|
|
Inhibition Effect of Brainea Insignis Extract Against Carbon Steel Corrosion in HCl Solution |
CHEN Wen1( ), HUANG Dexing1, WEI Feng2 |
1.Department of Chemistry and Life Science, Chuxiong Normal University, Chuxiong 675000, China 2.Chinese National Engineering Research Center for Petroleum and Natural Gas Tubular Goods, Baoji 721008, China |
|
|
Abstract The inhibition effect of brainea insignis extract (BIE) on the corrosion of Q235 steel in HCl solution was investigated by means of mass loss measurement, polarization curve measurement and electrochemical impedance spectroscopy. The results showed that BIE could effectively inhibit the carbon steel corrosion in HCl solution, as the BIE concentration was up to 560 mg·L-1, the corrosion rate of Q235 steel decreased to 1.125 g·m-2·h-1, namely the corrosion inhibition efficiency reached 94.3%. Electrochemical analysis shows that the BIE extract suppressed mainly the cathodic corrosion reaction. With the increasing concentration of BIE extract, the charge transfer process on the metal surface was hindered increasingly, resulting in enhanced corrosion inhibition performance. The highest corrosion inhibition efficiencies calculated from the fitting of polarization curves and electrochemical impedance spectroscopy were 95.8% and 95.3%, respectively, which were in agreement with the result of mass loss measurement. The adsorption action of BIE molecules on the steel surface followed Langmuir, Temkin adsorption isotherms and the EI-Awady thermodynamic-kinetic model, and belonged to heterogeneous adsorption, whilst there should exist lateral interaction forces between the adsorbed organic molecules. Spectral analysis and surface morphology observations confirmed the existance of the adsorption action and corrosion inhibition of the extract molecules, respectively.
|
Received: 04 April 2020
|
|
Fund: National Natural Science Foundation of China(51361001) |
Corresponding Authors:
CHEN Wen
E-mail: chenw@cxtc.edu.cn
|
About author: CHEN Wen, E-mail: chenw@cxtc.edu.cn
|
1 |
Zheng J, Wang Y N, Zhang B L, et al. Research progress on natural products as corrosion inhibitor in acid, neutral and alkaline mediums [J]. Corros. Sci. Prot. Technol., 2011, 23: 103
|
|
郑杰, 王亚娜, 章柏林等. 酸性、中性、碱性介质中植物型缓蚀剂的研究进展 [J]. 腐蚀科学与防护技术, 2011, 23: 103
|
2 |
Wang X, Ren S F, Zhang D X, et al. Inhibition effect of soybean meal extract on corrosion of Q235 steel in hydrochloric acid medium [J]. J. Chin. Soc. Corros. Prot., 2019, 39: 267
|
|
王霞, 任帅飞, 张代雄等. 豆粕提取物在盐酸中对Q235钢的缓蚀性能 [J]. 中国腐蚀与防护学报, 2019, 39: 267
|
3 |
Alvarez P E, Fiori-Bimbi M V, Neske A, et al. Rollinia occidentalis extract as green corrosion inhibitor for carbon steel in HCl solution [J]. J. Ind. Eng. Chem., 2018, 58: 92
|
4 |
Qiang Y J, Zhang S T, Tan B C, et al. Evaluation of Ginkgo leaf extract as an eco-friendly corrosion inhibitor of X70 steel in HCl solution [J]. Corros. Sci., 2018, 133: 6
|
5 |
Verma C, Ebenso E E, Bahadur I, et al. An overview on plant extracts as environmental sustainable and green corrosion inhibitors for metals and alloys in aggressive corrosive media [J]. J. Mol. Liq., 2018, 266: 577
|
6 |
Casaletto M P, Figà V, Privitera A, et al. Inhibition of Cor-Ten steel corrosion by “green” extracts of Brassica campestris [J]. Corros. Sci., 2018, 136: 91
|
7 |
