大气环境中涂层下金属的腐蚀和涂层的失效

中国腐蚀与防护学报

2002, Vol. 22

Issue (4): 249-256

综述

本期目录 | 过刊浏览

大气环境中涂层下金属的腐蚀和涂层的失效

徐永祥;严川伟

北京航空材料研究所

UNDERFILM CORROSION OF METALS AND FAILUREOF ORGANIC COATINGS IN ATMOSPHERE

Yongxiang Xv;Chuanwei Yan

北京航空材料研究所

全文: PDF(286 KB)

摘要: 综述了大气环境中金属腐蚀和涂层失效的机理、影响腐蚀失效的各种因素及研究方法和手段，展望了研究前景.老化和涂层下金属腐蚀是引起涂层失效两个重要的因素，老化为自由基机理，涂层下金属腐蚀为电化学反应机理.影响腐蚀失效的各种因素包括涂层性能、气体污染物、基体金属上可溶盐污染、基体金属表面状态和处理等 .研究方法主要有电化学方法和光谱学方法，电化学方法中最主要的是电化学阻抗法，较新的是Kelvin扫描电极；光谱学方法包括红外光谱、激光拉曼光谱等.现代采用多种方法综合研究，并且倾向于使用原位在线测量技术.

关键词 ：涂层, 大气腐蚀

Abstract：Underfilm corrosion of metals and failure of or gani c coatings in atmosphere are of great interesting and practical meaning.Weatheri ng and underfilm corrosion are the two most important factors which cause failur e of organic coatings.The mechanism of weathering is generally considered to be radical reaction initiated by photon while the mechanism of underfilm corrosion, to be electrochemical reaction.The factors affecting the corrosion and failure i nclude property of the coating,air pollutant,contamination of soluble salts on m etal substrate,surface condition and treating of substrate,and so on.The researc hing approaches are mainly electrochemical methods including DC and AC methods,a nd spectroscopy.Of the electrochemical methods,the electrochemical impedance spe ctroscopy (EIS) is the most important and widely used,and the Kelvin scanning pr obe is a new and promising method.Spectroscopy includes infrared spectroscopy an d Raman spectroscopy.Nowadays it is common to use these methods coordinately and to carry out in situ on-line measurements.The present paper reviews the above a spects.

Key words： coating atmosphere corrosion

收稿日期: 2000-11-01

ZTFLH:

TG174.4

通讯作者: 徐永祥

Corresponding author: Yongxiang Xv

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引用本文:

徐永祥; 严川伟 . 大气环境中涂层下金属的腐蚀和涂层的失效[J]. 中国腐蚀与防护学报, 2002, 22(4): 249-256 .
Yongxiang Xv, Chuanwei Yan. UNDERFILM CORROSION OF METALS AND FAILUREOF ORGANIC COATINGS IN ATMOSPHERE. J Chin Soc Corr Pro, 2002, 22(4): 249-256 .

