20#钢在含饱和CO<sub>2</sub>的离子液体醇胺溶液中的腐蚀行为研究

doi:10.11902/1005.4537.2019.095

中国腐蚀与防护学报

2020, Vol. 40

Issue (4): 309-316 DOI: 10.11902/1005.4537.2019.095

研究报告

本期目录 | 过刊浏览

20#钢在含饱和CO₂的离子液体醇胺溶液中的腐蚀行为研究

贺三¹(

), 孙银娟², 张志浩², 成杰², 邱云鹏¹, 高超洋¹

1.西南石油大学石油与天然气工程学院成都 610500
2.西安长庆科技工程有限责任公司西安 710000

Corrosion Behavior of 20# Steel in Alkanolamine Solution Mixed with Ionic Liquid Containing Saturated CO₂

HE San¹(

), SUN Yinjuan², ZHANG Zhihao², CHENG Jie², QIU Yunpeng¹, GAO Chaoyang¹

1. Petroleum Engineering School, Southwest Petroleum University, Chengdu 610500, China
2. Xi'an Changqing Technology Engineering Co. Ltd. , Xi'an 710000, China

全文: PDF(5572 KB) HTML

摘要:

利用腐蚀失重实验研究了20#钢在含饱和CO₂的离子液体醇胺混合溶液中的腐蚀行为，并结合SEM和EDS等技术研究了腐蚀产物膜及金属表面的形态。利用EIS拟合等效电路分析了电极表面状态，利用动电位扫描法分析了钝化区的钝化规律。结果表明，单乙醇胺 (MEA) 易与CO₂发生降解反应，生成的降解产物在实验条件下会导致极严重均匀腐蚀；添加[Bmim]BF₄离子液体后，对20#钢的腐蚀有抑制作用，使得均匀腐蚀速率减小；但由于混合溶液中BF₄^-的存在，使得钝化区范围变窄，从而诱发20#钢产生点蚀。

关键词 ： CO₂捕集, 20#钢, MEA溶液, [Bmim]BF₄, 均匀腐蚀, 点蚀

Abstract：

The corrosion behavior of 20# steel in CO₂ saturated mixture liquor of alkanolamine solution with ionic liquid ([Bmim]BF₄) was studied by means of weight loss measurement, electrochemical impedance spectroscopy (EIS) and SEM equipped with EDS. The results showed that monoethanolamine (MEA) was easy to degrade with CO₂, and the formed degradation products would lead to severe corrosion of 20# steel in experimental conditions. When the [Bmim]BF₄ was added, the corrosion of 20# steel was inhibited and hence its uniform corrosion rate was reduced. Besides, due to the existence of BF₄^- in [Bmim]BF₄, the range of passivation zone is narrowed, which is an important cause for pitting corrosion of 20# steel.

Key words： CO₂ capture 20# steel MEA solution [Bmim]BF₄ uniform corrosion pitting corrosion

收稿日期: 2019-06-28

ZTFLH:

TG174

基金资助:国家科技重大专项(2016ZX05016-003)

通讯作者: 贺三 E-mail: hesan@126.com

Corresponding author: HE San E-mail: hesan@126.com

作者简介: 贺三，男，1975年生，博士

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	贺三
	孙银娟
	张志浩
	成杰
	邱云鹏
	高超洋
44.8K

引用本文:

贺三, 孙银娟, 张志浩, 成杰, 邱云鹏, 高超洋. 20#钢在含饱和CO₂的离子液体醇胺溶液中的腐蚀行为研究[J]. 中国腐蚀与防护学报, 2020, 40(4): 309-316.
San HE, Yinjuan SUN, Zhihao ZHANG, Jie CHENG, Yunpeng QIU, Chaoyang GAO. Corrosion Behavior of 20# Steel in Alkanolamine Solution Mixed with Ionic Liquid Containing Saturated CO₂. Journal of Chinese Society for Corrosion and protection, 2020, 40(4): 309-316.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2019.095 或 https://www.jcscp.org/CN/Y2020/V40/I4/309

