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J Chin Soc Corr Pro  2008, Vol. 28 Issue (6期): 374-380    DOI:
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PRESENT STATUS AND DEVELOPMENT ON ELECTROCHEMISTRY AT HIGH TEMPERATURES AND HIGH PRESSURES AQUEOUS SYSTEMS
HUANG Junbo;WU Xinqiang;HAN En-Hou;KE Wei
State Key Larboratory for Corrosion and Protection; Institute of Metal Research; Chinese Academy of Sciences; Shenyang 110016
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Abstract  

Developments and unsolved problems of high-temperature and high-pressure cells and electrodes are summarized. The effects of aqueous electrolyte solutions on high-temperature aqueous corrosion are reviewed. The newly achievements of electrochemistry technologies utilized in high-temperature and high-pressure aqueous solutions, including potential-pH graphs, polarization curves, electrochemical impedance spectroscopy and electrochemical noise, are reported. An outlook is also given for future research needs.

Key words:  high temperature      high pressure      electrochemistry      aqueous electrolyte      potential-pH      diagram      polarization     
Received:  05 February 2007     
ZTFLH: 

TG172.82

 
Fund: 

国家重点基础研究发展规划项目(2006CB605001)、国家自然科学基金面上项目(50871113)及中国科学院金属研究所创新基金项目资助

Corresponding Authors:  WU Xinqiang   

Cite this article: 

HUANG Junbo WU Xinqiang HAN En-Hou KE Wei. PRESENT STATUS AND DEVELOPMENT ON ELECTROCHEMISTRY AT HIGH TEMPERATURES AND HIGH PRESSURES AQUEOUS SYSTEMS. J Chin Soc Corr Pro, 2008, 28(6期): 374-380.

URL: 