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y2002/V22/I4/249

[1]NguyenTN ,HubbardJB ,McFaddenGB .Amathematicalmodelforthecathodicblisteringoforganiccoatingsonsteelimmersedinelectrolytes[J].J.Coat.Tech.,1991,63(794):43-52.
[2]WangGY .CorrosionandProtectionofEntironment[M ].Beijing:ChemicalIndustryPress,1997.(王光雍等.自然环境的腐蚀与防护[M ].北京:化学工业出版社,1997.)
[3]HoffmannK ,StratmannM .Thedelaminationoforganiccoatingsfromrustysteelsubstrates[J].Corros.Sci.,1993,34(10):1625-1645.
[4]KoehlerEL .Theinfluenceofcontaminantsonthefailureofprotec tiveorganiccoatingsonsteel[J].Corrosion,1977,33(6):209-217.
[5]ArmstrongRD ,JohnsonBW .Aninvestigationintothecathodicdelaminationofunpigmentedchlorinatedrubberfilms[J].Corros.Sci.,1991,32(3):303-312.
[6]ArmstrongRD ,JohnsonBW ,WrightJD .Aninvestigationintothecathodicdelaminationofepoxy-polyamineprotectivecoatings[J].ElectrochemicaActa,1991,36(13):1915-1923.
[7]LeidheiserHJr,WangW ,IgetoftL .Themechanismfortheca thodicdelaminationoforganiccoatingsfromametalsurface[J].Prog.Org.Coatings,1983,11:19-40.
[8]ArmstrongRD ,JenkinsATA ,JohnsonBW .AninvestigationintotheUVbreakdownofthermosetpolyestercoatingsusingimpedancespectroscopy[J].Corros.Sci.,1995,37(10):1615-1625.
[9]HalliwellSM .Rap.Rev.Rev.5,Report53[C],1992.
[10]RabekJF .MechanismsofPhotophysicalProgressesandPhoto chemicalReactionsinPolymers[M ].JohnWilerandSons,1987.
[11]MckellarJF ,AllenNS .PhotochemistryofManMadePolymers[M].AppliedSciencePublishersLtd.,1979.
[12]PappasSP .Weatheringofcoatingsformulationandevaluation[J].Prog.Org.Coatings,1989,17:107-114.
[13]OosterbroekM ,LarmmersRJ ,VanderVenLGJ ,PereraDY .Crackformationandstressdevelopmentinanorganiccoating[J].J .Coat.Tech.1991,63(799):55-60.
[14]RitterJJ,KrugerJ.CorrosionControlbyOrganicCoatings[M ].EditedbyLeidheiserJrH .Houston:Texas,Natl.Assocn.Corro sionEngrs.,1981.
[15]PourbaixM .AtlasofElectrochemicalEquilibriainAqueousSolu tions[M ].London:PergamonPress,1966.
[16]KoehlerEL .Themechanismofcathodicdisbondmentofprotectiveorganiccoatings-aqueousdisplacementatelevatedpH[J].Corro sion,1984,40(1):5-8.
[17]NemethZ ,ErdeiL ,KolicsA .Anewapproachtostudyingiontransportincorrosionprotectivecoatingsusinganinsituradio tracermethod[J].Corros.Sci.,1995,37(7):1163-1166
[18]LambrevVG ,RodinNN ,KoftyukVA .Applicationofthemethodofneutronactivationforstudyingcorrosionprocessesandprotectiveabilityofpaintcoatings[J].Prog.Org.Coat.,1997,30:1-8.
[19]KairaitisAJ.Moistureabsorptioncapacityofpaintfilmsanindica tionoftheircorrosionprotectivecapability[J].CorrosionAustrala sia,1989,14(2):13.
[20]LaiCX .Mechanismofdelaminationofprotectivefilminitiatedbywaterandpreventionmeasure[J].Corros.Sci.Prote.Technol.,1992,4(2):127-134.(赖春晓.水引起保护涂膜剥离的机理及防止方法[J].腐蚀科学与防护技术,1992,4(2):127-134)
[21]DavisGD ,ShawBA ,ArahCO ,etal.EffectofSO2 depositiononpaintedsteelsurfaces[J].SurfaceandInterfaceAnalysis,1990,15:107-112.