表1 NaBF4的添加量

图1 不同温度条件下均匀腐蚀速率随[Bmim]BF4浓度变化曲线

图2 30%MEA+不同浓度的[Bmim]BF4条件下20#钢腐蚀产物膜微观形貌

图3 20#钢在添加不同浓度[Bmim]BF4的30%MEA混合溶液中浸泡后去除腐蚀产物膜的表面形貌

图4 20#钢在含不同浓度[Bmim]BF4的混合溶液中外层腐蚀产物膜的EDS分析结果

表2 Fe的EDS分析结果

图5 不同温度下极化曲线随MEA和[Bmim]BF4浓度的变化规律

图6 20#碳钢在含相同摩尔质量BF4-溶液中的极化曲线对比图

图7 20#钢在含不同浓度[Bmim]BF4的混合溶液中浸泡0.5 h后不同温度条件下的EIS曲线

图8 20#钢在混合溶液中浸泡0.5 h后电化学阻抗谱等效电路

表3 20#钢在30和70 ℃下含不同浓度[Bmim]BF4的混合溶液中浸泡0.5 h后阻抗拟合参数

[1]	Choi Y S, Nešić S. Determining the corrosive potential of CO₂ transport pipeline in high pCO₂-water environments [J]. Int. J. Greenhouse Gas Control, 2011, 5: 788 doi: 10.1016/j.ijggc.2010.11.008
[2]	Gale J, Davison J. Transmission of CO₂-safety and economic considerations [A]. Greenhouse Gas Control Technologies-6th International Conference [C]. Kyoto, Japan, 2003: 517
[3]	Osagie E, Biliyok C, Di Lorenzo G, et al. Techno-economic evaluation of the 2-amino-2-methyl-1-propanol (AMP) process for CO₂ capture from natural gas combined cycle power plant [J]. Int. J. Greenhouse Gas Control, 2018, 70: 45 doi: 10.1016/j.ijggc.2018.01.010
[4]	Bougie F, Pokras D, Fan X F. Novel non-aqueous MEA solutions for CO₂ capture [J]. Int. J. Greenhouse Gas Control, 2019, 86: 34 doi: 10.1016/j.ijggc.2019.04.013
[5]	Wang M, Lawal A, Stephenson P, et al. Post-combustion CO₂ capture with chemical absorption: A state-of-the-art review [J]. Chem. Eng. Res. Des., 2011, 89: 1609 doi: 10.1016/j.cherd.2010.11.005
[6]	Brennecke J F, Gurkan B E. Ionic liquids for CO₂ capture and emission reduction [J]. J. Phys. Chem. Lett., 2010, 1: 3459 doi: 10.1021/jz1014828
[7]	Ma T, Wang J X, Du Z Z, et al. A process simulation study of CO₂ capture by ionic liquids [J]. Int. J. Greenhouse Gas Control, 2017, 58: 223
[8]	Ye Y S, Elabd Y A. Relative chemical stability of imidazolium-based alkaline anion exchange polymerized ionic liquids [J]. Macromolecules, 2011, 44: 8494 doi: 10.1021/ma201864u
[9]	Cassity C G, Mirjafari A, Mobarrez N, et al. Ionic liquids of superior thermal stability [J]. Chem. Commun., 2013, 49: 7590 doi: 10.1039/c3cc44118k
[10]	Camper D, Bara J E, Gin D L, et al. Room-temperature ionic liquid-amine solutions: Tunable solvents for efficient and reversible capture of CO₂ [J]. Ind. Eng. Chem. Res., 2008, 47: 8496 doi: 10.1021/ie801002m
[11]	Feng Z, Ma J W, Zheng Z, et al. Study on the absorption of carbon dioxide in high concentrated MDEA and ILs solutions [J]. Chem. Eng. J., 2012, 181/182: 222
[12]	Xiao M, Liu H L, Gao H X, et al. CO₂ capture with hybrid absorbents of low viscosity imidazolium-based ionic liquids and amine [J]. Appl. Energy, 2019, 235: 311 doi: 10.1016/j.apenergy.2018.10.103
[13]	Akinola T E, Oko E, Wang M H. Study of CO₂ removal in natural gas process using mixture of ionic liquid and MEA through process simulation [J]. Fuel, 2019, 236: 135 doi: 10.1016/j.fuel.2018.08.152
[14]	Veawab A, Tontiwachwuthikul P, Chakma A. Corrosion behavior of carbon steel in the CO₂ absorption process using aqueous amine solutions [J]. Ind. Eng. Chem. Res., 1999, 38: 3917 doi: 10.1021/ie9901630
[15]	He S, Gao C Y, Zhang L. Research progress on corrosion of carbon steel during process of capture CO₂ with monoethanolamine solution [J]. Corros. Sci. Prot. Technol., 2018, 30: 454
[15]	(贺三, 高超洋, 张岭. MEA捕集CO₂腐蚀研究进展 [J]. 腐蚀科学与防护技术, 2018, 30: 454) doi: 10.11903/1002.6495.2017.226
