<strong>Nb</strong>对镍基合金堆焊层成型及耐腐蚀性能的影响研究

doi:10.11902/1005.4537.2025.168

中国腐蚀与防护学报

2026, Vol. 46

Issue (3): 903-910 CSTR: 32134.14.1005.4537.2025.168 DOI: 10.11902/1005.4537.2025.168

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Nb对镍基合金堆焊层成型及耐腐蚀性能的影响研究

兰志良, 白凌云, 肖伯涛, 向军淮(

)

江西科技师范大学材料与能源学院材料表面工程江西省重点实验室南昌 330013

Effect of Nb Addition on Formability and Corrosion Resistance of Build-up Welding Overlays of a Nickel-based Alloy

LAN Zhiliang, BAI Lingyun, XIAO Botao, XIANG Junhuai(

)

Jiangxi Provincial Key Laboratory of Materials Surface Engineering, School of Materials and Energy, Jiangxi Science and Technology Normal University, Nanchang 330013, China

引用本文:

兰志良, 白凌云, 肖伯涛, 向军淮. Nb对镍基合金堆焊层成型及耐腐蚀性能的影响研究[J]. 中国腐蚀与防护学报, 2026, 46(3): 903-910.
Zhiliang LAN, Lingyun BAI, Botao XIAO, Junhuai XIANG. Effect of Nb Addition on Formability and Corrosion Resistance of Build-up Welding Overlays of a Nickel-based Alloy[J]. Journal of Chinese Society for Corrosion and protection, 2026, 46(3): 903-910.

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摘要:

为了探究Nb对镍基堆焊成型及耐腐蚀性能的影响，本文模拟了垃圾焚烧炉气氛中的高温腐蚀环境，研究了NiCrMo:xNb (x = 0/3.6%，质量分数)堆焊层在N₂-CO₂(29.8 mg/L)-O₂(23.4 mg/L)-HCl (3.53 mg/L)混合气氛中、800 ℃下的高温腐蚀行为。通过扫描电子显微镜(SEM)、能谱分析仪(EDS)、Cl腐蚀和电化学腐蚀测试，结合JMatPro软件计算模拟，分析了Nb对镍基合金堆焊层微观结构、熔点和流动性和耐蚀性能的影响。结果表明，Nb的加入可以降低合金熔点，细化晶粒，改善合金流动性。但无Nb条件下制备的堆焊合金展现出更好的耐腐蚀性能，NiCrMo-0Nb合金在含O、Cl腐蚀气氛中腐蚀增重为0.0143 mg/cm²，而NiCrMo-3.6Nb合金为0.0520 mg/cm²。此外，降低Nb含量可显著减少生产成本，所以对于高性价比需求的应用场景中，无Nb的镍基合金可以作为一种潜在经济高效的使用材料。

关键词 ：等离子堆焊, Nb元素, 镍基合金, 金相组织, 腐蚀性能

Abstract：

Two build-up welding overlays of NiCrMo-xNb alloys (x = 0/3.6%, mass fraction) were fabricated on 12CrMoVG steel substrate via welding technique with NiCrMo-based alloy wires with and without 3.6%Nb addition as filler material. Then, their microstructure, and corrosion behavior at 800 ℃ in a mixed gas atmosphere N₂-CO₂(29.8 mg/L)-O₂(23.4 mg/L)-HCl (3.53 mg/L) were also assessed, the later issue aims to simulate the corrosive atmosphere of municipal solid waste (MSW) incinerators. The assessment focuses on the effect of Nb addition on local alloy parameters related to formation of the overlay layer such as microstructure, melting point, fluidity, as well as corrosion resistance of the nickel-based build-up welding overlay layers. The results demonstrate that the addition of Nb can lower the alloy's melting point, refine the grain structure, and improve the fluidity of molten alloy. However, the Nb-free alloy overlay layer exhibited superior corrosion resistance. The corrosion mass gain for the build-up welding of NiCrMo-0Nb alloy in this oxygen- and chlorine-containing corrosive atmosphere was 0.0143 mg/cm², while that for the NiCrMo-3.6Nb alloy reached 0.0520 mg/cm². Furthermore, reducing the Nb content significantly decreases the production costs. Therefore, for application scenarios demanding high cost-effectiveness, Nb-free nickel-based alloys present a potential cost-efficient candidate material.