[22]SimendingerWH ,BalikCM .Solubility,diffusivity,andchemicalreactivityofsulfurdioxidewithanalkydpaint[J].J .Coat.Tech nol.,1992,64(812):37-43.
[23]HochGM .LocalizedCorrosion[A].Staehleetal.ed.NACE[C],1974.
[24]VanLooM ,LaidermanDD ,BruhnRR .Filiformcorrosion[J].Corrosion,1953,9:277-283
[25]MorcilloM ,Solublesalts:theireffectsonprematuredegradationofanticorrosivepaints[J].Prog.Org.Coat.1999,36:137-147.
[26]MorcilloM .ProceedingsoftheEUROCOAT’98,UATCM/AETEPA ,Barcelona.Spain,1998,Vol.II:617-637.
[27]RuizJL ,HernandezLS ,MorcilloM .Proceedingsofthefirstcon gresonacionaldettratamientosdesuprficies[A].AIMME[C],Va lencia,1992.23.
[28]MorcilloM ,SimancasJ ,FierroJLG ,etal.Accelerateddegrada tionofachlorinatedrubberpaintsystemappliedoverrustedsteel[J].Prog.Org.Coatings,1993,21:315.
[29]MorcilloM ,RodriguezFJ ,BastidasJM .Theinfluenceofchlo rides,sulphatesandnitratesatthecoating-steelinterfaceonun derfilmcorrosion[J].Prog.Org.Coatings,1997,31:245-353.
[30]BastidasJM ,MorcilloM ,RodriguezFJ .Mildsteelcorrosioninsalinesolutions.comparisonbetweenbulksolutionsandsteel-coatinginterfacialsolutions[J].J .Coat.Technol.1998,70(882):61-66.
[31]MorcilloM .Atmosphericcorrosioninibero-America:TheMI CATproject[A].ASTM -STP1293[C].Philadelphia:ASTM ,1995:257-275.
[32]MorcilloM ,SimancasJ.Proceedingsofthe97PEC’,TheHague,March,1997,12.
[33]YanCW ,GaoTZ ,ShiZM ,LinHC ,CaoCN .Laboratoryofef fectofNaClonatmosphericcorrosionofzincinaircontainingSO2[J].ActaMetallurgicaSinica,2000,36(3):272-274.(严川伟,高天柱,史志明,林海潮,曹楚南.NaCl对含SO2环境中Zn大气腐蚀的影响[J].金属学报,2000,36(3):272-274)
[34]TannerAR .Iron(II)sulphateinrust[J].Chem.Ind.,1964,6:1027-1028.
[35]SchwartzH .Untersuchungentuberdiewirkungdeseisen(II)-sulfatesbeimatmospharischenrostenundbeimunterrostenvonanstrichen[J].WerkstoffeundKorrosion,1965,16:93-103.
[36]HintonBR ,CharltonP .Theinfluenceofsubstratesurfacefinishandcontaminationonthecathodicdelaminationofanepoxy-polyamidecoatingfromsteel[J].CorrosionAustralasia,1989,14(2):18-21.
[37]FisherTW ,IezziRA ,MarditchJM .Societyofautomotiveengi neersAnn.Meeting,1980:800149.
[38]IezziRA ,LeidheiserH .Surfacecharacteristicsofcold-rolledsteelastheyaffectpaintperformance[J].CorrosionNACE ,1981,37:28-38.
[39]LeroyV .Metallurgicalapplicationsofsurfaceanalyticaltechniques[J].MaterialSci.&Eng.,1980,42:289-307.
[40]WakanoS ,UsukiT ,NishihalaM ,FujinoH .Effectofsurfaceseg regationduringannealingandsurfaceoxidefilmson phosphatecoatingofcoldrolledsteelsheet[J].Tetsu-to-Hagane,1980,66:945-952.
[41]BrunoM .Perfetti.Substratefactorsaffectingtheperformanceoforganiccoatingsonsteelsheetsurface[J].J .Coat.Technol.,1991,63(795):43-50.
[42]ZhangJQ ,CaoCN .Studyandevaluationonorganiccoatingsbyelectrochemicalimpedancespectroscopy[J].CorrosionandProtec tion,1998,19(3):99-104.(张鉴清,曹楚南.电化学阻抗谱方法研究评价有机涂层[J].腐蚀与防护,1998,19(3):99-104)
[43]ZhangJQ ,CaoCN .AnalyticalsystemofEISdata[J].Corros.Sci.Prote.Technol.,1990,2(3):9-15.(张鉴清,曹楚南.交流阻抗数据分析系统[J].腐蚀科学与防护技术,1990,2(3):9-15)
