Effect of Solid Solution Treatment on Corrosion and Hydrogen Evolution Behavior of an As-extruded Mg-Zn-Y-Nd Alloy in an Artificial Body Fluid

doi:10.11902/1005.4537.2019.113

Journal of Chinese Society for Corrosion and protection

2020, Vol. 40

Issue (4): 351-357 DOI: 10.11902/1005.4537.2019.113

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Effect of Solid Solution Treatment on Corrosion and Hydrogen Evolution Behavior of an As-extruded Mg-Zn-Y-Nd Alloy in an Artificial Body Fluid

JIA Yizheng¹, WANG Baojie², ZHAO Mingjun², XU Daokui³(

)

1. Innovation and Practice Base for Postdoctors, Sichuan College of Architectural Technology, Deyang 618000, China
2. School of Environmental and Chemical Engineering, Shenyang Ligong University, Shenyang 110159, China
3. Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

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Abstract

The corrosion behavior of an as-extruded Mg-6Zn-1.2Y-0.8Nd alloy before and after solid solution (T4) treatment was assessed comparatively in Hank's solution by means of hydrogen evolution examination, electrochemical tests and corrosion morphologies characterization. The results showed that after being solution treated at 475 ℃ for 4 h, the corrosion resistance of the alloy was improved. In addition, when the pre-soaking time was less than 24 h, the corrosion resistance of the alloy before and after T4 treatment all increased with the pre-soaking time. However, when the pre-soaking time was 48 h, the corrosion resistance of the differently treated alloys was reduced. The hydrogen evolution data showed that the hydrogen evolution rate of the T4 alloy was 0.75 times as high as that of the as-extruded ones. As the corrosion morphology of different treated alloys was compared, it can be seen that the corrosion attack on the surface of as-extruded alloy was much severe with deeper corrosion pits.

Key words: magnesium alloy pre-soaking hydrogen evolution pitting solid solution treatment

Received: 26 July 2019

ZTFLH:

TG172.5

Fund: National Natural Science Foundation of China(51701129);National Natural Science Foundation of China(51871211);Key Technology R&D Program of Deyang City Government of China(2014ZZ051);Postdoctoral Start Fund of Shenyang Ligong University(10500010006)

Corresponding Authors: XU Daokui E-mail: dkxu@imr.ac.cn

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Cite this article:

JIA Yizheng, WANG Baojie, ZHAO Mingjun, XU Daokui. Effect of Solid Solution Treatment on Corrosion and Hydrogen Evolution Behavior of an As-extruded Mg-Zn-Y-Nd Alloy in an Artificial Body Fluid. Journal of Chinese Society for Corrosion and protection, 2020, 40(4): 351-357.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2019.113 OR https://www.jcscp.org/EN/Y2020/V40/I4/351

Fig.1 SEM (a, b) and OM (c, d) images of as-extruded Mg-6Zn-1.2Y-0.8Nd alloy without (a, c) and with (b, d) solid solution treatment

Fig.2 Hydrogen evolution curves of as-extruded and final T4 treated Mg-6Zn-1.2Y-0.8Nd alloy in Hank's solution

Fig.3 Polarization curves of as-extruded (a) and final T4 treated (b) Mg-6Zn-1.2Y-0.8Nd alloy pre-immersed in Hank's solution for different time

Table 1 Fitted parameters of polarization curves of as-extruded Mg-6Zn-1.2Y-0.8Nd alloy before and after T4 treatment

Fig.4 Surface corrosion morphologies and 3D images of the as-extruded Mg-6Zn-1.2Y-0.8Nd alloy before and after pre-immersion in Hank's solution for 4 h (a), 24 h (b) and 48 h (c)

Fig.5 Surface corrosion morphologies and 3D images of the T4-treated Mg-6Zn-1.2Y-0.8Nd alloy before and after pre-immersion in Hank's solution for 4 h (a), 24 h (b) and 48 h (c)

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