Key words： PTAS niobium element nickel-based alloy metallographic structure corrosion performance

收稿日期: 2025-06-05 32134.14.1005.4537.2025.168

ZTFLH:

TG174

基金资助:国家自然科学基金(51865014);国家自然科学基金(52465040);材料成形与模具技术国家重点实验室开放课题研究基金(P2019-012)

通讯作者: 向军淮，E-mail：xiangjunhuai@163.com，研究方向为金属腐蚀与防护

Corresponding author: XIANG Junhuai, E-mail: xiangjunhuai@163.com

作者简介: 兰志良，男，2000年生，硕士生

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表1 NiCrMo-(0/3.6)Nb堆焊层的主要成分

图1 高温氯腐蚀装置示意图

图2 NiCrMo-(0/3.6)Nb堆焊层的XRD谱

图3 NiCrMo-(0/3.6)Nb堆焊层经王水腐蚀后的表面金相组织

图4 NiCrMo-(0/3.6)Nb堆焊层上中下经王水腐蚀后的截面金相组织

图5 经王水腐蚀后NiCrMo-(0/3.6)Nb堆焊层表面形貌及元素分布

图6 采用JMatPro7.0软件计算的NiCrMo-(0/3.6)Nb平衡相图

图7 NiCrMo-(0/3.6)Nb焊道宽度对比图

图8 NiCrMo-(0/3.6)Nb合金熔体粘度随温度的变化图

图9 NiCrMo-(0/3.6)Nb堆焊层在800 ℃腐蚀60 h后的XRD谱

图10 NiCrMo-(0/3.6)Nb堆焊合金在800 ℃腐蚀60 h后的的增重柱状图

图11 NiCrMo-(0/3.6)Nb堆焊合金在800 ℃，N2-CO2 (29.8 mg/L)-O2 (23.4 mg/L)-HCl (3.53 mg/L)混合气氛中腐蚀60 h后的表面形貌及物相组成

图12 NiCrMo-(0/3.6)Nb堆焊层在800 ℃，N2-CO2 (29.8 mg/L)-O2 (23.4 mg/L)-HCl (3.53 mg/L)混合气氛中腐蚀 60 h 后的元素分布图

