progress in micro-arc oxidation[J]. Ordnance Mater. Sci. Eng., 2010, 33(5): 102
(段关文, 高晓菊, 满红等. MAO研究进展[J]. 兵器材料科学与工程, 2010, 33(5): 102)
[27] Xue W B, Deng Z W, Lai Y C, et al. Growth patterns of micro-arc oxidation coating on ZM5 magnesium alloy[J]. Trans. Met. Heat Treat., 1998, 19(3): 42
(薛文斌, 邓志威, 来永春等. ZM5镁合金MAO膜的生长规律[J]. 金属热处理学报, 1998, 19(3): 42)
[28] Ma Y, Zhang H F, Hao Y, et al. Interaction of heat-treatment and micro-oxidation on AZ91D magnesium alloys[J]. Chin. J. Mater. Res., 2009, 23(6): 656
(马颖, 张洪锋, 郝远等. AZ91D镁合金热处理与MAO的交互作用[J]. 材料研究学报, 2009, 23(6): 656)
[29] Liu Y G, Zhang W, Gao J, et al. Painting of magnesium alloys based on microarc electrodeposition[J]. J. Univ. Sci. Technol. Beijing, 2005, 27(2): 213
(刘元刚, 张巍, 高瑾等. 镁合金MAO-涂装体系的研究[J]. 北京科技大学学报, 2005, 27(2): 213)
[30] Yuan B, Yuan S, Jiang B L, et al. Corrosion resistance of magnesium alloy with complex surface-modifying micro-arc oxidation coating and organic coating studied by neutral salt spraying[J]. J. Mater. Prot., 2006, 39(9): 15
(袁兵, 袁森, 蒋百灵等. 镁合金MAO及后续涂装耐盐雾腐蚀的研究[J]. 材料保护, 2006, 39(9): 15)
[31] Zhang Y, Chen Y L, Yu D Z, et al. Influence of micro-arc oxidation on mechanical properties of magnesium alloys AZ91D[J]. J. Chin. Soc. Corros. Prot., 2010, 30(3): 222
(张勇, 陈跃良, 郁大照等. MAO对AZ91D镁合金力学性能的影响[J]. 中国腐蚀与防护学报, 2010, 30(3): 222)
[32] Hao J M, Chen H, Zhang R J, et al. Corrosion resistance of magnesium alloy micro-arc oxidization ceramic coating[J]. Chin. J. Nonferrous Met., 2003, 13(4): 988
(郝建民, 陈宏, 张荣军等. 镁合金MAO陶瓷层的耐蚀性[J]. 中国有色金属学报, 2003, 13(4): 988)
[33] Chen X M, Luo C P, Liu J W, et al. Structure of ceramic coating produces by micro-arc oxidation on mg alloy[J]. J. Cent. South Univ., 2006, 37(6): 1065
(陈显明, 罗承萍, 刘江文等. 镁合金MAO膜层结构[J]. 中南大学学报, 2006, 37(6): 1065)
[34] Chen X M, Luo C P, Liu J W, et al. Mechanisms for the formation of porous micro-arc oxidation coatings on magnesium alloys[J]. J. Mater. Prot., 2009, 42(1): 1
(陈显明, 罗承萍, 刘江文等. 镁合金微弧氧华表面层多孔结构的形成机制[J]. 材料保护, 2009, 42(1): 1)
[35] Miao Y J, Shen C J, Liu J J. Corrosion resistance of ceramic layer on AZ91D magnesium alloy formed by micro-arc oxidation[J]. Light Alloy Fabr. Technol., 2006, 34(10): 43
(缪姚军, 沈承金, 刘建军. AZ91D镁合金MAO膜耐蚀性的试验研究[J]. 轻合金加工技术, 2006, 34(10): 43)
[36] Zhi Q, Gao J, Dong C F, et al. Corrosion behavior of microarc oxidation film on AZ91D magnesium alloy[J]. Acta Metall. Sin., 2008, 44(8): 986
(郅青, 高瑾, 董超芳等. AZ91D镁合金MAO膜的腐蚀行为研究[J]. 金属学报, 2008, 44(8): 986)
[37] Zhang Y, Chen Y L, Yu D Z, et al. Influence of thickness of micro-arc oxidation coatings on corrosion resistance of AZ91D magnesium alloy [J]. Corros. Prot., 2010, 31(2): 131
(张勇, 陈跃良, 郁大照等. AZ91D镁合金MAO膜厚对其耐蚀性的影响[J]. 腐蚀与防护, 2010, 31(2): 131)
[38] Chen M, Ma Y Z, Ma Y, et al. Effects of voltage increment on performances of micro-arc oxidation coating of magnesium alloys[J]. Rare Met. Mater. Eng., 2010, 39(11): 1943
(陈明, 马跃洲, 马颖等. 电压增幅对镁合金MAO膜层性能的影响[J]. 稀有金属材料与工程, 2010, 39(11): 1943)