https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2008/V28/I6期/374

[1]Frank E F.Fluids at high pressures and temperatures[J].Pure Appl.Chem.,1987,59(1):25-34
[2]Zhang L,Wang J Q,Guan H,et al.Progress in study on super-critical water oxidation technology and relevant materials corrosion[J].Corros.Sci.Prot.Technol.,2001,13(5):270-274(张丽,王俭秋,关辉等.超临界水氧化技术及其环境中材料的腐蚀研究现状[J].腐蚀科学与防护技术,2001,13(5):270-274)
[3]Zhang Z E,Han E H,Zhang L,et al.The application of super-critical water oxidation(SCWO)in environment protection[J].Environ.Technol.,2002,4:21-26(张召恩,韩恩厚,张丽等.超临界水氧化(SCWO)在环境保护中的应用[J].环境技术,2002,4:21-26)
[4]Zhang Z E,Zhang L,Guan H,et al.Advances in supercritical water oxidation technology and its application[J].Corros.Sci.Prot.Technol.,2003,15(4):212-215(张召恩,张丽,关辉等.超临界水氧化技术研究方法及应用[J].腐蚀科学与防护技术,2003,15(4):212-215)
[5]Bard A J,Flarsheim W M,Johnston K P.High-pressure electro-chemical oxidation of benzene at a lead dioxide electrode in aque-ous bisulfate solution at25℃to250℃[J].J.Electrochem.Soc.,1988,135:1939-1944
[6]Flarsheim W M,Tsou Y M,Trachtenberg I,et al.Electrochem-istry in near-critical and supercritical fluids.3.Studies of Br-,I-and hydroquinone in aqueous solutions[J].J.Phys.Chem.,1996,90:3857-3862
[7]McDonald A C,Fan F R F,Bard A J.Electrochemistry in near-critical and supercritical fluids.2.Water-experimental techniques and the copper(II)system[J].J.Phys.Chem.,1986,90:196-202
[8]Lvov S N,Gao H,MacDonald D D.Advanced flow-through ex-ternal pressure-balanced reference electrode for potentiometric and pH studies in high temperature aqueous solution[J].J.Elec-troanal.Chem.,1998,443:186-194
[9]Lvov S N,Zhou X Y,Ulmer G C,et al.Progress on yttria-stabi-lized zirconia sensors for hydrothermal pH measurements[J].Chem.Geol.,2003,198(3-4):141-162
[10]Kritzer P,Boukis N,Dinjus E.Corrosion of alloy625in aqueous solutions containing chloride and oxygen[J].Corrosion,1998,54(10):824-834
[11]Kiwamu S,Munehiro U,Toshihiko U,et al.Apparatus for direct pH measurement of supercritical aqueous solutions[J].J.Super-crit.Fluids,2004,28:287-296
[12]Kriksunov L B,MacDonald D D.Corrosion in supercritical water oxidation systems:a phenomenological analysis[J].J.Electrochem.Soc.,1995,142:4069-4073
[13]Saito N,Tsuchiya Y,Akai Y,et al.Corrosion performance of metals for supercritical water,oxidation-utilized organic waste-processing reactors[J].Corrosion,2006,62(5):383-394
[14]Seneviratne D S,Papangelakis V G,Zhou X Y,et al.Potentio-metric pH measurements in acidic sulfate solutions at250℃rele-vant to pressure leaching[J].Hydrometallurgy,2003,68:131-139
[15]Zhang L,Han E H,Zhang Z E,et al.The corrosion of stainless steel and nickel base alloys in subcritical water condition[J].Acta Metall.Sin.,2003,39(6):649-654(张丽,韩恩厚,张召恩等.不锈钢及镍基合金在亚临界水环境中的腐蚀[J].金属学报,2003,2003,39(6):649-654)
[16]Zhang L,Han E H,Ke W.Corrosion behavior of stainless steel and nickel-base alloy in supercritical water oxidation system[R].Wuhan:Chinese Society for Corrosion and Protection,2003(张丽,韩恩厚,柯伟.不锈钢及镍基合金在超临界水氧化反应环境中的腐蚀研究[R].武汉:中国腐蚀与防护学会,2003)
[17]Zhou X Y,Lvov S N,Wei X J,et al.Quantitative evaluation of general corrosion of type304stainless steel in subcritical and su-percritical noise analysis[J].Corros.Sci.,2002,44(4):841-860
[18]Li H M,Yang W,Cai X,et al.Fractography of the stress corro-sion cracking specimens of type304stainless steel in high tem-perature water containing boric acid and lithium ion[J].J.Chin.Soc.Corros.Prot.,2004,24(1):16-19(李红梅,杨武,蔡珣等.304不锈钢在含硼和锂的高温水中的应力腐蚀破裂和断口分析[J].中国腐蚀与防护学报,2004,24(1):16-19)
[19]Zhang L,Han E H,Ke W.Corrosion of superalloy GH132tube in the environment of disposing propellant wastewater by super-critical water oxidation[J].J.Chin.Soc.Corros.Prot.,2004,24(2):121-124(张丽,韩恩厚,柯伟.GH132管在超临界水氧化反应法处理航天推进废水环境中的腐蚀[J].中国腐蚀与防护学报,2004,24(2):121-124)
[20]Han E H,Mitton D B,Zhang S H,et al.Corrosion of metals in supercritical aqueous solution[R].Beijing:Chinese Society for Corrosion and Protection,1999(韩恩厚,Mitton D B,Zhang S H等.几种金属材料在超临界水中的腐蚀[R].北京:中国腐蚀与防护学会,1999)