[16]	Bello A, Idem R O. Pathways for the formation of products of the oxidative degradation of CO₂-loaded concentrated aqueous monoethanolamine solutions during CO₂ absorption from flue gases [J]. Ind. Eng. Chem. Res., 2005, 44: 945 doi: 10.1021/ie049329+
[17]	Saiwan C, Supap T, Idem R O, et al. Part 3: Corrosion and prevention in post-combustion CO₂capture systems [J]. Carbon Manag., 2011, 2: 659 doi: 10.4155/CMT.11.63
[18]	DuPart M, Bacon T, Edwards D. Understanding corrosion in alkanolamine gas treating plants: Part 1 [J]. Hydrocarb. Process., 1993, 72: 75
[19]	Tanthapanichakoon W, Veawab A, McGarvey B. Electrochemical investigation on the effect of heat-stable salts on corrosion in CO₂ capture plants using aqueous solution of MEA [J]. Ind. Eng. Chem. Res., 2006, 45: 2586
[20]	Fytianos G, Grimstvedt A, Knuutila H, et al. Effect of MEA's degradation products on corrosion at CO₂ capture plants [J]. Energy Proced., 2014, 63: 1869
[21]	Hasib-Ur-Rahman M, Larachi F. Prospects of using room-temperature ionic liquids as corrosion inhibitors in aqueous ethanolamine-based CO₂ capture solvents [J]. Ind. Eng. Chem. Res., 2013, 52: 17682 doi: 10.1021/ie401816w
[22]	Wu K X, Zhou X B, Wu X M, et al. Understanding the corrosion behavior of carbon steel in amino-functionalized ionic liquids for CO₂ capture assisted by weight loss and electrochemical techniques [J]. Int. J. Greenhouse Gas Control, 2019, 83: 216
[23]	Tseng C H, Chang J K, Chen J R, et al. Corrosion behaviors of materials in aluminum chloride-1-ethyl-3-methylimidazolium chloride ionic liquid [J]. Electrochem. Commun., 2010, 12: 1091 doi: 10.1016/j.elecom.2010.05.036
[24]	Lin P C, Sun I W, Chang J K, et al. Corrosion characteristics of nickel, copper, and stainless steel in a Lewis neutral chloroaluminate ionic liquid [J]. Corros. Sci., 2011, 53: 4318 doi: 10.1016/j.corsci.2011.08.047
[25]	Perissi I, Bardi U, Caporali S, et al. High temperature corrosion properties of ionic liquids [J]. Corros. Sci., 2006, 48: 2349 doi: 10.1016/j.corsci.2006.06.010
[26]	Perissi I, Bardi U, Caporali S, et al. Ionic liquids as diathermic fluids for solar trough collectors’ technology: A corrosion study [J]. Sol. Energy Mater. Sol. Cells, 2008, 92: 510 doi: 10.1016/j.solmat.2007.11.007
[27]	Shkurankov A, El Abedin S Z, Endres F. AFM-assisted investigation of the corrosion behaviour of magnesium and AZ91 alloys in an ionic liquid with varying water content [J]. Aust. J. Chem., 2007, 60: 35 doi: 10.1071/CH06305
[28]	NACE. RP0775-2005 Preparation, installation, analysis, and interpretation of corrosion coupons in oilfield operations [S]. Houston, TX: NACE International Publication, Item, 2005
[29]	Fytianos G, Ucar S, Grimstvedt A, et al. Corrosion evaluation of MEA solutions by SEM-EDS, ICP-MS and XRD [J]. Energy Proced., 2016, 86: 197 doi: 10.1016/j.egypro.2016.01.020
[30]	Xiang Y, Yan M C, Choi Y S, et al. Time-dependent electrochemical behavior of carbon steel in MEA-based CO₂ capture process [J]. Int. J. Greenhouse Gas Control, 2014, 30: 125
[31]	Cao C N. Principle of Corrosion Electrochemistry [M]. 2nd Ed. Beijing: Chemical Industry Press, 2004
[31]	(曹楚南. 腐蚀电化学原理 [M]. 第2版. 北京: 化学工业出版社, 2004)
[32]	Atilhan M, Jacquemin J, Rooney D, et al. Viscous behavior of imidazolium-based ionic liquids [J]. Ind. Eng. Chem. Res., 2013, 52: 16774 doi: 10.1021/ie403065u