[1]	Li C X, He E Q, Bai J F, et al. Research on processing methods and control strategies of nickel-based superalloy materials [J]. Mech. Electr. Eng. Technol., 2025
[1]	李晨熙, 何恩球, 白俊峰等. 镍基高温合金材料加工工艺方法现状与发展趋势 [J]. 机电工程技术, 2025
[2]	Li Z Y, Gong Y, Liu S B, et al. Development of nickel-based superalloys [A]. Proceeding of China Foundry Activity Week [C]. Hefei, 2020
[2]	李重阳, 龚燚, 刘时兵等. 镍基高温合金的发展综述 [A]. 2020中国铸造活动周论文集 [C]. 合肥, 2020
[3]	Mohammadi Zahrani E, Alfantazi A M. Hot corrosion of Inconel 625 wrought alloy and weld overlay on carbon steel by gas metal arc welding in 47 PbSO₄-23 ZnO-13 Pb₃O₄-7 PbCl₂-5 CdO-5 Fe₂O₃ molten salt mixture [J]. Corros. Sci., 2021, 183: 109348 doi: 10.1016/j.corsci.2021.109348
[4]	Wang D, Hou Z Q, Cheng D H, et al. Effect of NbC on the microstructure and mechanical properties of electrospark deposited NiCrBSi-NbC abrasive coatings for Ni-based superalloy blade tips [J]. Surf. Coat. Technol., 2025, 505: 132104 doi: 10.1016/j.surfcoat.2025.132104
[5]	Wang S Y, Liu S W, Hou X Y, et al. Effect of wire composition on weldability of a Ni-based superalloy welded by TIG method [J]. Trans. China Weld. Inst., 2023, 44(3): 31
[5]	王诗洋, 刘士伟, 侯星宇等. 焊丝成分对镍基高温合金TIG焊焊接性的影响 [J]. 焊接学报, 2023, 44(3): 31 doi: 10.12073/j.hjxb.20220401001
[6]	Li D, Li W, Liu X J. Effect of Nb content on microstructure and mechanical properties of TiZrVNb _x high-entropy energetic alloys [J]. J. Alloy. Compd., 2025, 1036: 181550 doi: 10.1016/j.jallcom.2025.181550
[7]	Feng Y Q, Ye J L, Feng Y L, et al. Microstructure evolution and high temperature oxidation behavior of laser cladded titanium-based composite modified by Nb/Si addition [J]. Surf. Coat. Technol., 2022, 444: 128677 doi: 10.1016/j.surfcoat.2022.128677
[8]	Su S, Li M A, Liu J Y, et al. Effect of Nb content on microstructure and mechanical properties of porous Ti-Nb alloys [J]. J. Mater. Eng., 2024, 52(9): 141 doi: 10.11868/j.issn.1001-4381.2023.000649
[8]	苏苏, 李明骜, 刘俊逸等. Nb含量对多孔Ti-Nb合金组织与力学性能的影响 [J]. 材料工程, 2024, 52(9): 141
[9]	Hao W Y, Gong T Z, Chen Y, et al. Temperature gradient mechanism in the heterogeneous nucleation of inoculated alloy: A quantitative phase-field study [J]. Mater. Today Commun., 2024, 41: 110701
[10]	Wang S B, Sun W Q, Wang M, et al. The effect of Nb on microstructure and properties of GH4169 alloy pipe [J]. Spec. Steel, 2024, 45(5): 34 doi: 10.20057/j.1003-8620.2023-00224
[10]	王哨兵, 孙文强, 王曼等. Nb对GH4169合金管材组织性能的影响 [J]. 特殊钢, 2024, 45(5): 34
[11]	Zhang Y M, Wu S W, Guo Z X, et al. Defects caused by powder spattering and entrainment in laser powder bed fusion process: High-fidelity modeling of gas, melt pool and powder dynamics [J]. Acta Mater., 2025, 288: 120816 doi: 10.1016/j.actamat.2025.120816
[12]	Dubey P K, Bandopadhyay A, Manna I, et al. Role of melt pool convection in optimising defect free components fabricated via laser powder bed fusion of CuSn alloy [J]. Appl. Therm. Eng., 2025, 268: 125876 doi: 10.1016/j.applthermaleng.2025.125876
[13]	Dou K, Lordan E, Zhang Y J, et al. A novel approach to optimize mechanical properties for aluminium alloy in High pressure die casting (HPDC) process combining experiment and modelling [J]. J. Mater. Process. Technol., 2021, 296: 117193 doi: 10.1016/j.jmatprotec.2021.117193
[14]	Cheng G, Chen Y P, Wang Q Y. Phase field simulation of grain growth kinetics with solute drag in Fe-Mo-Nb alloy [J]. At. Energy Sci. Technol., 2023, 57: 1980
[14]	程刚, 陈宇鹏, 王庆宇. Fe-Mo-Nb合金中溶质拖曳晶粒长大动力学的相场模拟 [J]. 原子能科学技术, 2023, 57: 1980
[15]	Shang J X, Zhao Y B, Hu L N. Abnormal viscosity changes in high-temperature metallic melts [J]. Acta Phys. Sin., 2018, 67: 106402 doi: 10.7498/aps
[15]	商继祥, 赵云波, 胡丽娜. 高温金属熔体黏度突变探索 [J]. 物理学报, 2018, 67: 106402
[16]	Bai L Y. Study on high temperature chlorine corrosion properties of the modified alloys and high-entropy alloys based on 904L steel [D]. Nanchang: Nanchang University, 2022
[16]	白凌云. 基于904L的改性合金及高熵合金的高温氯腐蚀性能研究 [D]. 南昌: 南昌大学, 2022
[17]	Lin B Q, Hu L J, Zhou Z H, et al. Effect of Nb₂O₅ particle size on inner stress in oxide film on zirconium alloy [J]. Shanghai Met., 2020, 42(3): 59
[17]	林保全, 胡丽娟, 周志浩等. Nb₂O₅颗粒尺寸对锆合金氧化膜内应力的影响 [J]. 上海金属, 2020, 42(3): 59
[18]	Wang J Y, Zhang J S, Yue M K, et al. Improving oxidation resistance by fabricating micro-rings on the surface: Proof of concept for nickel-based superalloy [J]. Surf. Coat. Technol., 2025, 498: 131812 doi: 10.1016/j.surfcoat.2025.131812
[19]	Ye X J, Yang B B, Nie Y, et al. Influence of Nb addition on the oxidation behavior of novel Ni-base superalloy [J]. Corros. Sci., 2021, 185: 109436 doi: 10.1016/j.corsci.2021.109436
[20]	Liu D, Dong R F, Zhang X Y, et al. High-temperature oxidation behavior of Ni-Cr-W and Ni-Cr-Fe superalloys: A comparative study at 1000 ℃ [J]. J. Alloy. Compd., 2025, 1025: 180271 doi: 10.1016/j.jallcom.2025.180271
[21]	Zhao Z W, Wang S L, Lu Y L, et al. Oxidation behavior of a Ni-Cr-Fe superalloy from 800 ℃ to 1100 ℃ in air: Formation and mechanism of multilayer oxide films [J]. J. Alloy. Compd., 2025, 1020: 179393 doi: 10.1016/j.jallcom.2025.179393

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