Fang Y S, Yang Y B, Yang M H, et al. Chemical constituents from the fern Brainea insignis (Blechnaceae) [J]. Acta Bot. Yunnanica, 2008, 30: 725
|
|
方云山, 杨亚滨, 杨明惠等. 苏铁蕨的化学成分 [J]. 云南植物研究, 2008, 30: 725
|
8 |
Wu P, Xie H H, Tao W Q, et al. Phytoecdysteroids from the rhizomes of Brainea insignis [J]. Phytochemistry, 2010, 71: 975
|
9 |
Fan Y M, Tao W Q, Gao S Z, et al. Purification and analysis of the Brainia insignis (Hook.) J. Sm. polysaccharides [J]. J. Guangzhou Univ. (Nat. Sci. Ed.), 2008, 7(6): 46
|
|
樊亚鸣, 陶文琴, 高绍中等. 苏铁蕨多糖的提取及其组分分析 [J]. 广州大学学报 (自然科学版), 2008, 7(6): 46
|
10 |
Liu Y C. Chemical composition and antioxidant activity of fern Brainea insignis [J]. Yunnan Agric., 2016, (12): 46
|
|
刘艳春. 苏铁蕨的化学成分与抗氧化活性研究 [J]. 云南农业, 2016, (12): 46
|
11 |
Morales-Gil P, Walczak M S, Cottis R A, et al. Corrosion inhibitor binding in an acidic medium: Interaction of 2-mercaptobenizmidazole with carbon-steel in hydrochloric acid [J]. Corros. Sci., 2014, 85: 109
|
12 |
Frateur I, Lartundo-Rojas L, Méthivier C, et al. Influence of bovine serum albumin in sulphuric acid aqueous solution on the corrosion and the passivation of an iron-chromium alloy [J]. Electrochim. Acta, 2006, 51: 1550
|
13 |
Chauhan L R, Gunasekaran G. Corrosion inhibition of mild steel by plant extract in dilute HCl medium [J]. Corros. Sci., 2007, 49: 1143
|
14 |
Asami K, Hashimoto K, Shimodaira S. X-ray photoelectron spectrum of Fe2+ state in iron oxides [J]. Corros. Sci., 1976, 16: 35
|
15 |
Shimura T, Aramaki K. Additional modification to two-dimensional polymer films of a hydroxymethylbenzene self-assembled monolayer with alkyltriethoxysilanes for enhancing the protective abilities against iron corrosion [J]. Corros. Sci., 2008, 50: 596
|
16 |
Liu B Y, Xi H X, Li Z, et al. Adsorption and corrosion-inhibiting effect of 2-(2-{[2-(4-Pyridylcarbonyl) hydrazono]methyl}phenoxy) acetic acid on mild steel surface in seawater [J]. Appl. Surf. Sci., 2012, 258: 6679
|
17 |
Liu X H, Han J, Sun C Y, et al. Mechanism of tungstate compound inhibitor in sea water with XPS and EDS [J]. Surf. Technol., 2011, 40(3): 52
|
|
柳鑫华, 韩婕, 孙彩云等. 用XPS及EDS能谱研究钨酸盐复合缓蚀剂在天然海水中的缓蚀机理 [J]. 表面技术, 2011, 40(3): 52
|
18 |
Cao C N. Principles of Electrochemistry of Corrosion [M]. 3rd Ed. Beijing: Chemical Industry Press, 2008
|
|
曹楚南. 腐蚀电化学原理 [M]. 第3版. 北京: 化学工业出版社, 2008
|
19 |
Abd El-Lateef H M. Experimental and computational investigation on the corrosion inhibition characteristics of mild steel by some novel synthesized imines in hydrochloric acid solutions [J]. Corros. Sci., 2015, 92: 104
|
20 |
Popova A, Raicheva S, Sokolova E, et al. Frequency dispersion of the interfacial impedance at mild steel corrosion in acid media in the presence of benzimidazole derivatives [J]. Langmuir, 1996, 12: 2083
|
21 |
Ateya B G, El-Anadouli B E, El-Nizamy F M. The adsorption of thiourea on mild steel [J]. Corros. Sci., 1984, 24: 509
|
22 |
Rahal H T, Abdel-Gaber A M, Younes G O. Inhibition of steel corrosion in nitric acid by sulfur containing compounds [J]. Chem. Eng. Commun., 2016, 203: 435
|
23 |
Şahın M, Bılgıç S. The effect of crotyl alcohol on the corrosion of austenitic chromium-nickel steel [J]. Appl. Surf. Sci., 1999, 147: 27
|
24 |
Umoren S A, Ebenso E E. The synergistic effect of polyacrylamide and iodide ions on the corrosion inhibition of mild steel in H2SO4 [J]. Mater. Chem. Phys., 2007, 106: 387
|
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|