[21]Han E H.Supercritcical water oxidation technology and its mate-rials degradation[J].Rare Met.Mater.Eng.,2000,29(z1):45-48(韩恩厚.超临界水氧化技术及其环境中的材料损伤[J].稀有金属材料与工程,2000,29(z1):45-48)
[22]Gao X,Wu X Q,Zhang Z E,et al.Some factors of oxide form-ing in supercritical aqueous solution[A].In:Han E H,Li M S,eds.,Proceedings of the5th Cross-strait Conference on Materials Corrosion and Protection[C].Shenyang:Institute of Metal Re-search,Chinese Academy of Science,2006,127-130(高欣,吴欣强,张召恩等.影响超临界水腐蚀产物膜的若干因素研究[A].韩恩厚,李美栓主编.第五届海峡两岸材料腐蚀与防护研讨会论文集[C].沈阳:中国科学院金属研究所,2006,127-130)
[23]Gao X,Wu X Q,Zhang Z E,et al.Characterization of oxide films grown on316L stainless steel exposed to H2O2-containing supercritical water[J].J.Supercrit.Fluids(in press)
[24]Montemor M F,Ferreira M G S,Walls M,et al.Influence of pH on properties of oxide films formed on type316L stainless steel,alloy600and alloy690in high-temperature aqueous environ-ments[J].Corrosion,2003,59(1):11-21
[25]Fill C,Tiltscher H.Investigations on material and corrosion prob-lems for the oxidation of contaminations in supercritical water[J].Mater.Corros.,1997,48(3):146-150
[26]Delville M H,Botella P,Jaszay T,et al.Electrochemical study of corrosion in aqueous high pressure,high temperature media and measurements of materials corrosion rates:applications to the hy-drothermal treatments of organic wastes by SCWO[J].J.Supercrit.Fluids,2003,26:169-179
[27]Kritzer P,Boukis N,Dinjus E.Review of the corrosion of nick-el-based alloys and stainless steels in strongly oxidizing pressur-ized high-temperature solutions at subcritical and supercritical temperatures[J].Corrosion,2000,56(11),1093-1104
[28]Hwang S S,Kim H P,Kim J S.Degradation of alloy600steam generator tubes in operating pressurized water reactor nuclear power plants[J].Corrosion,2003,59(9):821-827
[29]Fujisawa R,Nishimura K,Nishida T,et al.Corrosion behavior of nickel-based alloys and type316stainless steel in slightly oxi-dizing or reducing supercritical water[J].Corrosion,2006,62(3):270-274
[30]Hua F,Mon K,Passupathi P,et al.A review of corrosion of ti-tanium grade7and other titanium alloys in nuclear waste reposi-tory environments[J].Corrosion,2005,61(10):987-1003
[31]Chen Y Z,MacDonald M U,MacDonald D D.The electrochem-istry of zirconium in aqueous solutions at elevated temperatures and pressures[J].J.Nucl.Mater.,2006,348(1-2):133-147
[32]Liu C Y,Snyder S,Bard A J.Electrochemistry in near-critical and supercritical fluids.9.Improved apparatus for water systems(23℃~385℃)-the oxidation of hydroquinone andiodide[J].J.Phys.Chem.,1997,101:1180-1185
[33]Zhou X Y,Lvov S N,Ulyanov S M.Yttria-stabilized Zirconia Membrane Electrode[P].US Patent:6517694,2003
[34]MacDonald D D,Hettiarachchi S,Lenhart S.The thermody-namic viability of yttria-stabilized pH sensor for high temperature aqueous solutions[J].J.Solution Chem.,1988,17:719-732
[35]Lvov S N,Zhou X Y,Ulyanov S M,et al.Reference systems for assessing viability and accuracy of pH sensors in high tempera-ture subcritical and supercritical aqueous solutions[J].Chem.Ge-ol.,2000,167:105-115
[36]Zhang R H,Zhang X T,Hu S M.Nanocrystalline ZrO2thin films as electrode materials using in high temperature-pressure chemi-cal sensors[J].Mater.Lett.,2006,60(25-26):3170-3174
[37]MacDonald D D.Reference electrodes for high temperature aqueous systems-a review and assessment[J].Corrosion,1978,34(3):75-84
[38]Tian B,Hu M,Li C F.et al.State of the art and future trends of Ag/AgCl reference electrodes for high temperature and high pressure aqueous systems[J].J.Chin.Soc.Corros.Prot.,2003,23(6):370-374(田斌,胡明,李春福等.高温高压水溶液用Ag/AgCl参比电极研究现状及反展趋势[J].中国腐蚀与防护学报,2003,23(6):370-374
[39]Gregory G W,Debora G,Nathan S L,et al.High-temperature electrochemistry:a review[J].Electroanalysis,2004,16(6):421-433
[40]Tomonori S,Shunsuke U,Takashi T,et al.Effects of hydrogen peroxide and oxygen on polarization curves of stainless steel in high temperature pure water[R].Korea:International Conference on Water Chemistry of Nuclear Reactor Systems,2006
