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中国腐蚀与防护学报  2022, Vol. 42 Issue (1): 16-24    DOI: 10.11902/1005.4537.2021.021
  综合评述 本期目录 | 过刊浏览 |
层状双金属氢氧化物防腐蚀涂层材料的研究进展
刘术辉, 刘斌(), 徐大伟, 刘蔚, 陈凡伟, 刘思琪
北京化工大学材料科学与工程学院 材料电化学过程与技术北京市重点实验室 北京 100029
Research Progress on Anti-corrosion Coatings of Layered Double Hydroxides
LIU Shuhui, LIU Bin(), XU Dawei, LIU Yu, CHEN Fanwei, LIU Siqi
Beijing Key Laboratory of Electrochemical Processes and Technology of Materials, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
全文: PDF(1573 KB)   HTML
摘要: 

层状双金属氢氧化物 (LDHs) 作为一种重要的无机纳米容器型材料,具有离子交换性、结构可调控、热稳定性良好等优势,近年来已发展成为防腐蚀涂层领域的研究热点。本文系统总结了近年来该领域的相关研究成果,阐述了LDHs材料的防腐蚀机理和影响LDHs防腐蚀性能的因素,总结了几类主流LDHs防腐蚀涂层的研究进展,分析了其在应用过程中存在的问题并提出具有可行性的解决途径。同时,重点对LDHs防腐蚀涂层在多功能化和复合化方面的相关进展进行了总结和展望。

关键词 层状双金属氢氧化物(LDHs)防腐蚀涂层    
Abstract

Layered double hydroxide (LDHs) is a type of layered compound composed of positively charged metal hydroxides and negatively charged anions. LDHs has the unique advantages of ion exchange, adjustable structure, good thermal stability and low manufacturing cost, therefore, it is an important class of inorganic nanocontainer material, and has a wide range of applications in the fields of flame retardancy, catalysis, water treatment, drug sustained release, etc. In recent years, LDHs has been proven to be able to load corrosion inhibitors and release them into the environment through ion exchange, which has become a major research hotspot in the field of anti-corrosion coatings. In this article, the anti-corrosion mechanism, influencing factors of LDHs materials, the research progress of various types of LDHs anti-corrosion coatings were summarized. At the same time, problems and solutions related with the application process were also analyzed. On the other hand, the relevant progress of LDHs anti-corrosion coatings in terms of multi-functionalization and compounding was summarized and prospected.

Key wordslayered double hydroxide (LDHs)    anti-corrosion    coating
收稿日期: 2021-01-29     
ZTFLH:  TG174  
基金资助:中央高校基本科研业务费专项(buctrc201730)
通讯作者: 刘斌     E-mail: liubindr@163.com
Corresponding author: LIU Bin     E-mail: liubindr@163.com
作者简介: 刘术辉,男,1997年生,硕士生

引用本文:

刘术辉, 刘斌, 徐大伟, 刘蔚, 陈凡伟, 刘思琪. 层状双金属氢氧化物防腐蚀涂层材料的研究进展[J]. 中国腐蚀与防护学报, 2022, 42(1): 16-24.
Shuhui LIU, Bin LIU, Dawei XU, Yu LIU, Fanwei CHEN, Siqi LIU. Research Progress on Anti-corrosion Coatings of Layered Double Hydroxides. Journal of Chinese Society for Corrosion and protection, 2022, 42(1): 16-24.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2021.021      或      https://www.jcscp.org/CN/Y2022/V42/I1/16

图1  LDHs离子交换机理示意图[16]
图2  负载有缓蚀剂的LDH封接阳极氧化层的示意图[28]
ProcessStep 1Step 2Step 3Step 4
FP1Al(NO3)3Mg(NO3)2NaOHNa2CO3
FP2Al(NO3)3Na2CO3NaOHMg(NO3)2
FP3Mg(NO3)2Na2CO3NaOHAl(NO3)3
FP4Na2CO3Mg(NO3)2Al(NO3)3NaOH
表1  4种不同的投料顺序[38]
图3  不同投料顺序所得LDHs涂层的表面形貌及接触角[38]
图4  超疏水涂层保护机理示意图[46]
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