|
|
Corrosion Behavior of Microarc Oxidized Alumina Films in High Temperature NaCl Solution |
XU Ke1, XIAO Shubin2, LIU Yanhui1, RUAN Guoling1 |
1. The Institute of Seawater Desalination and Multipurpose Utilization, SOA, Tianjin 300192, China;
2. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China |
|
|
Abstract Abstract:The corrosion behaviors of microarc oxidized 5052 alumina immersed in 70 ℃/7% NaCl solutions with different time were studied through the open circuit potential (OCP) and electrochemical impedance spectroscopy (EIS) measurements. The results reveal that high temperature solution could permeate through microarc oxidation films and induce the corrosion of aluminum alloy substrate in the initial stage. After that, the corrosion products depositing in film defects could block the permeation of solution, which make microarc oxidation films exhibiting a self-sealing ability. And the film resistance keeps mostly unchangeable after initial rapidly decrease. Sealing treatment of microarc oxidation film could improve the self-sealing ability effectively.
|
|
|
[1] Wei T B, Yan F Y, Tian J. Characterization and wear- and corrosion-resistance of microarc oxidation ceramic coatings on aluminum alloy [J]. J. Alloys Compd., 2005, 389(1-2): 169-176 [2] Monfort F, Berkani A, Matykina E, et al. Development of anodic coatings on aluminium under sparking conditions in silicate electrolyte [J]. Corros. Sci., 2007, 49(2): 672-693 [3] Li J M, Cai H, Jiang B L. Growth mechanism of black ceramic layers formed by microarc oxidation [J]. Surf. Coat. Technol., 2007, 201(21): 8702-8708 [4] Shao Z C, Kang F D, Hao Q W, et al. Effect of the technological parameters on the properties of microarc oxidation coating of LF4 Al-alloy [J]. Chin. J. Mater. Res., 2006, 20(5): 528-532(邵忠财, 康凤娣, 郝清伟等. LF4铝合金微弧氧化膜的性能 [J]. 材料研究学报,2006,20(5):528-532) [5] Xue W B, Wang C, Tian H, et al. Corrosion behaviors and galvanic studies of microarc oxidation films on Al-Zn-Mg-Cu alloy [J]. Surf. Coat. Technol., 2007, 201(21): 8695-8701 [6] Wen L, Wang Y M, Zhou Y, et al. Corrosion evaluation of microarc oxidation coatings formed on 2024 aluminium alloy [J]. Corros. Sci., 2010, 52(8): 2687-2696 [7] Wen L, Wang Y M, Liu Y, et al. EIS study of a self-repairing microarc oxidation coating [J]. Corros. Sci., 2011, 53(2): 618–623 [8] Shi P, Ng W F, Wong M H, et al. Improvement of corrosion resistance of pure magnesium in Hanks' solution by microarc oxidation with sol-gel TiO2 sealing [J]. J. Alloys Compd., 2009, 469(1-2): 286-292 [9] Wang Y Q, Wang Y, Wang F H, et al. Microstructure, corrosion and wear resistances of microarc oxidation coating on Al alloy 7075[J]. Acta Metall. Sin., 2011, 47(4): 455-461(王艳秋, 王岳, 王福会等. 7075铝合金微弧氧化涂层的组织结构与耐蚀耐磨性能 [J]. 金属学报,2011,47(4):455-461) [10] Yun F L, Xu K. Effect of heavy metal ions on the corrosion of aluminum alloy 5052[J]. Chem. Ind. Eng., 2010, 27(2): 173-176(云凤玲, 徐克. 重金属离子对5052铝合金耐蚀性能的影响 [J]. 化学工业与工程,2010,27(2):173-176) [11] Zhang W, Wang J, Zhao Z Y, et al. EIS study on the deterioration process of organic coatings under immersion and cyclic wet-dry conditions [J]. J. Chin. Soc. Corros. Prot., 2011, 31(5): 329-335(张伟, 王佳, 赵增元等. 电化学阻抗谱对比研究连续浸泡和干湿循环条件下有机涂层的劣化过程 [J]. 中国腐蚀与防护学报,2011,31(5): 329-335) [12] Huang Y L, Hong S H, Huang H C, et al. Evaluation of the corrosion resistance of anodized aluminum 6061 using electrochemical impedance spectroscopy (EIS) [J]. Corros. Sci., 2008, 50(12): 3569-3575 [13] Zhao X H, Zuo Y, Zhao J M, et al. A study on the self- sealing process of anodic films on aluminum by EIS [J]. Surf. Coat. Technol., 2006, 200(24): 6846-6853 [14] Zuo Y, Zhao P H, Zhao J M. The influences of sealing methods on corrosion behavior of anodized aluminum alloys in NaCl solutions [J]. Surf. Coat. Technol., 2003, 166(2-3): 237-242 [15] Deflorian F, Rossia S, Fedrizzi L, et al. EIS study of organic coating on zinc surface pretreated with environmentally friendly products [J]. Prog. Org. Coat., 2005, 52(4): 271-279
|
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|