先进高温热障涂层用高性能粘接层制备及研究进展

doi:10.11902/1005.4537.2019.154

中国腐蚀与防护学报

2019, Vol. 39

Issue (5): 395-403 DOI: 10.11902/1005.4537.2019.154

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先进高温热障涂层用高性能粘接层制备及研究进展

余春堂¹,阳颖飞²,鲍泽斌¹(

),朱圣龙¹

1. 中国科学院金属研究所金属腐蚀与防护实验室沈阳 110016
2. 暨南大学先进耐磨蚀及功能材料研究院广州 510632

Research Progress in Preparation and Development of Excellent Bond Coats for Advanced Thermal Barrier Coatings

YU Chuntang¹,YANG Yingfei²,BAO Zebin¹(

),ZHU Shenglong¹

1. Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
2. Institute of Advanced Wear & Corrosion Resistant and Functional Material, Jinan University, Guangzhou 510632, China

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摘要:

热障涂层能显著提高航空发动机的效率和推重比，具备保护关键热端部件 (例如涡轮叶片) 能力而获得广泛运用，其构成一般由外表面的陶瓷隔热层和抗高温氧化的中间粘接层组成。在热障涂层体系中，粘接层抗高温氧化性能的好坏直接决定了热障涂层体系的服役性能和寿命，因此受到相关研究者的关注。金属Pt改性的粘接层具有优异的抗高温氧化和热腐蚀综合性能，特别是表面生成的连续致密Al₂O₃氧化膜抗剥落性强，是高温防护金属粘结层的优选方案。本文重点介绍了Pt改性MCrAlY粘接层和Pt改性铝化物涂层的研究现状和进展，并且论述了制备方法与原理及其特点，对先进Pt改性粘接层的发展趋势进行了展望。

关键词 ：热障涂层, MCrAlY, 铂铝涂层, 活性元素

Abstract：

Thermal barrier coatings (TBCs) are widely used in hot section of gas turbine engines, holding excellent protection properties at high temperature, with the goal of improving engine efficiency and reducing the operation cost. Generally, a typical TBC is composed of a ceramic topcoat and an oxidation-resistant bond coat, while, the oxidation performance of the bond coat directly determines the overall performance and lifetime of the whole TBC. Thus, the challenge of TBCs operating at higher temperature and harsher environments has attracted the relevant researchers to develop advanced bond coats. Pt-modified aluminide coatings, possessing excellent oxidation resistance, are capable of forming a continuously dense Al₂O₃ scale with low tendency of spallation during exposure at elevated temperature. In the present paper, special attention is devoted to review the development and status of Pt- modified bond coats, including MCrAlY and nickel aluminides, as well as the merits and deficiency of such coatings have been elucidated. At last, the perspectives of manufacturing an advanced bond coat and the development trend are summarized.

Key words： thermal barrier coating MCrAlY Pt-modified aluminide coating reactive element

收稿日期: 2019-09-12

ZTFLH:

TG172

基金资助:国家自然科学基金(51301184)

通讯作者: 鲍泽斌 E-mail: zbbao@imr.ac.cn

Corresponding author: Zebin BAO E-mail: zbbao@imr.ac.cn

作者简介: 余春堂，男，1987年生，博士生

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引用本文:

余春堂,阳颖飞,鲍泽斌,朱圣龙. 先进高温热障涂层用高性能粘接层制备及研究进展[J]. 中国腐蚀与防护学报, 2019, 39(5): 395-403.
Chuntang YU, Yingfei YANG, Zebin BAO, Shenglong ZHU. Research Progress in Preparation and Development of Excellent Bond Coats for Advanced Thermal Barrier Coatings. Journal of Chinese Society for Corrosion and protection, 2019, 39(5): 395-403.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2019.154 或 https://www.jcscp.org/CN/Y2019/V39/I5/395

图1 Pt改性NiCoCrAlY粘接层制备流程图[18]

图4 普通NiCoCrAlY-4YSZ和Pt改性的NiCoCrAlY-4YSZ热障涂层于1100 ℃下循环氧化1000次后的截面形貌[19]

图2 不同方式电镀Pt改性的NiCoCrAlY涂层的氧化增重曲线以及氧化后表面XRD谱[18]

图3 Pt改性NiCoCrAlY-4YSZ制备态截面元素分布和热障涂层体系循环氧化增重对比[19]

图5 Ni-Pt-Al在1100 ℃下的三元相图和β-(Ni，Pt) Al和γ/γ'铂铝涂层循环氧化增重对比[20]

图6 酸性、碱性电镀铂制备的 (Ni，Pt)Al涂层于1100 ℃下恒温氧化300 h氧化动力学曲线[21]

图7 酸性碱性电镀铂制备的 (Ni，Pt)Al涂层于1100 ℃下高温氧化300 h后的表面形貌[21]

图8 酸性电镀铂制备 (Ni，Pt)Al涂层于1100 ℃下循环氧化中发生的氧化膜剥落现象[21]

图9 酸性和碱性电镀铂制备的 (Ni，Pt)Al涂层于1100 ℃下氧化20 h后TOF-SIMS分析[21]

图10 普通 (Ni，Pt)Al与Hf改性 (Ni，Pt)Al恒温氧化动力学对比[23]

图11 普通 (Ni，Pt)Al与Hf改性 (Ni，Pt)Al涂层恒温氧化后截面形貌对比[23]

图12 普通 (Ni，Pt)Al与Hf改性 (Ni，Pt)Al在1100 ℃下氧化20 h后的表面形貌[23]

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