[44]ZhangJQ ,CaoCN .EISdataanalysisforevaluationofprotectivepropertyoforganiccoatings[J].Corros.Sci.Prote.Technol.,1994,6(4):318-324.(张鉴清,曹楚南.评价有机涂层防护性能的EIS数据处理[J].腐蚀科学与防护技术,1994,6(4):318-324)
[45]SimpsonTC ,MoranPJ ,MoshierWC ,DavidGD ,ArahCD ,ZankleKI .Anelectrochemicalmonitorforthedetectionofcoatingdegradationinatmosphere[J].J .Electrochem.Soc.,1989,136:2761-2762.
[46]AmirudinA ,ThierryD .Electrochemicalsensorformonitoringat mosphericcorrosionofpolymercoatedmetal[J].Br.Corros.J.,1995,30(3):214-220.
[47]DeWittJHW .Proc.12thInt.CorrosionCong.[C].Houston:TX .,USA ,September1993:420.
[48]FrecheteE ,CompereC ,GhaleE .Evaluationofthecorrosionrisis tanceofpaintedsteelbyimpedancemeasurements[J].Corros.Sci.,1992,33:1067-1081.
[49]StratmannM ,StreckleH ,FeserR .Anewtechniqueabletomea suredirectlythedelaminationoforganicpolymer[J].Corros.Sci.,1991,32(4):467-470
[50]ZhouF ,HanW ,LongK ,HanWA .DeterminationofKelvinpo tentialbylinearregression[J].Corros.Sci.Prote.Technol.,1995,7(1):17-22.(邹峰,韩薇,龙康,韩文安.线性回归法进行Kelvin电位测试[J].腐蚀科学与防护技术,1995,7(1):17-22)
[51]StratmannM ,LengA ,FurbethW ,etal.ThescanningKelvinprobe;anewtechniquefortheinsituanalysisofthedelaminationoforganiccoatings[J].Prog.Org.Coat.,1996,27:216-267.
[52]MesserschmidtRG ,HarthcockMA ,Eds.InfraredMicrospec troscopyTheoryandPractice[M ].NewYork:MarcelDecker,Inc.,NY ,1988.
[53]KrishnanK .Proc.SPIE -Int.Soc.Opt.Eng.1986,665:252.
[54]HarthockMA ,LentzLA ,DavisBL ,KrishnanK .ApplicationsoftransmittanceandreflectanceMicro/FT -IRtopolymericmateri als[J].Appl.Spectrosc.,1986,40(2):210-214.
[55]DanielJSkrovanek.Fouriertransforminfraredspectroscopicstud iesofcoatingsdefects[J].J .Coat.Technol.,1989,61(769):31-37.
[56]LuTH .SurfaceenhancedRamanspectroscopyanditsapplicationinchemistry[J].Corros.Sci.Prote.Technol.,1995,7(2):102-107.(陆天虹.表面增强拉曼光谱及其在化学中的应用[J].腐蚀科学与防护技术,1995,7(2):102-107)
[57]YanCW ,YuJK ,LinHC ,CaoCN ,SongGL .ApplicationoflaserRamanspectroscopytotheresearchofmetalcorrosion[J].Corros.Sci.Protec.Technol.,1998,10(3):164-170.(严川伟,余家康,林海潮,曹楚南,宋光玲.激光拉曼光谱在金属腐蚀研究中的应用[J].腐蚀科学与防护技术,1998,10(3):164-170)
[58]BernardMC ,Hugot-LeGoffA ,PhillipsN .Insitustudyofthecorrosionofzinc-coatedsteelinthepresenceofchloride[J].J .Electrochem.Soc.,1995,142(7):2162-2167.
[59]BernardMC ,Hugot-LeGoffA ,PhillipsN .Insitustudyofthecorrosionofzinc-coatedsteelinthepresenceofchloride[J].J .Electrochem.Soc.,1995,142(7):2167-2173.
[60]LiY ,CaoCN ,LinHC .ApplicationofSTMtocorrosion-elec trochemicalresearch[J].Corros.Sci.Prote.Technol.,1998,10(5):284-289.(李瑛,曹楚南,林海潮.扫描隧道显微镜在腐蚀电化学研究中的应用[J].腐蚀科学与防护技术,1998,10(5):284-298)
[61]WuLS .Applicationofelectronicmicroscopetothecorrosionfield[J].CorrosionandProtection,1982,4:47-50.(吴连生.电子显微镜在腐蚀领域中的应用[J].腐蚀与防护,1982,4:47-50)
[62]ChangRQ .AbriefintroductionofM ssbauereffect[J].CorrosionandProtection,1983,6:40-43.(常汝勤.穆斯鲍尔效应简介[J].腐蚀与防护,1983,6;40-43)

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