[41]Turnbull A,Dombrowski M P.A review of electrochemistry of relevance to environment-assisted cracking in light water reactors[J].Corros.Sci.,1992,33:1925-1966
[42]Kim Y J.Evaluation of alternate reductants for application in light water reactors[J].Corrosion,2006,62(9):795-800
[43]Frost B R T.Nuclear Materials(Parts2)[M].Beijing:Science Press,1999
[44]Wen J H,Lai X P.Electrochemical behavior of T225NG titani-um alloy in high temperature and high pressure aqueous solution[J].Nucl.Power Eng.,2006,27(6):106-108(温菊花,赖旭平.T225NG钛合金在高温高压水质中的电化学行为[J].核动力工程,2006,27(6):106-108)
[45]Kritzer P.Corrosion in high-temperature and supercritical water and aqueous solutions:a review[J].J.Supercrit.Fluids,2004,29:1-29
[46]Gloyna E F,Li L,McBrayer R N.Engineering aspects of super-critical water oxidation[J].Water Sci.Technol.,1994,30(9):1-10
[47]Cao C N.Corrosion Electrochemical[M].Beijing:Chemical In-dustry Press,2004(曹楚南.腐蚀电化学原理[M].北京:化学工业出版社,2004)
[48]Cubiccotti D.Potential-pH diagrams for alloy-water systems un-der LWR condition[J].J.Nucl.Mater.,1993,201:176-183
[49]MacDonald D D,Kriksunov L B.Probing the chemical and electrochemical properties of SCWO systems[J].Electrochim.Ac-ta,2001,47:775-790
[50]Kriksunov L B,MacDonald D D.Potential-pH diagrams for iron in supercritical water[J].Corrosion,1997,53(8):605-611
[51]Kim Y J,Andresen P L.Data quality,issues and guidelines for electrochemical corrosion potential measurement in high-tempera-ture water[J].Corrosion,2003,59(7):584-596
[52]Kim Y J,Andresen P L,Moran E,et al.Modification of surface property for controlling the type304stainless steel electrochemical corrosion potential in288℃water[J].Corrosion,2005,61(7):648-654
[53]Botella P,Frayret C,Jaszay T,et al.Experimental study,via current-potential curves,of the anodic behavior of alloy C-276and T60titanium in chlorinated and oxygenated aqueous media under sub-to supercritical conditions[J].J.Supercrit.Fluids,2003,25:269-278
[54]Rihan O R,Srdjan N.Erosion-corrosion of mild steel in hot caus-tic.PartⅠ:NaOH solution[J].Corros.Sci.,2006,48(9):2633-2659
[55]Rihan O R,Srdjan N.Erosion-corrosion of mild steel in hot caustic.PartⅡ:The effect of acid cleaning[J].Corros.Sci.,2006,48(9):2660-2675
[56]Engelhardt G R,Biswas R,Ahmed Z,et al.The use of channel flow cells for electrochemical kinetic studies in high temperature aqueous solutions[J].Electrochim.Acta,2007,52:4124-4131
[57]Hong T,Jepson W P.Corrosion inhibitor studies in large flow loop at high temperature and high pressure[J].Corros.Sci.,2001,43(10):1839-1849
[58]Bojinov M,Kinnumen P,Sundholm G.Electrochemical behavior of nickel-chromium alloys in a high-temperature aqueous elec-trolyte[J].Corrosion,2003,59(2):91-103
[59]Marichev V A.Contact electroresistance method for in situ inves-tigation of metal surface in electrolytes[J].Surf.Sci.Rep.,2001,44:51-158
[60]Daigo Y,Watanabe Y,Sugahara K,et al.Compatibility of nickel-based alloys with supercritical water applications:aging effects on corrosion resistance and mechanical properties[J].Corrosion,2006,62(2):174-181
[61]Schroer C,Konys J,Novotny J,et al.Aspects of the corrosion ki-netics for binary nickel-chromium alloys under conditions found in supercritical water oxidation plants processing chlorinated sub-stance[J].Corrosion,2006,62(5):444-459H3:871-875)

[5]Zhao Y T,Sun M X.Review on simulated tests of corrosion in flowing seawater[J].Dev.Appl.Mater.,1999,4(1):31-34(赵永韬,孙明先.动海水腐蚀模拟试验的发展[J].材料开发与应用,1999,4(1):31-34)

[6]Yang F,Zheng Y G,Yao Z M,et al.Study on erosion-corrosion behavior of Cu-Ni alloy BFe30-1-1in flowing artificial seawater[J].J.Chin.Soc.Corros.Prot.,1999,19(4):207-213(杨帆,郑玉贵,姚治铭等.铜镍合金BFe30-1-1在流动人工海水中的腐蚀行为[J].中国腐蚀与防护学报,1999,19(4):207-213)

[7]Song S Z.Electrochemical Corrosion Research Methods[M].Bei-jing:Chemical Industry Press,1987(宋诗哲.腐蚀电化学研究方法.北京:化学工业出版社,1987)

[8]Cao C N.Electrochemical Corrosion(2nd ed.)[M].Beijing:Chemi-cal Industry Press,2004(曹楚南.腐蚀电化学原理(第二版).北京:化学工业出版社,2004)
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