[39] Zeng Z H, Lou B Y. Corrosion resistance and wear behavior under corrosive environment of micro-arc oxidation coating on magnesium alloy[J]. J. Mater. Sci. Eng., 2011, 29(3): 433
(曾志恒, 楼白杨. 镁合金MAO膜的耐蚀性及其在腐蚀介质下的磨损行为[J] .材料科学与工程学报, 2011, 29(3): 433)
[40] Bala S P, Zettler R, Blawert C, et al. A study on the effect of plasma electrolytic oxidation on the stress corrosion cracking behaviour of a wrought AZ61 magnesium alloy and its friction stir weldment[J]. Mater. Charact., 2009, 60: 389
[41] Peng J H, Huang F L, Liu G, et al. Dry sliding wear behavior of AZ91D mg alloy with micro-arc-oxidation coating[J]. Chin. J. Nonferrous Met., 2009, 19(6): 981
(彭继华, 黄芳亮, 刘刚等. AZ91D镁合金MAO涂层的干摩擦磨损行为[J]. 中国有色金属学报, 2009, 19(6): 981)
[42] Chen F, Zhou H, Yao B, et al. Study on the tribological behavior of micro-arc oxidized ceramic coatings on magnesium alloy surfaces[J]. Rare Met. Mater. Eng., 2006, 35(5): 806
(陈飞, 周海, 姚斌等. 镁合金表面MAO陶瓷层摩擦学性能的研究[J]. 稀有金属材料与工程, 2006, 35(5): 806)
[43] Zhang H. Study on fretting wear of magnesium alloy and surface treatment [D]. Chengdu: Southwest Jiaotong University, 2007
(张晖. 镁合金及表面处理微动磨损研究 [D]. 成都: 西南交通大学, 2007)
[44] Cai L J. Study on impact wear characteristics of ZM5 magnesium alloy and micro-arc oxidation ceramic layer [D]. Chengdu: Southwest Jiaotong University, 2007
(蔡立君. ZM5镁合金及其MAO陶瓷层的冲击磨损特性研究[D]. 成都: 西南交通大学, 2007)
[45] Li Y, Niu L Y, Gao G L, et al. Effect of processing parameters of microarc oxidation and sealing treatment on corrosion resistance of magnesium alloy[J]. Surf. Technol., 2008, 37(6): 14
(李勇, 牛丽媛, 高光亮等. MAO工艺及封孔处理对镁合金耐蚀性能的影响[J]. 表面技术, 2008, 37(6): 14)
[46] Jiang B L, Zhang S F, Wu G J. The study of the corrosion resistance of the ceramic coatings formed by micro-arc oxidation on the mg-base alloy[J]. J. Chin. Soc. Corros. Prot., 2002, 22(5): 300
(蒋百灵, 张淑芬, 吴国建. 镁合金MAO陶瓷层耐蚀性的研究[J]. 中国腐蚀与防护学报, 2002, 22(5): 300)
[47] Wang Z C, Tang Y, Xu J. Study on the micro-arc oxidation and surface treatment of AZ91D magnesium alloy[J]. J. Xiamen Univ., 2006, 45(5): 292
(王周成, 唐毅, 许杰. AZ91D镁合金微弧阳极氧化及表面处理研究[J]. 厦门大学学报, 2006, 45(5): 292)
[48] Shi H Y, Yang C J, Zhang M. Corrosion resistance of micro-arc oxidation and sol-gel composite coating on magnesium alloy by cyclic heat-NaCl solution spray/dry test[J]. J. Chin. Soc. Corros. Prot. 2013, 33(5): 435
(时惠英, 杨朝静, 张勉. AZ31B镁合金表面MAO-溶胶凝胶复合膜层干、湿热交替条件下耐蚀性研究[J]. 中国腐蚀与防护学报, 2013, 33(5): 435)
[49] Shang W. Preparation and corrosion resistance of the composite coatings treated by micro arc oxidation and sol-gel on magnesium alloy AZ91D [D]. Changsha: Central South University, 2011
(尚伟. AZ91D镁合金MAO-溶胶凝胶复合膜层制备及其耐蚀性[D]. 长沙: 中南大学, 2011)
[50] Bin Y H, Liu Y, Li W, et al. Sealing process of micro-arc oxidation and sol-gel coatings on magnesium alloy[J]. Mater. Prot., 2012,45(3): 75
(宾远红, 刘英, 李卫等. 镁合金MAO膜溶胶-凝胶封孔工艺[J]. 材料保护, 2012, 45(3): 75)
[1] WEI Zheng, MA Baoji, LI Long, LIU Xiaofeng, LI Hui. Effect of Ultrasonic Rolling Pretreatment on Corrosion Resistance of Micro-arc Oxidation Coating of Mg-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 117-124.
