Research Progress on Corrosion Behavior of Metallic Materials in Acetic Acid Environment

doi:10.11902/1005.4537.2022.186

Journal of Chinese Society for Corrosion and protection

2023, Vol. 43

Issue (1): 13-21 DOI: 10.11902/1005.4537.2022.186

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Research Progress on Corrosion Behavior of Metallic Materials in Acetic Acid Environment

LIU Mingming¹^,², YANG Xiaobing³, CHEN Xiaoqi³, WANG Zhengbin²(

), ZHENG Yugui², HE Chunlin⁴

^1.Normal College, Shenyang University, Shenyang 110044, China
^2.CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^3.Nantong Cellulose Fibers Co. Ltd., Nantong 226008, China
^4.Liaoning Provincial Key Laboratory of Advanced Materials, Shenyang University, Shenyang 110044, China

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Abstract

Acetic acid is an important raw material and plays an important role in the modern chemical industry. However, acetic acid is highly corrosive, which can easily cause corrosion of metallic components, threatening the service safety of equipment. In order to better understanding and preventing the corrosion induced by acetic acid, this paper summarizes the mechanisms, influencing factors (temperature, acetic acid concentration and impurities) and protection measures for corrosion of metals in acetic acid, on the basis of practical corrosion failure cases. It is expected to provide some guidance for selecting proper materials and taking effective measures to protect components serving in acetic acid environments from corrosion.

Key words: acetic acid metals corrosion mechanism influencing factor prevention measure

Received: 08 June 2022 32134.14.1005.4537.2022.186

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	Mingming LIU
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	Yugui ZHENG
	Chunlin HE

Cite this article:

LIU Mingming, YANG Xiaobing, CHEN Xiaoqi, WANG Zhengbin, ZHENG Yugui, HE Chunlin. Research Progress on Corrosion Behavior of Metallic Materials in Acetic Acid Environment. Journal of Chinese Society for Corrosion and protection, 2023, 43(1): 13-21.

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https://www.jcscp.org/EN/10.11902/1005.4537.2022.186 OR https://www.jcscp.org/EN/Y2023/V43/I1/13

Fig.1 Relationship between the surface coverage of acetic acid adsorbed on metal materials and the undissociated acetic acid concentration. Cathodic currents (green diamonds) and anodic currents (red squares)^[6]

Fig.2 Schematic diagram of the crevice corrosion mechanism of N80 carbon steel in CO₂-containing solution containing HAc^[21]: (a) at the beginning, (b) after 72 h

Table 1 Corrosion rates of stainless steel in acetic acid solutions (mm·a^-¹ )

Fig.3 Corrosion rates of austenitic and duplex stainless steels in 50% acetic acid solutions with different proportions of formic acid^[25]

Table 2 Recommendations for the use of metal materials in different acetic acid solutions

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