[1]	冉斗, 孟惠民, 刘星, 李全德, 巩秀芳, 倪荣, 姜英, 龚显龙, 戴君, 隆彬. pH对14Cr12Ni3WMoV不锈钢在含氯溶液中腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2021, 41(1): 51-59.
[2]	张浩, 杜楠, 周文杰, 王帅星, 赵晴. 模拟海水溶液中Fe³⁺对不锈钢点蚀的影响[J]. 中国腐蚀与防护学报, 2020, 40(6): 517-522.
[3]	于浩冉, 张文丽, 崔中雨. 4种镁合金在Cl^--NH₄⁺-NO₃^-溶液体系中的腐蚀行为差异研究[J]. 中国腐蚀与防护学报, 2020, 40(6): 553-559.
[4]	戴明杰, 刘静, 黄峰, 胡骞, 李爽. 基于正交方法研究阴极保护电位波动下X100管线钢的点蚀行为[J]. 中国腐蚀与防护学报, 2020, 40(5): 425-431.
[5]	张欣, 杨光恒, 王泽华, 曹静, 邵佳, 周泽华. 冷拉拔变形过程中含稀土铝镁合金腐蚀行为研究[J]. 中国腐蚀与防护学报, 2020, 40(5): 432-438.
[6]	李清, 张德平, 王薇, 吴伟, 卢琳, 艾池. L80油管钢实际腐蚀状况评估及室内电化学和应力腐蚀研究[J]. 中国腐蚀与防护学报, 2020, 40(4): 317-324.
[7]	郏义征, 王保杰, 赵明君, 许道奎. 固溶处理制度对挤压态Mg-Zn-Y-Nd镁合金在模拟体液中腐蚀和析氢行为的影响规律研究[J]. 中国腐蚀与防护学报, 2020, 40(4): 351-357.
[8]	何壮,王兴平,刘子涵,盛耀权,米梦芯,陈琳,张岩,李宇春. 316L和HR-2不锈钢在盐酸液膜环境中的钝化与点蚀[J]. 中国腐蚀与防护学报, 2020, 40(1): 17-24.
[9]	苏小红,胡会娥,孔小东. W颗粒/Zr_41.2Ti_13.8Cu_12.5Ni₁₀Be_22.5基非晶复合材料在3%NaCl溶液中的腐蚀行为研究[J]. 中国腐蚀与防护学报, 2020, 40(1): 70-74.
[10]	王标,杜楠,张浩,王帅星,赵晴. 304不锈钢点蚀产物对亚稳态点蚀萌生和稳态蚀孔生长的加速作用[J]. 中国腐蚀与防护学报, 2019, 39(4): 338-344.
[11]	李雨,关蕾,王冠,张波,柯伟. 机械应力对不锈钢点蚀行为的影响[J]. 中国腐蚀与防护学报, 2019, 39(3): 215-226.
[12]	张思齐,杜楠,王梅丰,王帅星,赵晴. 阴极面积对3.5%NaCl溶液中304不锈钢稳态点蚀生长速率的影响[J]. 中国腐蚀与防护学报, 2018, 38(6): 551-557.
[13]	黄博博,刘平,刘新宽,梅品修,陈小红. 新型HSn70-1铜网衣两年期海水腐蚀行为研究[J]. 中国腐蚀与防护学报, 2018, 38(6): 594-600.
[14]	樊志民, 于锦, 宋影伟, 单大勇, 韩恩厚. 镁合金点蚀的研究进展[J]. 中国腐蚀与防护学报, 2018, 38(4): 317-325.
[15]	王玉昆, 刘静, 胡骞, 黄峰. S^2-对A710钢在NaCl溶液中腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2018, 38(3): 233-240.

Viewed

Full text

Abstract

Cited

Shared

Discussed