[2] HAN Yuetong, ZHANG Pengchao, SHI Jiefu, LI Ting, SUN Juncai. Surface Modification of TA1 Bipolar Plate for Proton Exchange Membrane Fuel Cell[J]. 中国腐蚀与防护学报, 2021, 41(1): 125-130.
[3] SHI Kunyu, WU Weijin, ZHANG Yi, WAN Yi, YU Chuanhao. Electrochemical Properties of Nb Coating on TC4 Substrate in Simulated Body Solution[J]. 中国腐蚀与防护学报, 2021, 41(1): 71-79.
[4] BAO Ren, ZHOU Genshu, LI Hongwei. Preparation of High-tin Bronze Corrosion-resistant Coating by Potentiostatic Pulse Electrodeposition[J]. 中国腐蚀与防护学报, 2020, 40(6): 585-591.
[5] YUE Liangliang, MA Baoji. Effect of Ultrasonic Surface Rolling Process on Corrosion Behavior of AZ31B Mg-alloy[J]. 中国腐蚀与防护学报, 2020, 40(6): 560-568.
[6] LIU Haixia, HUANG Feng, YUAN Wei, HU Qian, LIU Jing. Corrosion Behavior of 690 MPa Grade High Strength Bainite Steel in a Simulated Rural Atmosphere[J]. 中国腐蚀与防护学报, 2020, 40(5): 416-424.
[7] LI Congwei, DU Shuangming, ZENG Zhilin, LIU Eryong, WANG Feihu, MA Fuliang. Effect of Current Density on Microstructure, Wear and Corrosion Resistance of Electrodeposited Ni-Co-B Coating[J]. 中国腐蚀与防护学报, 2020, 40(5): 439-447.
[8] JIA Yizheng, WANG Baojie, ZHAO Mingjun, XU Daokui. Effect of Solid Solution Treatment on Corrosion and Hydrogen Evolution Behavior of an As-extruded Mg-Zn-Y-Nd Alloy in an Artificial Body Fluid[J]. 中国腐蚀与防护学报, 2020, 40(4): 351-357.
[9] CAO Jingyi, FANG Zhigang, CHEN Jinhui, CHEN Zhixiong, YIN Wenchang, YANG Yange, ZHANG Wei. Preparation and Properties of Micro-arc Oxide Film with Single Dense Layer on Surface of 5083 Aluminum Alloy[J]. 中国腐蚀与防护学报, 2020, 40(3): 251-258.
[10] WANG Yingjun, LIU Honglei, WANG Guojun, DONG Kaihui, SONG Yingwei, NI Dingrui. Investigation of Anodic Film on a Novel RE-containing Al-Alloy Al-Zn-Mg-Cu-Sc[J]. 中国腐蚀与防护学报, 2020, 40(2): 131-138.
[11] ZHANG Yao, GUO Chen, LIU Yanhui, HAO Meijuan, CHENG Shiming, CHENG Weili. Electrochemical Corrosion Behavior of Extruded Dilute Mg-2Sn-1Al-1Zn Alloy in Simulated Body Fluid[J]. 中国腐蚀与防护学报, 2020, 40(2): 146-150.
[12] WANG Le,YI Danqing,LIU Huiqun,JIANG Long,FENG Chun. Effect of Ru on Corrosion Behavior of Ti-6Al-4V Alloy and Its Mechanism[J]. 中国腐蚀与防护学报, 2020, 40(1): 25-30.
[13] SHI Chao,SHAO Yawei,XIONG Yi,LIU Guangming,YU Yuelong,YANG Zhiguang,XU Chuanqin. Influence of Silane Coupling Agent Modified Zinc Phosphate on Anticorrosion Property of Epoxy Coating[J]. 中国腐蚀与防护学报, 2020, 40(1): 38-44.
[14] WU Dongcai,HAN Peide. Effects of Moderate Temperature Aging Treatment on Corrosion Resistance of SAF2304 DuplexStainless Steel[J]. 中国腐蚀与防护学报, 2020, 40(1): 51-56.
[15] YANG Yinchu,FU Xiuqing,LIU Lin,MA Wenke,SHEN Moqi. Electrochemical Corrosion of Ni-P-BN(h)-Al2O3 Composite Coating Deposited by Spray Electrodeposition[J]. 中国腐蚀与防护学报, 2020, 40(1): 57-62.
No Suggested Reading articles found!