稀土复合掺杂ZrO2陶瓷涂层抗Na2SO4+NaVO3热腐蚀性能的研究进展

doi:10.11902/1005.4537.2018.132

中国腐蚀与防护学报

2019, Vol. 39

Issue (4): 291-298 DOI: 10.11902/1005.4537.2018.132

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稀土复合掺杂ZrO₂陶瓷涂层抗Na₂SO₄+NaVO₃热腐蚀性能的研究进展

陈超¹,梁艳芬¹,梁天权^1,²(

),满泉言¹,罗毅东¹,张修海^1,²,曾建民^1,²

1. 广西大学资源环境与材料学院南宁 530004
2. 广西大学广西有色金属及特色材料加工重点实验室南宁 530004

Research Progress on Hot Corrosion of Rare Earth Oxides Co-doped ZrO₂ Ceramic Coatings in Molten Na₂SO₄+NaVO₃ Salts

CHEN Chao¹,LIANG Yanfen¹,LIANG Tianquan^1,²(

),MAN Quanyan¹,LUO Yidong¹,ZHANG Xiuhai^1,²,ZENG Jianmin^1,²

1. School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China
2. Guangxi Key Laboratory of Processing for Non-ferrous Metallic and Featured Materials, Guangxi University, Nanning 530004, China

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摘要:

系统讨论了单元掺杂、二元掺杂、多元稀土掺杂对ZrO₂陶瓷涂层抗Na₂SO₄+NaVO₃热腐蚀性能的影响；总结了Na₂SO₄+NaVO₃对热障涂层陶瓷表层、热生长氧化物层、粘结层的腐蚀行为及典型的3种热腐蚀机理；指出了提高ZrO₂陶瓷涂层抗Na₂SO₄+NaVO₃热腐蚀性能的研究方向。

关键词 ：稀土掺杂ZrO₂陶瓷涂层, Na₂SO₄+NaVO₃熔盐, 热腐蚀, 研究进展

Abstract：

The doping effect of single, binary and ternary rare earth oxides respectively on the hot corrosion resistance of ZrO₂ ceramic coatings in molten Na₂SO₄+NaVO₃ salts was systematically summarized and discussed in this paper. The hot corrosion behavior of the top ceramic coating, thermal grown oxide scale and bond coat of the TBCs in molten Na₂SO₄+NaVO₃ and the relevant hot corrosion mechanisms were summarized. The research direction of improving the hot corrosion resistance of ZrO₂ceramic coating against the Na₂SO₄+NaVO₃ salts was suggested, too.

Key words： rare earth oxides co-doped zirconia ceramic coating sulfate and vanadate molten salts hot corrosion research progress

收稿日期: 2018-09-13

ZTFLH:

TG174

基金资助:国家自然科学基金(51361003);广西有色金属及特色材料加工重点实验室青年基金(GXYSYF1801);广西高等学校千名中青年骨干教师培育计划资助项目

通讯作者: 梁天权 E-mail: liangtianquan@gxu.edu.cn

Corresponding author: Tianquan LIANG E-mail: liangtianquan@gxu.edu.cn

作者简介: 陈超，男，1991年生，硕士生

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引用本文:

陈超,梁艳芬,梁天权,满泉言,罗毅东,张修海,曾建民. 稀土复合掺杂ZrO₂陶瓷涂层抗Na₂SO₄+NaVO₃热腐蚀性能的研究进展[J]. 中国腐蚀与防护学报, 2019, 39(4): 291-298.
Chao CHEN, Yanfen LIANG, Tianquan LIANG, Quanyan MAN, Yidong LUO, Xiuhai ZHANG, Jianmin ZENG. Research Progress on Hot Corrosion of Rare Earth Oxides Co-doped ZrO₂ Ceramic Coatings in Molten Na₂SO₄+NaVO₃ Salts. Journal of Chinese Society for Corrosion and protection, 2019, 39(4): 291-298.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2018.132 或 https://www.jcscp.org/CN/Y2019/V39/I4/291

图1 YSZ涂层循环寿命与Y2O3的含量关系[9]

图2 700和900 ℃下NaVO3腐蚀100 h后ScYSZ中m-ZrO2含量 [16]

图3 YSZ和CYSZ涂层在1000 ℃下Na2SO4+V2O5熔盐中分别腐蚀12和30 h后表面的XRD谱[17]

图4 ScYSZ和YSZ 涂层在1000 ℃下经熔融Na2SO4+V2O5腐蚀后的表面XRD谱[8]

表1 涂层成分与钒酸盐发生化学反应的规律[19]

图5 YSZ和CYSZ在1050 ℃下Na2SO4+V2O5熔盐中分别腐蚀20和28 h后的SEM形貌[20]

图6 TiYSZ在1050 ℃下经Na2SO4+V2O5腐蚀20和40 h后的SEM形貌[20]

图7 典型YSZ热障涂层结构

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